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Exploring Overbank Sediment Deposition Variation In Heavily Modified Floodplains Of The Lower Mississippi River: A Sedimentological And Geophysical Analysis, Seth Fradella

Master's Theses

Since the 1930s, the Lower Mississippi River (LMR) has experienced large-scale modifications to the channel profile and surrounding floodplains through dams, dikes, revetments, dredging, and channel cutoffs. Although these changes have improved navigation and reduced flood risk, unanticipated changes to the major flood return period, individual flood severity and duration, and sediment regime have become increasingly apparent and sometimes problematic, such as the 2011 and 2018-2020 floods. Flood control levees along the LMR have reduced the natural floodplain area by 70-90%, resulting in heavily restricted overbank storage capacity of water and sediment. For the same flood events in recent history, …

The Effects Of Amphibole- And Sulfide-Producing Melts On Crustal Strength In Gabbros Of Lower Oceanic Crust In Oceanic Core Complexes, Mid-Atlantic And Southwest Indian Ridges, Trevor Hoffmann

Master's Theses

This study investigates gabbro-cored oceanic core complexes in the slow-spreading Mid-Atlantic Ridge (MAR) and the ultraslow spreading Southwest Indian Ridge (SWIR). Dikelets are a texture found in thin section samples from these systems that form as a result of crystal-plastic deformation. Thin section samples from the Atlantis Massif, MARK Area, and 13˚-15˚ North of the MAR and the Atlantis Bank of the SWIR were observed with petrography to find these dikelets and identify what type of dikelet is present. SEM-EDS is used to identify the mineral assemblages present in the dikelets. LA-ICP-MS is used on amphibole to determine if its …

Cost-Risk Analysis Of The Ercot Region Using Modern Portfolio Theory, Megan Sickinger

Master's Theses

In this work, we study the use of modern portfolio theory in a cost-risk analysis of the Electric Reliability Council of Texas (ERCOT). Based upon the risk-return concepts of modern portfolio theory, we develop an n-asset minimization problem to create a risk-cost frontier of portfolios of technologies within the ERCOT electricity region. The levelized cost of electricity for each technology in the region is a step in evaluating the expected cost of the portfolio, and the historical data of cost factors estimate the variance of cost for each technology. In addition, there are several constraints in our minimization problem to …

The Effects Of Free Volume And Processing On The Development Of Gas Separation Membranes, Jacob Schekman

Dissertations

Structure, thermal, mechanical, gas transport, and free volume properties of thiol-ene based systems are investigated and discussed. In the pursuit of generating low energy-cost polymer membranes for gas separation, it became apparent that UV-curing of thiol-ene materials presented several routes toward achieving this goal. Network structure plays a vital role in determining the gas transport properties of membrane materials. UV photopolymerization techniques provide a means to rapidly vitrify network morphologies which can be tuned depending on choice of monomer. Thiol-ene monomers offer a broad range of precursor materials from which to choose for the design of functional membrane materials.

Chapter …

Learning Scene Semantics For 3d Scene Retrieval, Natalie Gleason

Honors Theses

This project presents a comprehensive exploration into semantics-driven 3D scene retrieval, aiming to bridge the gap between 2D sketches/images and 3D models. Through four distinct research objectives, this project endeavors to construct a foundational infrastructure, develop methodologies for quantifying semantic similarity, and advance a semantics-based retrieval framework for 2D scene sketch-based and image-based 3D scene retrieval. Leveraging WordNet as a foundational semantic ontology library, the research proposes the construction of an extensive hierarchical scene semantic tree, enriching 2D/3D scenes with encoded semantic information. The methodologies for semantic similarity computation utilize this semantic tree to bridge the semantic disparity between 2D …

Reviving The Past: Enhancing Language Models With Historical Text Optimization, Heather D. Broome

Honors Theses

Recent advancements in Natural Language Processing (NLP) have brought attention to the significant potential that exists for widespread applications of Large Language Models (LLMs). As demands and expectations for LLMs rise, ensuring efficiency and accuracy becomes paramount. Addressing these challenges requires more than just optimizing current techniques; it urges novel approaches to NLP as a whole. This study investigates novel data preprocessing methods designed to enhance LLM performance by mitigating inefficiencies rooted in natural language, particularly by simplifying the complexities presented by historical texts. Utilizing the classical text The Odyssey by Homer, two preprocessing techniques are introduced: tokenization of names …

How To Explain Allen-Manandhar’S Method To Beginner Mathematicians : A Convergence Analysis Of A Hybrid Method For Variable-Coefficient Boundary Value Problems, Rebecca Scariano

Honors Theses

In this project, analogies are employed to make complex math concepts approachable to beginners who may only have a basic understanding of calculus and linear algebra. Serving as the focal point of this project, Allen-Manandhar’s method solves an equation, known as an ordinary differential equation (ODE). The mentioned equation with its coefficients is comparable to a pie recipe with ingredients. With the outcome to a recipe seen as its solution, the solution to our pie recipe is a perfectly baked pie, as in without error. The chosen method for baking a pie then classifies as its baking approach that when …

Antibiotic Resistance In A Coastal River In Mississippi, Usa – Potential Drivers, Shuo Shen, Wei Wu, Eric A. Saillant, Darrell Jay Grimes

Gulf and Caribbean Research

Wastewater treatment plants (WWTPs) are major sources of antibiotic resistant bacteria (ARB) and antibiotic resistance genes (ARGs) in water bodies. Most studies on the impact of WWTPs on antibiotic resistance have focused on freshwater systems, with little information on coastal and estuarine waters with variable salinity. This study monitored seasonal levels of ARGs at the effluent and downstream of the Pascagoula— Moss Point WWTP in the lower Pascagoula River, a coastal river in southeastern Mississippi, USA. Surface water samples were collected seasonally at upstream, outflow, and 3 downstream sites from February to November 2016. Bacterial resistance to sulfamethazine, tetracycline, and …

Applying The Disaster Risk Assessment Framework To Sargassum Inundation In Barbados, A. Karima Degia, Micaela Small, Hazel A. Oxenford

Gulf and Caribbean Research

Episodic influxes of pelagic Sargassum into the Caribbean result in inundation of coastlines with significant negative impacts to the environment, society, and economy. The spatial complexities of this issue demand a strategy that combines spatial planning with an analytical framework that can systematically unpack the underlying factors to inform effective management. We test the application of the United Nations Disaster Risk Reduction (UNDRR) conceptual framework for disaster risk assessment to Sargassum inundation, with a focus on the hazard and exposure components of risk, using Barbados, a Caribbean Small Island Developing State (SIDS), as a case study. We first consider in …

Braving The Elements: Loss Of Metals From Mardi Gras Beads Due To Handling And Weathering, Thomas O. Carmichael, Ruth H. Carmichael

Gulf and Caribbean Research

The largest Mardi Gras celebrations in the U.S. are found along the Gulf of Mexico coast. With increasing awareness of and concern for environmental and human health risks due to pollution from Mardi Gras celebrations, there is a need for studies to quantify potential harms. We conducted a 2—part study to determine whether use—related handling and weathering of common Mardi Gras beaded necklaces results in loss of potentially harmful metals to the environment at levels of ecological or human health concern. Our data indicate that weathering and use—related handling can cause metals to be shed from the metallic coating of …

Variability In Semidiurnal Surface And Internal Tides In Global Ocean Model Simulations, Harpreet Kaur

Dissertations

This dissertation focuses on semidiurnal (D2) surface and internal tides. Chapter 2 investigates the transition of M₂ barotropic Kelvin waves into Hybrid Kelvin-Edge (HKE) waves and the associated generation of internal tides at widening shelves using theory and a realistic global baroclinic Hybrid Coordinate Ocean Model (HYCOM) simulation. To understand the effect of complex, realistic bathymetry on the HKE wave transition, we perform quasi-realistic barotropic HYCOM simulations of the Celtic Sea/Bay of Biscay shelf areas. We conclude that the HKE wave transition is most likely masked by the effects of complex bathymetry and offshelf baroclinic fluxes cannot be exclusively …

Biophysical Factors Affecting Habitat Suitability For Crassostrea Virginica, Jason D. Tilley

Dissertations

Oyster reefs provide a variety of important ecosystem services. However, the mortality rate of eastern oyster, Crassostrea virginica, the dominant species that produces oyster reefs in the northern Gulf of Mexico, is increasing at an alarming rate due to a variety of abiotic and biological factors. I examined how biophysical factors, including the less-studied fatty acid profiles of the suspended particulate matter on which oysters feed, influenced morphometric condition of C. virginica.

I sampled suspended particulate matter (SPM) and oysters in-situ in the western Mississippi Sound, which historically supported the majority of oyster production in Mississippi waters. Sampling …

Structural And Kinematic Investigation Of The Dadeville Complex-Brevard Zone Contact (Southern Appalachians): Polyphase Emplacement Of An Allochthonous Terrane On The Laurentian Margin, Andrew Williams

Master's Theses

The Dadeville Complex (DC) lies in the Inner Piedmont of eastern Alabama and western Georgia. The DC formed as a volcanic island arc during the Taconic orogeny (Ordovician Period) and was accreted onto Laurentia during the Acadian orogeny (Devonian-Mississippian Periods); however, the mechanism and role of accretion during the Acadian orogeny is not well constrained. Three proposed emplacement mechanisms for the DC include: (1) orogen-perpendicular translation; (2) orogen-parallel translation; (3) orogenic channel flow.

Today, the DC is a major (over 100 kilometers long) allochthonous terrane composed mostly of meta-igneous rocks. This study investigated structural fabrics and kinematic indicators in the …

A Computational Kinetics Model To Quantify Radiation Induced Chemical Products Of Atmospheric Gas Mixtures, Patrick Ables

Dissertations

This research is focused on the development of a computational model which will calculate the effects of radiation on the chemical composition of the atmosphere. The approach utilizes the open-source chemical kinetics toolkit Cantera to model the creation of radiation-induced reactant species within irradiated air mixtures. Chemical solutions are iteratively stepped toward chemical equilibrium within a ‘constantly stirred’ (homogeneous) reactor of fixed volume. Three different radiation chemistry models are implemented in several different pulsed and continuous radiation schemes. The first model includes the mechanisms and rates of a pulse radiation model from the literature to test the validity of the …

Characterization And Estimation Of Musculoskeletal Pain Using Machine Learning, Boluwatife Faremi

Master's Theses

Traditional scales utilized for recording pain are known to be highly subjective and biased due to inaccuracies in recollecting actual pain intensities. As a result, machine learning (ML) models that are trained using these scores as ground truth are reported to have low performance for objective pain classification because of the huge disparity between what was felt in moments of pain and the scores recorded afterward.

In the present study, two devices were designed for gathering real-time, continuous in-session subjective pain scores and the recording of the autonomic nervous system (ANS) altered endodermal (EDA) activity. 24 participants were recruited to …

Annotation Of Non-Model Species’ Genomes, Taiya Jarva

Master's Theses

The innovations in high throughput sequencing technologies in recent decades has allowed unprecedented examination and characterization of the genetic make-up of both model and non-model species, which has led to a surge in the use of genomics in fields which were previously considered unfeasible. These advances have greatly expanded the realm of possibilities in the fields of ecology and conservation. It is now possible to the identification of large cohorts of genetic markers, including single nucleotide polymorphisms (SNPs) and larger structural variants, as well as signatures of selection and local adaptation. Markers can be used to identify species, define population …

Scalable Preparation Of The Masked Acyl Cyanide Tbs-Mac, Haley Hinton, Jack Patterson, Jared Hume, Krunal Patel, Julie Pigza

Faculty Publications

This paper describes the three-step synthesis of TBS-MAC, a masked acyl cyanide (MAC) and a versatile one-carbon oxidation state three synthon. We have developed a scalable and detailed synthesis that involves: (1) acetylation of malononitrile to form the sodium enolate, (2) protonation of the enolate to form acetylmalononitrile, and (3) epoxidation of the enol, rearrangement to an unstable alcohol, and TBS-protection to form the title compound. Both the sodium enolate and acetylmalononitrile are bench-stable precursors to the intermediate hydroxymalononitrile, which can be converted to other MAC reagents beyond TBS by varying the protecting group (Ac, MOM, EE, etc.).

Solving The Cable Equation, A Second-Order Time Dependent Pde For Non-Ideal Cables With Action Potentials In The Mammalian Brain Using Kss Methods, Nirmohi Charbe

Master's Theses

In this thesis we shall perform the comparisons of a Krylov Subspace Spectral method with Forward Euler, Backward Euler and Crank-Nicolson to solve the Cable Equation. The Cable Equation measures action potentials in axons in a mammalian brain treated as an ideal cable in the first part of the study. We shall subject this problem to the further assumption of a non-ideal cable. Assume a non-uniform cross section area along the longitudinal axis. At the present time, the effects of torsion, curvature and material capacitance are ignored. There is particular interest to generalize the application of the PDEs including and …

Understanding The Flow Dynamics Of The Pearl River, Ms, Through Hydrodynamic Modeling, Nahruma Mehzabeen Pieu

Master's Theses

The Pearl River brings fresh water and nutrients into Lake Borgne regulating conditions for oyster growth in estuarine waters. However, there are no flow measurement stations installed on East Pearl or West Pearl either at the river outlets or after the upstream bifurcation of the Pearl. This study aims to model the Lower Pearl River to understand the flow dynamics in the major branches, and to determine the final outflow distribution into the Mississippi Sound, aiming to improve river forcing for ocean models studying estuarine dynamics of the Mississippi Sound.

Synthetic meandering bathymetry with updated banks is developed and applied …

The Mobility Of Long-Lived Radioisotopes And Their Burial In The Marine Environment, Neil Redmond

Dissertations

Marine sediments record chemical signals that reflect past environmental conditions. It is important to establish how these signals are created and whether they may be altered over time so that they can be useful for reconstructing ocean history. Measurements of uranium isotopes are used as a novel proxy for sedimentary diagenetic processes (Chapter 2). Because ²³⁴U can be ejected from mineral lattice during the decay of ²³⁸U, it creates a pool of U in porewater that is potentially mobilized and then deposited elsewhere in the core. We found that alpha-recoiled ²³⁴U is sensitive to differences in sediment …

Understanding The Impacts Of Topobathymetric Data On Storm Surge Model Predictions, Sydni Crain

Master's Theses

The topobathymetric characteristics of a region are regularly altered by natural and anthropogenic causes. This directly impacts the resulting storm surge during a hurricane. The primary goal of this research was to gain a better understanding of the impact that topography and bathymetry have on storm surge models, particularly the Advanced Circulation (ADCIRC) Model. Hurricane Zeta (2020) and Hurricane Ida (2021) were chosen as case studies; therefore, the Gulf of Mexico (GOM) was chosen as the study site. This research was completed by comparing ADCIRC storm surge results which were based on older, lower-resolution data with results derived from more …

Connecting Social And Ecological Systems In Small-Scale Fisheries In The Philippines, Sara Eisler Marriott

Dissertations

Nearly 50% of all marine fish capture in the Philippines is from artisanal fisheries, most of which is un- or under-reported. As in many emerging nations around the world, the Philippines cannot fully address overfishing by managing only half of the catch that comes from commercial fisheries. Marine reserves are a popular governance strategy for conservation and of growing interest for fisheries management. Many marine reserves in the Philippines, however, are not considered effective. In 2014, Rare, an international NGO, implemented a community-based management program to increase the effectiveness of the marine reserves, and while it found biomass increased, there …

Origin And Structure Of The First Sharp Diffraction Peak Of Amorphous Solids, Devilal Dahal

Dissertations

Several explanations have been reported in the literature about the origin of extended-range oscillations (EROs) in the atomic pair-correlation function of amorphous materials. Although the radial ordering beyond the short-range order of about 5 Å has been extensively studied in amorphous materials, the exact nature of the radial ordering beyond a nanometer is still not resolved. This dissertation address this problem and explains the nature of the EROs by using high-quality models of amorphous silicon (a-Si) obtained from Monte Carlo and Molecular Dynamics simulations. The extended-range ordering in a-Si is examined through radial oscillations on the length …

Determining The Refractive Index Of Phytoplankton Via Direct Measurement Of Cellular Structures, Michael Kamowski

Master's Theses

The refractive index of phytoplankton has never been directly measured before despite its importance towards studying the optical characteristics of marine particles. Previous attempts to measure it have been done through indirect methods. While these methods have proven useful, they contain assumptions about the particles morphology and composition that cause for uncertainty with the measurements. Through the use of the 3D Cell Explorer, a high precision holotomographic microscope, the RI of phytoplankton can be directly measured for the first time. With volume measurements, the phytoplankton were found to not display a single bulk RI, instead the bulk RI was different …

New Insights Into The Paleovegetation Of The Ancient Underwater Forest Located In The Northern Gulf Of Mexico, Karla Lizarraga Garcia

Master's Theses

A well-preserved remnant of an ancient bald cypress forest (hereafter, Underwater Forest) constitutes the only known archive of a glacial refuge on the once exposed continental shelf of the Northern Gulf of Mexico. This forest existed around 41-72 yBP (MIS 3-5) according to the existing dating methods applied on previous studies. As the climate conditions and sea levels changed, the vegetation of this glacial refuge shifted from bald cypress forests to open marshes, altering the vegetation dynamics. The present research analyzed four new cores (21DF-5A, 21DF-5B, 15DF-6, and 16DF-3A), which provided additional insights into the vegetation that once existed in …

Dissolved Copper Distributions In The Western Mississippi Sound: Characterizing An Unrecognized Endmember, Megan Hansen

Honors Theses

This study examined the distribution of dissolved copper (Cu) in the western Mississippi Sound, as the element can be beneficial or harmful to organisms depending on its concentration and its chemical form. A mixing experiment eliminated flocculation as a control on Cu distributions during estuarine mixing in both dissolved and colloidal fractions. Field sampling of the western Mississippi Sound occurred during a low river discharge period, and distributions of Cu indicated conservative mixing between fresh ([Cu] ≈ 17 nM) and saline ([Cu] ≈ 2 nM) sources in mid-to-high salinities. Storm outfalls were sampled after rain events to evaluate the impact …

Separating The R Vs. S Enantiomers Of A Quinoline Aimed At Inhibiting The Allosteric Binding Pocket Of Hiv-1 Integrase, Madison Canfield

Honors Theses

HIV-1 is a retroviral disease that infects CD4+ T cells in the body. Once inside the body, HIV-1 uses human cell machinery to replicate and reproduce using several enzymes to reverse transcribe viral RNA to DNA and integrate the viral DNA into the human genome to reproduce. Several drugs, such as NRTIs, INSTIs, NNRTIs, and PIs, have been created to inhibit specific parts of the viral life cycle and are used in combination to fight HIV-1. However, these medications face challenges of viral mutation and resistance, which increases the importance of creating more potent and effective drugs. Recently, a new …

Separating The R Vs. S Enantiomers Of A Quinoline Aimed At Inhibiting The Allosteric Binding Pocket Of Hiv-1 Integrase, Madison Canfield

Honors Theses

HIV-1 is a retroviral disease that infects CD4+ T cells in the body. Once inside the body, HIV-1 uses human cell machinery to replicate and reproduce using several enzymes to reverse transcribe viral RNA to DNA and integrate the viral DNA into the human genome to reproduce. Several drugs, such as NRTIs, INSTIs, NNRTIs, and PIs, have been created to inhibit specific parts of the viral life cycle and are used in combination to fight HIV-1. However, these medications face challenges of viral mutation and resistance, which increases the importance of creating more potent and effective drugs. Recently, a new …

Hydrothermal Fluid Transport Pathways Along Fractures And Veins At Brothers Volcano, Southern Kermadec Arc, Robert Atnip

Master's Theses

Hydrothermal fluid flow in fractures and veins is a key component in the mineralization of economic metals within calderas. But there are several methods by which fractures can form. Regional extension, episodic caldera collapse, and fluid overpressure all have the potential to create brittle features. Current studies focus on the formation of fractures and veins by these methods, but do not focus on the preferred movement of hydrothermal fluids through brittle features, nor which features are more dominant in active hydrothermal systems. This thesis introduces multiple studies to better understand which method of fracture creation dominates Brothers volcano. Data from …

The Influence Of Diamine Curing Additives On The Network Architecture Of Phthalonitrile Thermosetting Polymers, Tyler J. Richardson

Dissertations

Phthalonitrile monomers undergo diamine-promoted polymerization by a complex reaction mechanism involving two competitive cure pathways, forming two primary network architectures: linear polyisoindoline chains and branched triazine crosslinks. The influence of the diamine curing additive on the polymerization pathway, and the influence of the resulting network architectures on cured network properties, have not been adequately explored within the phthalonitrile field. Two structurally different diamine curing additives, bis[4-(3-aminophenoxy)phenyl] sulfone (mBAPS) and 1,3-phenylenebis((4-(4-aminophenoxy)phenyl)methanone) (AEK-134), were studied for the polymerization of resorcinol phenylphosphate phthalonitrile (RPPhPN), where the influence of diamine structure and concentration on the polymerization behavior, network architecture, and bulk thermal and thermomechanical …