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Formulation, Structure, And Applications Of Therapeutic, Amino Acid, And Water-Based Deep Eutectic Solvents, Md Sajjadur Rahman Jan 2022

Formulation, Structure, And Applications Of Therapeutic, Amino Acid, And Water-Based Deep Eutectic Solvents, Md Sajjadur Rahman

Electronic Theses and Dissertations

In the design of greener chemicals, deep eutectic solvents (DESs) are considered as one of the most versatile alternative solvents with widespread applications. DESs have the advantages of being nonflammable with negligible vapor pressure compared to traditional solvents. They share many characteristics of ionic liquids, but DESs are cheaper to formulate, typically nontoxic, recyclable, biodegradable, and are suitable for use with biological systems. In my Ph.D. research, three types of emerging and unconventional types of DESs, namely therapeutic DES (THEDES), amino acid-based DES (AADES), and water-based DES (WDES), have been investigated. To formulate these DES easily available and cheaper chemicals, …


Machine-Learning And Meta-Analysis Techniques To Quantify And Predict Soil Organic Carbon, N2O-N And Co2-C Emissions In Cover Crop Systems, Deepak Raj Joshi Jan 2022

Machine-Learning And Meta-Analysis Techniques To Quantify And Predict Soil Organic Carbon, N2O-N And Co2-C Emissions In Cover Crop Systems, Deepak Raj Joshi

Electronic Theses and Dissertations

People worldwide are challenged by multiple threats including climate change, growing populations, and soil degradation. Addressing these challenges requires understanding of the local environment, farming systems and modern technologies. These technologies include new ways to process information that include artificial intelligence, machine learning and meta-analysis. Models produced using these technologies may be useful for predicting the consequences of implementing conservation practices that reduce GHG emissions as well as for determining the carbon footprint of cropping systems that include environmentally friendly conservation technologies such as growing cover crop. Therefore, our objectives of this study were to: 1) provide an overview of …


Efficient Numerical Optimization For Parallel Dynamic Optimal Power Flow Simulation Using Network Geometry, Rylee Sundermann Jan 2022

Efficient Numerical Optimization For Parallel Dynamic Optimal Power Flow Simulation Using Network Geometry, Rylee Sundermann

Electronic Theses and Dissertations

In this work, we present a parallel method for accelerating the multi-period dynamic optimal power flow (DOPF). Our approach involves a distributed-memory parallelization of DOPF time-steps, use of a newly developed parallel primal-dual interior point method, and an iterative Krylov subspace linear solver with a block-Jacobi preconditioning scheme. The parallel primal-dual interior point method has been implemented and distributed in the open-source PETSc library and is currently available. We present the formulation of the DOPF problem, the developed primal dual interior point method solver, the parallel implementation, and results on various multi-core machines. We demonstrate the effectiveness our proposed block-Jacobi …


Study On Performance Of Pruned Cnn-Based Classification Models, Mengling Deng Jan 2022

Study On Performance Of Pruned Cnn-Based Classification Models, Mengling Deng

Electronic Theses and Dissertations

Convolutional Neural Network (CNN) is a neural network developed for processing image data. CNNs have been studied extensively and have been used in numerous computer vision tasks such as image classification and segmentation, object detection and recognition, etc. [1] Although, the CNNs-based approaches showed humanlevel performances in these tasks [2], they require heavy computation in both training and inference stages, and the models consist of millions of parameters. This hinders the development and deployment of CNN-based models for real world applications. Neural Network Pruning and Compression techniques have been proposed [3, 4] to reduce the computation complexity of trained CNNs …


The Significance Of A New 11,000-Year Volcanic Record From The South Pole And Inferences From Comparisons With Other Volcanic Records, Derek Lee Brandis Jan 2022

The Significance Of A New 11,000-Year Volcanic Record From The South Pole And Inferences From Comparisons With Other Volcanic Records, Derek Lee Brandis

Electronic Theses and Dissertations

Snow accumulation at the polar regions of the planet preserves chemical substances from the atmosphere creating natural archives. Records of the atmospheric environment including atmospheric chemical composition and the climate can be reconstructed from ice cores from the polar ice sheets. Sulfur emitted by explosive volcanic eruptions is preserved as sulfate in polar snow and can be used to reconstruct the record of volcanic eruptions. Since large volcanic eruptions impact the environment and climate, records of volcanic eruptions from ice cores can help us to study and understand climate change and model the future climate environment. A 1750-m ice core …


Phosphorus Use And Management Based On Fertilizer Placement, Rate Of Application, And Soil Biota In No-Till Situations, Brennan Alexander Bingham Lewis Jan 2022

Phosphorus Use And Management Based On Fertilizer Placement, Rate Of Application, And Soil Biota In No-Till Situations, Brennan Alexander Bingham Lewis

Electronic Theses and Dissertations

Phosphorus (P) pollution has become a concern among multiple scientific organizations as it leads to eutrophication, an algal bloom that depletes lacustrine and marine ecosystems of native species. Multiple strategies can be implemented to reduce phosphorus loss from agriculture fields, which is often implicated as a cause of eutrophication. Soil phosphorus chemistry results in phosphate fertilizers absorbing to clay minerals over time. Soil phosphorus is lost from agricultural fields primarily through wind and water erosion. No-till practices prevent soil erosion, which reduces the phosphorus from loading into waterways. Fertilizer placement affects phosphorus loss. Surface application of phosphorus fertilizers increases the …


Diversity And Inclusion In Science Teaching Learning (Distl): Focusing On The Perspectives Of Undergraduate Students And Graduate Teaching Assistants In The Chemistry Classroom, Albert Aidoo Jan 2022

Diversity And Inclusion In Science Teaching Learning (Distl): Focusing On The Perspectives Of Undergraduate Students And Graduate Teaching Assistants In The Chemistry Classroom, Albert Aidoo

Electronic Theses and Dissertations

Students in Science, Technology, Engineering and Mathematics (STEM) come with a wide range of experiences and educational backgrounds. There is high attrition rate and low academic achievement among students in STEM areas, specifically in college chemistry courses that are prerequisites for many STEM majors. Hence it is important to look at diversity and inclusion specifically in first- and second-year college chemistry courses to address the challenge of student attrition in STEM. Diversity can be understood as the differences each student brings along the dimensions of prior knowledge, skills, race, ethnicity, sexual orientation, gender, socio-economic status, age, ability, religious or political …


Combining Soil Health And Fertility Measurements To Improve The Accuracy Of Predicting Corn Grain Yield Responses To P And K Fertilization, Benjamin Groebner Jan 2022

Combining Soil Health And Fertility Measurements To Improve The Accuracy Of Predicting Corn Grain Yield Responses To P And K Fertilization, Benjamin Groebner

Electronic Theses and Dissertations

Researchers have pointed to changes in climate and land management practices to justify the need to reevaluate the accuracy of current South Dakota (SD) corn (Zea mays L.) P and K fertilizer recommendations. Also, an increase in soil health understanding has created the potential for soil health measurements to be used to improve the accuracy of these recommendations. The objectives for this study were to 1) evaluate the current P and K critical values and 2) determine the effect of including soil health indicators on improving fertilizer recommendation accuracy. This project was conducted throughout central and eastern SD from 2019-2021 …


Effects Of Conservation Management Practices On Soil Health And Crop Yields In Eastern South Dakota, Alex Mclain Jan 2022

Effects Of Conservation Management Practices On Soil Health And Crop Yields In Eastern South Dakota, Alex Mclain

Electronic Theses and Dissertations

Conservation management practice adoption on agricultural land has increased in recent years due to increasing public and private investment. The anticipated impact of increasing conservation management practice adoption are reduced greenhouse gas emissions and improved soil, water, and air quality. Understanding how these conservation management practices affect agricultural producers economically is vital to properly incentivize these practices. The existing literature on how conservation management practices affect soil health and crop yields is mixed and generally has been conducted on experimental research stations. These studies may not fully account for the on-farm effects of conservation management practices. The objectives of this …


Totally Multicolored Rado Numbers For The Equation X_1 + X_2 + X_3 + ... + X_(M−1) = X_M, Skylar Halverson Jan 2022

Totally Multicolored Rado Numbers For The Equation X_1 + X_2 + X_3 + ... + X_(M−1) = X_M, Skylar Halverson

Electronic Theses and Dissertations

A set is called Totally Multicolored (TMC) if no elements in the set are colored the same. For all natural numbers t, m, let R(t, m) be the least natural number n such that for every t-coloring of the set {1, 2, 3, ..., R(t, m)} there exist a solution set {x_1, x_2, . . ., x_m} to L(m), x_1 + x_2 + x_3 + ... + x_(m−1) = x_m such that x_i does not equal x_j for all i that does not equal j, that avoids being Totally Multicolored. This paper shows a function to find R(t,m) for any …


Using Deep Neural Networks To Analyze Precision Agriculture Data, Stephanie Liebl Jan 2022

Using Deep Neural Networks To Analyze Precision Agriculture Data, Stephanie Liebl

Electronic Theses and Dissertations

As the population of the Earth increases, there is a growing need for food to feed the inhabitants. Precision agriculture offers techniques and tools that can be used to help accommodate the growing population. One specific precision agriculture tool is remote sensing data, which can be used to image fields as an effort to better predict or understand the crops. In this thesis, deep neural networks are used to evaluate various spatial, spectral, and temporal resolutions of three different satellite images to determine which best predicts corn yield. The main metrics we used to evaluate the models were R-squared (R2), …


Eastern Redcedar (Juniperus Virginiana L.) Encroachment On South-Central South Dakota Rangelands: Impact On Plant Communities, Austin K. Domeier Jan 2022

Eastern Redcedar (Juniperus Virginiana L.) Encroachment On South-Central South Dakota Rangelands: Impact On Plant Communities, Austin K. Domeier

Electronic Theses and Dissertations

Grasslands historically covered 46 million km2 of Earth’s surface representing nearly 42% of the living vegetation. Encroachment of woody species onto grasslands and savannas is a widely researched global phenomenon, with eastern redcedar (ERC) (Juniperus virginiana L.) trees being the most prominent woody encroacher in the Northern Great Plains (NGP) due to the lack of prescribed fire and planted ERC escaping from shelterbelts. This encroachment poses a threat to native plant communities in terms of their reproduction, regeneration, and diversity. ERC are fierce competitors and can establish in most soil types, are drought tolerant, and prolific seed reproducers. These qualities …


Application Of Pork Checkoff We Care Sustainability Principles To Pork Production: Water, Nutrition, And Biosecurity, Hannah Miller Jan 2022

Application Of Pork Checkoff We Care Sustainability Principles To Pork Production: Water, Nutrition, And Biosecurity, Hannah Miller

Electronic Theses and Dissertations

The Pork Checkoff program was founded in 1986 as a means to strengthen U.S. pork in the market place (Pork Checkoff). Under this program all U.S. pork producers and importers pay $0.40 for every $100 worth of pigs is sold (Pork Checkoff). Funds are then used for pork promotion, research, and education for producers and consumers (Pork Checkoff). The Pork Checkoff program uses the We Care ethical principles as a means to address “continuous improvement in the pork industry’s production practices and promote a strong record of responsible farming to those outside of the industry” (National Pork Board, 2018a). The …


Evaluating Avian Use Of Cover Crops In The Corn Belt, Megan Figura Jan 2022

Evaluating Avian Use Of Cover Crops In The Corn Belt, Megan Figura

Electronic Theses and Dissertations

The tallgrass prairie of North America has changed drastically since colonial settlement, with up to 99% of this region converted for agriculture and other land-uses. Concurrent with grassland conversion, grassland birds have experienced the most extreme, consistent, and widespread population declines of any avian guild. Agricultural lands in the U.S. Midwest were able to provide adequate habitat for several bird species until the 1950’s; however, altered and intensified management practices have degraded much of remaining suitable habitat and undermined ecosystem functions. Consequently, many grassland birds have been identified as Species of Greatest Conservation Need (SGCN) in many State Wildlife Action …


Pathogen Prevalence In Domestic Sheep In Western Nebraska: Implications For Bighorn Sheep Conservation And Coexistence On A Multi-Use Landscape, Kaytlin Bohr Jan 2022

Pathogen Prevalence In Domestic Sheep In Western Nebraska: Implications For Bighorn Sheep Conservation And Coexistence On A Multi-Use Landscape, Kaytlin Bohr

Electronic Theses and Dissertations

Bighorn sheep (Ovis canadensis) and domestic sheep (Ovis aries) are members of the same genus and thus share multiple pathogens that can be spread between them. One specific respiratory pathogen of concern is Mycoplasma ovipneumoniae (M. ovipneumoniae), which has been linked to pneumonia epizootics in bighorn sheep that are often characterized by all age die offs upon initial exposure followed by years of low lamb recruitment. Domestic sheep have been identified as one carrier of M. ovipneumoniae with transmission between sheep species occurring when there is close contact on the landscape. To prevent this cross-species transmission, importance has been placed …


Students’ Perceptions Of Specific Laboratory Curricula On The Learning Experience In Chemistry Courses, Arwa Ali Alshehri Jan 2022

Students’ Perceptions Of Specific Laboratory Curricula On The Learning Experience In Chemistry Courses, Arwa Ali Alshehri

Electronic Theses and Dissertations

Laboratory courses play a key role in developing critical thinking and problem-solving skills and providing experience in certain aspects of a laboratory setting including reactions, materials, and equipment. Prior studies suggest that a laboratory course assists students toward cognitive gain on lecture content. In contrast, other studies conclude that laboratory is uncorrelated with cognitive gain on lecture content. Thus, a discord exists between researchers regarding the role that laboratory experiences play in furthering the understanding of chemistry concepts taught in lectures. The purpose of this research is to examine the impact of two different laboratory curricula on students’ performance in …


Post-Fledging Habitat Selection And Movements Of Juvenile Mallards In The Prairie Pothole Region, Cynthia E. Anchor Jan 2022

Post-Fledging Habitat Selection And Movements Of Juvenile Mallards In The Prairie Pothole Region, Cynthia E. Anchor

Electronic Theses and Dissertations

The Prairie Pothole Region (PPR) of North America provides critical habitat for waterfowl across life stages, but anthropogenic changes to the landscape have negatively impacted habitat quality for waterfowl. The mallard (Anas platyrhynchos) is abundant and socioeconomically valuable in the PPR, as it is a preferred target species of waterfowl hunters. Extensive research has evaluated breeding ecology of mallards in the PPR, but the period between juvenile mallards fledging and migrating has rarely been studied. The post-fledging ecology of juvenile mallards is a vital consideration for comprehensive waterfowl management. Further, juvenile mallards are a significant portion of hunter harvest at …


Northern Great Plains Saline Sodic Soil Development, Classification, Remediation, And Management., Shaina Westhoff Jan 2022

Northern Great Plains Saline Sodic Soil Development, Classification, Remediation, And Management., Shaina Westhoff

Electronic Theses and Dissertations

Soil salinity and sodicity are issues of growing concern in the United States (U.S.) and globally. Knowledge gaps for glaciated, dryland salt-affected soils exist because much original salinity and sodicity research focused on irrigated systems. Land managers are being asked to produce food, feed, fiber, and fuel for an expanding global population. The number of land managers and crop advisors who are affected by these soils is increasing. Addressing salinity and sodicity knowledge gaps will be critical for their success. Salinity and sodicity have been impeding crop productivity since the advent of cultivation. Saline and sodic soils form via multiple …


Sentiment Without Sentiment Analysis: Using The Recommendation Outcome Of Steam Game Reviews As Sentiment Predictor, Anqi Zhang Jan 2022

Sentiment Without Sentiment Analysis: Using The Recommendation Outcome Of Steam Game Reviews As Sentiment Predictor, Anqi Zhang

Electronic Theses and Dissertations

This paper presents and explores a novel way to determine the sentiment of a Steam game review based on the predicted recommendation of the review, testing different regression models on a combination of Term Frequency-Inverse Document Frequency (TF-IDF) and Latent Dirichlet Allocation (LDA) features. A dataset of Steam game reviews extracted from the Programming games genre consisting of 21 games along with other significant features such as the number of helpful likes on the recommendation, number of hours played, and others. Based on the features, they are grouped into three datasets: 1) either having keyword features only, 2) keyword features …


Development Of A Chromatographic Method To Authenticate Aspirin Brands, Megan Guetzloff Jan 2022

Development Of A Chromatographic Method To Authenticate Aspirin Brands, Megan Guetzloff

Electronic Theses and Dissertations

Counterfeit pharmaceuticals pose a threat to society that can include inaccurate amounts of the active pharmaceutical ingredient (API), no API, or containing off-target compounds. For example, there are many recent examples of counterfeit pharmaceuticals containing potentially lethal doses (> 2 mg) of fentanyl (i.e., a synthetic opioid). Current measures to combat illicit pharmaceuticals (e.g., unique packaging and product serialization) have merit, however with evolved technologies, counterfeiters can relatively easily simulate these measures and continue to distribute illicit pharmaceuticals. The only accurate way to definitively determine that a suspected counterfeit is, in fact, counterfeit is advanced chemical analysis. However, current methods …


Regenerative Agriculture Effects On Invertebrate And Bird Communities And Insect-Provided Ecosystem Services, Alex Michels Jan 2022

Regenerative Agriculture Effects On Invertebrate And Bird Communities And Insect-Provided Ecosystem Services, Alex Michels

Electronic Theses and Dissertations

Conventional agricultural practices can have unintended consequences on the environment and wildlife. Insects and birds are declining at rapid rates around the world, and the current conventional agricultural paradigm is a major driver through habitat loss and the intensification of production. Invertebrates in agroecosystems provide services to both farmers and the rest of society. Regenerative systems may promote the functioning of an agroecosystem by influencing invertebrate abundance, diversity, and ecosystem services and mitigate bird and insect declines through conservation practices that increase soil health, reduce disturbances, and increase biological diversity. Here I address knowledge gaps of the effects of regenerative …


Using Long Short-Term Memory Networks To Make And Train Neural Network Based Pseudo Random Number Generator, Aditya Harshvardhan Jan 2022

Using Long Short-Term Memory Networks To Make And Train Neural Network Based Pseudo Random Number Generator, Aditya Harshvardhan

Electronic Theses and Dissertations

Neural Networks have been used in many decision-making models and been employed in computer vision, and natural language processing. Several works have also used Neural Networks for developing Pseudo-Random Number Generators [2, 4, 5, 7, 8]. However, despite great performance in the National Institute of Standards and Technology (NIST) statistical test suite for randomness, they fail to discuss how the complexity of a neural network affects such statistical results. This work introduces: 1) a series of new Long Short- Term Memory Network (LSTM) based and Fully Connected Neural Network (FCNN – baseline [2] + variations) Pseudo Random Number Generators (PRNG) …


Soil Hydro-Physical Properties, Computed Tomography Measured Pore Parameters, And Soil Health Indicators As Influenced By Tillage And Crop Rotation Systems, Goutham Thotakuri Jan 2022

Soil Hydro-Physical Properties, Computed Tomography Measured Pore Parameters, And Soil Health Indicators As Influenced By Tillage And Crop Rotation Systems, Goutham Thotakuri

Electronic Theses and Dissertations

Long-term tillage and crop rotation systems are important agricultural management practices as these can have direct impact on the soil’s key properties. The objectives of this study were to (ⅰ) quantify the soil pore characteristics under long-term tillage and crop rotation using X-ray computed tomography (XCT) and to assess the relationships between XCT-measured pore parameters and soil hydro-physical properties; and (ⅱ) evaluate the impacts of long-term tillage and crop rotation on select soil health indicators. The objective (ⅰ) was carried out at Haskell Agricultural Laboratory (HAL), Concord, NE; and objective (ⅰi) was carried out at South Central Agricultural Laboratory (SCAL), …


Response Of Soil Biochemical And Physical Properties To Long Term Prairie Cordgrass And Kura Clover Intercropping System, Vaishnavi Varikuti Jan 2022

Response Of Soil Biochemical And Physical Properties To Long Term Prairie Cordgrass And Kura Clover Intercropping System, Vaishnavi Varikuti

Electronic Theses and Dissertations

Prairie cordgrass (Spartina pectinata) (PCG) is a warm-season perennial grass that can be used as a biofuel feedstock and can be grown on marginal lands. Previous studies on intercropping of a perennial legume i.e., kura clover (Trifolium ambiguum) (KC) with PCG can improve soil biochemical properties, increase biomass production, mitigate greenhouse gas (GHG) emissions while reducing the chemical fertilizer requirement. However, there is a lack of evidence about the effects of PCG production on soil biochemical and physical properties during the cropping season and at deeper soil depths in reference to support plant growth, environmental implications and enhance the soil …


It's Not Just No-Till: Crop Rotations Are Key To Improving Soil Quality And Grain Yields At Dakota Lakes Research Farm, Natalie Sturm Jan 2022

It's Not Just No-Till: Crop Rotations Are Key To Improving Soil Quality And Grain Yields At Dakota Lakes Research Farm, Natalie Sturm

Electronic Theses and Dissertations

No-till is increasingly promoted as a vital agricultural practice to address the challenge of improving soil quality while maintaining the ability to produce food, feed, fuel, and fiber. However, questions remain regarding 1) how different crop rotations impact soil quality under no-till management specifically and 2) whether significant improvements in soil quality can be made without negatively impacted crop yields. In this study, we demonstrate that even under the same long-term no-till management, differences in grain yields and soil biological, chemical, and physical properties exist between crop rotations at Dakota Lakes Research Farm in central South Dakota. We propose that …


A Post-Pneumonia Epizootic Evaluation Of The Rapid City, South Dakota Bighorn Sheep Herd, Amanda N. Ensrud Jan 2022

A Post-Pneumonia Epizootic Evaluation Of The Rapid City, South Dakota Bighorn Sheep Herd, Amanda N. Ensrud

Electronic Theses and Dissertations

Pneumonia is a major factor affecting populations of free-ranging bighorn sheep (Ovis canadensis) across western North America. Pneumonia can occur in large-scale epizootics, during which greater than half of the population typically dies. After these epizootics, surviving ewes continue to conceive and bear lambs. However, lamb recruitment may remain low due to periodic or annual pneumonia outbreaks causing high lamb mortality rates, sometimes greater than 90%. Our study focused on the Rapid City, South Dakota bighorn sheep (BHS) herd that has recorded pneumonia-induced population decline since 2009. The first objective was to improve lamb health and survival by identifying and …


Targeted Browsing With Goats For Eastern Redcedar (Juniperus Virginiana L.) Control, Alanna M. Hartsfield Jan 2022

Targeted Browsing With Goats For Eastern Redcedar (Juniperus Virginiana L.) Control, Alanna M. Hartsfield

Electronic Theses and Dissertations

As eastern redcedar (ERC) (Juniperus virginiana L.) grassland encroachment progresses, all potential control methods should be explored in the interest of Great Plains grassland health and longevity. Targeted browsing with goats has been proven as an effective control method on some juniper species; however, little is known about its ability to control ERC. These studies intend to mend knowledge gaps of how targeted browsing with goats control ERC by causing tree death without chemicals or machinery. The first study is two 3x3 Latin squares comparing protein-supplemented diets. The second study is a randomized complete block design of five 0.224 ha …


The Efficacy Of The South Dakota State University Summer Jacks Leap Program, Tessa M. Sundermann Jan 2022

The Efficacy Of The South Dakota State University Summer Jacks Leap Program, Tessa M. Sundermann

Electronic Theses and Dissertations

Today, several studies detail the continuing struggle many students have with college mathematics courses at universities across the United States. The South Dakota State University Summer Jacks LeaP program is a summer bridge mathematics program aimed at improving incoming students’ mathematics success. This analysis used a mixed methods research design to examine the efficacy of the Summer Jacks LeaP program. First, we analyzed the LeaP students’ homework averages, exam 1 scores, final exam scores, and overall grade scores to determine if they were finding success in their fall semester mathematics courses. We also used hypothesis testing to compare LeaP participants …


Fire Emissions In The Tropical Indonesia: Improved Estimation And Driving Forces Investigation, Xiaoman Lu Jan 2022

Fire Emissions In The Tropical Indonesia: Improved Estimation And Driving Forces Investigation, Xiaoman Lu

Electronic Theses and Dissertations

Indonesia has experienced frequent fires since the 1970s due to large-scale peatland conversion and extensive drainage for agricultural development. Fire emissions released from these fires have led to Indonesia being the world’s 3rd largest emitter of greenhouse gases in certain years. Given that fire emissions severely affect climate, weather, and the human environment, numerous approaches have been developed to estimate fire emissions. However, existing emission estimates differ largely by a factor of four in this tropical country because of frequent cloud interferences and low-temperature smoldering fires. Therefore, this dissertation aims to improve the quantification of Indonesian fire emissions through enhanced …