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The Development Of An Arsenic(V) Selective Electrode, Sandra Gee Kang

Dissertations and Theses

The object of this research was to develop an arsenic(V) selective electrode. The electrode is based on a solid state membrane prepared by pressing a precipitate of silver arsenate-silver sulfide into a pellet. After the electrode was made, experiments were designed to check for three general characteristics of the electrodes: dependence of potential on pH for constant arsenic(V) concentration; dependence of potential on arsenic(V) concentrations at constant pH and extent of interference due to phosphate and arsenic(III) ions. From these measurements, it was found that Ag₂HAs0₄ was formed originally in the membranes containing a small fraction of …

Characterization Of Zinc-Containing Metalloproteins By Resonance Raman Spectroscopy, Robert Edward Derry

Dissertations and Theses

Cobalt-substituted carboxypeptidase and carbonic anhydrase were chosen as candidates for resonance Raman spectroscopy because they possess visible absorption due to the Co(II)-protein complex. However, no evidence for resonance-enhanced peaks due to the cobalt-containing chromophore was found with laser excitation near the visible absorption bands (514.5 nm) or closer to the ultraviolet absorption bands (457.9nm).

Arsanilazocarboxypeptidase and model azotyrosine compounds were selected for a Raman spectroscopic investigation because they have intense absorption bands in the visible region. All of these substances yielded similar resonance Raman spectra. Although there was no evidence for specific zinc-ligand vibrations, shifts in vibrational frequencies of the …

Alumina-Catalyzed Cope Rearrangement, Paul Jhy-Shing Wang

Dissertations and Theses

The alumina-catalyzed Cope rearrangements of meso- and dl-3,4-diphenylhexa-1,5-diene were examined in detail, following up a preliminary observation by H. Berg at Portland State University. Commercial column-chromatography grade alumina was employed, and was further activated before use by heating at 650-700° for four hours.

Using a ratio of 20 mg of dl-3,4-diphenylhex-l,5-diene to 1 g of alumina in heptane, the Cope rearrangement was complete within 15 minutes at room temperature to give exclusively trans,trans-1,6-diphenylhexa-1,5-diene. This was identified.by melting point, infrared spectroscopy and vapor phase chromatography.

The catalyzed rearrangement of meso-3,4-diphenylhexa-l,5-diene was run using the same diene …

The Effects Of Pentachlorophenol On The Electrical Conductivity Of Lipid Bilayer Membranes, William Harvey Perman

Dissertations and Theses

The effects of pentachlorophenol (PCP), a widely used pesticide, on the electrical characteristics of lipid bilayer membranes has been studied. When a small amount of PCP (even at a concentration of a few micromoles per liter) is present in the electrolytic solution surrounding the membrane, the electrical conductivity of the membrane significantly increases. The present work was concerned with detailed measurements of the changes in the conductivity caused by PCP under chemically controlled conditions. The experimental results were analyzed to determine the permanent species in the membrane, and an attempt was made to correlate the data with existing models of …

Probability Driven Heuristic Nets, Lynn Robert Carter

Dissertations and Theses

Let a probability driven switch be defined as a switch of three input paths and three output paths. The status of the input paths defines a probability for each output path (as to whether it will generate a signal or not.) One output path is linked to one input path, so the results of the switch at time t can affect the switch at time t+1. A switch so constructed can be defined (by the probabilities) to take on the function of the standard logic gates (AND, OR, …) A net constructed of these switches can be “taught” by …

Water Quality Within East Portland Terraces, Fouad Mohamed Tawfik

Dissertations and Theses

Groundwater from thirty-three wells which are randomly distributed within 42 square miles of the residential, agricultural and industrial area of East Portland Terraces have been analyzed. The area is moderately wet with an annual precipitation of about 37 inches. Residual and transported sediments from different sources, dominantly volcanic, comprise the subsurface lithology. The sedimentary units that were deposited by means of rivers and lakes have filled an original structural and erosional valley in the area. This relatively unconsolidated valley filling is about 900 feet of predominantly lenticular, stratified and cross-bedded lenses of clay, silt, sand, gravel, cobbles and boulders.

The …

Vibration Damping Characteristics Of Typical Harpsichord Strings, Jack Lee Simmons

Dissertations and Theses

Present-day builders of harpsichords disagree as to the use of iron or carbon-steel wire in their attempt to duplicate the tonal qualities of the early 16th century instruments. The variations in tone produced by vibrating iron and steel wires may be due, at least in part, to differences in their decay characteristics. A wire was set into vibration by placing a section in a magnetic field and passing a variable-frequency alternating current through it. A condition of resonance was established by appropriately selecting frequencies, lengths, and tensions that would simultaneously satisfy the relationship: fr = n/2L(T/p)1/2. Then measurements of decay …

A Mineralogical And Geochemical Study Of The Ferruginous Bauxite Deposits In Columbia County, Oregon, And Wahkiakum County, Washington, Ronald Laverne Jackson

Dissertations and Theses

Wet chemical analysis and instrumental neutron activation analysis (INAA) were performed on a suite of samples from three residual ferruginous bauxite profiles in the study area for abundances of Al₂O₃,

SiO₂, Fe₂O₃, Ti O₂, Na, Sc, Hf, Cr, Co, La, Sm, Yb, Lu, and Th. In addition a mineralogical study accompanied this research, using petrographic, differential thermal, and x-ray diffraction techniques. In each profile, the relative mobility of these elements were calculated by empirical methods for comparison with the parent rock and mineral properties in the saprolite.

This …

The Recognition, Investigation, Interpretation, And Treatment Of Landslides In The Pacific Northwest, Harry Ludowise

Dissertations and Theses

Certain features unique to the Pacific Northwest influence landsliding in this region. Weakly consolidated sediments, dense vegetation and seasonally concentrated rainfall all contribute to the distinctive conditions that are encountered here.

This study gathers together information applying to the recognition and correction of Pacific Northwest landslides. Treatment practices common to this region are discussed.

A large slide located about 30 miles east of Portland, Oregon along the Clackamas River is used as an example. Exploration, instrumentation, analysis and corrective measures are illustrated.

A Phytochemical Investigation Of Liverwort Frullania Franciscana Howe, Timothy Ta-E Huang

Dissertations and Theses

Liverwort Frullania franciscana Howe was found high on the allergic test scale by J. Mitchell of the Medical School of the University of British Columbia and co-workers. Frullanolide was isolated from Frullania tamarisci by J.D. Connoly and by G. Oisson and his co-workers.

The plant sample, collected in Oregon, was hand separated, confirmed, air dried and milled before the extractions were done. A Soxhlet extraction with ether and cold extractions with n-hexane and with ether were carried out. Ether is a better extraction solvent than n-hexane for cold extraction.

Column chromatography was used for the separation of the extract based …

Biostratigraphy Of The Type Yamhill Formation, Polk County, Oregon, Larry R. Gaston

Dissertations and Theses

One hundred and seventy-four species and varieties of fossil Foraminifera are recorded from thirty-eight localities in the Siletz River Volcanics, Yamhill and Nestucca Formations exposed along Mill and Gooseneck Creeks, in the Northern Coast Range of Oregon. Marginulina holmesi is described as new. The Foraminifera indicate that this sequence was deposited during late Ulatisian and Narizian time, in marine waters at bathyal or lower neritic depths, with cool surface temperatures. The Yamhill Formation can be correlated with Moody Shale member of the Toledo Formation and the Coaledo Formation of Oregon; the McIntosh and Aldwell Formations of Washington; and the upper …

Heat Transfer Across Carbon-Liquid Helium I Interface, Constantine Antonopoulos

Dissertations and Theses

The subject to be discussed in this thesis is an experimental problem in heat transfer across a carbon-liquid helium I interface. The interest in this particular problem arose from experimental work first presented by Luce (1) concerning a similar heat transfer problem from a heated bismuth surface immersed in liquid helium. This study produced some interesting results which it was hoped could be duplicated with carbon. The choice of carbon as an alternative material was based on reasons which will be discussed later. Before beginning a detailed discussion of the problem a history of its development and the results which …