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Clemson University

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Biodiesel

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Improved Oxidative Stability In Biodiesel Via Commercially-Viable Processing Strategies, Gregory Lepak May 2014

Improved Oxidative Stability In Biodiesel Via Commercially-Viable Processing Strategies, Gregory Lepak

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Biodiesel made from waste cooking oil (WCO) frequently requires antioxidants to meet oxidation stability specifications set forth in ASTM D6751 or EN 14214. In contrast, unrefined cottonseed oil (CSO), containing tocopherols and high concentrations of gossypol, a toxic polyphenolic antioxidant, is unique for biodiesel processing because it produces biodiesel resulting in higher oxidation stability. During biodiesel production, however, only a portion of these endogenous natural antioxidants are suspected to be retained. Because the economics of biodiesel manufacturing rely upon inexpensive sources of triglycerides, emphasis was placed upon developing improved alternative commercially-viable processing strategies where WCO is the main source of …


Biodiesel Production Using Chemical And Enzymatic Catalysts And Improvement Of Cold Flow Properties Using Additives, Hem Joshi May 2011

Biodiesel Production Using Chemical And Enzymatic Catalysts And Improvement Of Cold Flow Properties Using Additives, Hem Joshi

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Biodiesel production was carried out from soybean, canola and cottonseed oils along with poultry fat using catalytic potassium hydroxide. Further, the physical properties of biodiesel were studied with addition of ethyl levulinate (ethyl 4-oxopentanoate), short-chain alcohols (ethanol, isopropanol and butanol), and commercial cold flow improver (CFI) additives. The effects of adding ethyl levulinate, short-chain alcohols, and commercial additives were determined by studying their influence on the acid value (AV), cloud point (CP), pour point (PP), cold filter plugging point (CFPP), induction period (IP), kinematic viscosity (KV) and the flash point (FP). The results showed improved low temperature properties of the …