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Oceanography and Atmospheric Sciences and Meteorology

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Earth Sciences

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2006

Articles 1 - 2 of 2

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In Situ Evidence For Renitrification In The Arctic Lower Stratosphere During The Polar Aura Validation Experiment (Pave), Jack E. Dibb, Eric Scheuer, Melody A. Avery, G W. Sachse Jun 2006

In Situ Evidence For Renitrification In The Arctic Lower Stratosphere During The Polar Aura Validation Experiment (Pave), Jack E. Dibb, Eric Scheuer, Melody A. Avery, G W. Sachse

Earth Sciences

In-situ measurements of nitric acid (HNO3), ozone (O3), and nitrous oxide (N2O) were made from the NASA DC-8 during the Polar Aura Validation Experiment in January/February 2005. In the lower stratosphere (9–12.5 km, potential temperature 300–350 K) characteristic compact relationships were observed between all three gases. The ratio HNO3/O3 averaged 3.5 (±0.7) ppt/ppb. Samples with enhanced HNO3/O3 (>4.0) were most abundant under the edge of the Arctic Polar vortex in airmasses with enhanced mixing ratios of both gases (>400 ppb O3 and >2000 ppt HNO …


Observations Of Hono By Laser-Induced Fluorescence At The South Pole During Antci 2003, W Liao, A T. Case, J Mastromarino, D Tan, Jack E. Dibb May 2006

Observations Of Hono By Laser-Induced Fluorescence At The South Pole During Antci 2003, W Liao, A T. Case, J Mastromarino, D Tan, Jack E. Dibb

Earth Sciences

Observations of nitrous acid (HONO) by laser-induced fluorescence (LIF) at the South Pole taken during the Antarctic Troposphere Chemistry Investigation (ANTCI), which took place over the time period of Nov. 15, 2003 to Jan. 4, 2004, are presented here. The median observed mixing ratio of HONO 10 m above the snow was 5.8 pptv (mean value 6.3 pptv) with a maximum of 18.2 pptv on Nov 30th, Dec 1st, 3rd, 15th, 17th, 21st, 22nd, 25th, 27th and 28th. The measurement uncertainty is ±35%. The LIF HONO observations are compared to concurrent HONO observations performed by mist chamber/ion chromatography (MC/IC). The …