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Micro Modeling Study Of Cathode/Electrolyte Interfacial Stresses For Solid Oxide Fuel Cells, Xinfang Jin, Xingjian Xue
Micro Modeling Study Of Cathode/Electrolyte Interfacial Stresses For Solid Oxide Fuel Cells, Xinfang Jin, Xingjian Xue
Faculty Publications
Delamination of the cathode/electrolyte interface is an important degradation phenomenon in solid oxide fuel cells (SOFCs). While the thermal stress has been widely recognized as one of the major reasons for such delamination failures, the role of chemical stress does not receive too much attention. In this paper, a micro-model is developed to study the cathode/electrolyte interfacial stresses, coupling oxygen ion transport process with structural mechanics. Results indicate that the distributions of chemical stress are very complicated at the cathode/electrolyte interface and show different patterns from those of thermal stress. The maximum principal stresses take place at the cathode/electrolyte interface …
Atomic Layer Deposition On Porous Materials: Problems With Conventional Approaches To Catalyst And Fuel Cell Electrode Preparation, Tzia Ming Onn, Rainer Küngas, Paolo Fornasiero, Kevin Huang, Raymond J. Gorte
Atomic Layer Deposition On Porous Materials: Problems With Conventional Approaches To Catalyst And Fuel Cell Electrode Preparation, Tzia Ming Onn, Rainer Küngas, Paolo Fornasiero, Kevin Huang, Raymond J. Gorte
Faculty Publications
Atomic layer deposition (ALD) offers exciting possibilities for controlling the structure and composition of surfaces on the atomic scale in heterogeneous catalysts and solid oxide fuel cell (SOFC) electrodes. However, while ALD procedures and equipment are well developed for applications involving flat surfaces, the conditions required for ALD in porous materials with a large surface area need to be very different. The materials (e.g., rare earths and other functional oxides) that are of interest for catalytic applications will also be different. For flat surfaces, rapid cycling, enabled by high carrier-gas flow rates, is necessary in order to rapidly grow thicker …