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Mechanical Engineering

Mechanical Engineering Faculty Publications

2007

Proton exchange membrane (PEM); Nafion®; membrane; Humidity cycle; Mechanical response; Elasto-plasticity; Swelling anisotropy

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Mechanical Behavior Of Fuel Cell Membranes Under Humidity Cycles And Effect Of Swelling Anisotropy On The Fatigue Stresses, Ahmet Kusoglu, Anette M. Karlsson, Michael H. Santare, Simon Cleghorn, William B. Johnson Jul 2007

Mechanical Behavior Of Fuel Cell Membranes Under Humidity Cycles And Effect Of Swelling Anisotropy On The Fatigue Stresses, Ahmet Kusoglu, Anette M. Karlsson, Michael H. Santare, Simon Cleghorn, William B. Johnson

Mechanical Engineering Faculty Publications

The mechanical response of proton exchange membranes in a fuel cell assembly is investigated under humidity cycles at a constant temperature (85°C). The behavior of the membrane under hydration–dehydration cycles is simulated by imposing a humidity gradient from the cathode to the anode. Linear elastic, plastic constitutive behavior with isotropic hardening and temperature and humidity dependent material properties are utilized in the simulations for the membrane. The evolution of the stresses and plastic deformation during the humidity cycles are determined using finite element analysis for two clamping methods and various levels of swelling anisotropy. The membrane response strongly depends on …