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Increasing Power Density Of Lsgm-Based Solid Oxide Fuel Cells Using New Anode Materials, Kevin Huang, Jen-Hau Wan, John B. Goodenough

Faculty Publications

Chemical reactions between the superior perovskite oxide-ion conductor Sr- and Mg-doped LaGaO₃ (LSGM), CeO₂, and NiO have been studied by powder X-ray diffraction. The results showed that an extensive reactivity occurs as a result of La migration driven by a gradient of La chemical activity. La migration across the LSGM/electrode interfaces in a fuel cell leads to the formation of resistive phases at the interface, either LaSrGa₃O₇ or LaSrGaO₄. Use of 40 mol % La₂O₃ -doped CeO₂ as an interlayer between anode and electrolyte as well as in …