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Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya

Doctoral Dissertations

The need for alternative energy sources has led to extensive research on optimizing the conversion efficiency of thermoelectric (TE) materials. TE efficiency is governed by figure-of-merit (ZT) and it has been an enormously challenging task to increase ZT > 1 despite decades of research due to the interdependence of material properties. Most doped inorganic semiconductors have a high electrical conductivity and moderate Seebeck coefficient, but ZT is still limited by their high lattice thermal conductivity. One approach to address this problem is to decrease thermal conductivity by means of alloying and nanostructuring, another is to consider materials with an inherently low …

Development And Characterization Of Nanofiber-Based Thermoelectric And Piezoelectric Composites, Julio Enrique Trevino

Theses and Dissertations

This study focuses on the development and characterization of nanofiber-based composites with the goal of developing flexible, lightweight, and cost effective thermoelectric and piezoelectric devices. The following materials were used in the development of the composites: polyvinylidene fluoride (PVDF) with polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), polycarbazole (PCZ), polyacrylonitrile (PAN), functionalized multi-walled carbon nanotubes (MWCNT-COOH), and camphorsulfonic acid (CSA). Blends and in-situ polymerization techniques were utilized to increase the desired thermoelectric/piezoelectric response. Nanofiber systems were produced utilizing the Forcespinning® technique. The morphology, structure, electrochemical, thermal stability, thermoelectric, and piezoelectric performance was analyzed. All of the nanofiber PVDF/CP …

Exploring A Platinum Nanocatalytic Microcombustion-Thermoelectric Coupled Device, Dylan Moore Mcnally

Theses and Dissertations

This work aimed to create a first-generation power device for eventual application to portable electronics. A platinum nanoparticle catalytic substrate was employed in a microcombustion-thermoelectric coupled (MTC) device for the purpose of chemical-to-electrical energy conversion. Multiple microcombustion reactors were designed, fabricated, and investigated. Most importantly, the reactor configuration was designed to accommodate thermoelectric generators (TEGs) for power production. Temperature studies with catalytic combustion of methanol-air fuel mixtures were used to evaluate the thermal power generation performance of each reactor. The final reactor design enabled ignition at room temperature with the ability to achieve repeat catalytic cycles upon subsequent exposure to …

The Design, Fabrication, And Testing Of A Cooling Garment, Richard James Garza

Theses and Dissertations

The aim of this research is to design a device or technology capable of cooling the user – such as a college student walking to class, for example – in a manner as convenient as putting on a jacket. The idea is to use the peltier effect – a phenomenon in which two dissimilar semi-conductors heat up and cool down with the application of an electric current – as the source of heat absorption used to cool the user. In this research it will be determined whether or not it is feasible to use such a phenomenon to keep the …

Doping With Rare Earth Elements And Resultant Nano-Inclusions On The Electrical And Thermal Properties Of The Mis-Fit Layered Thermoelectric Oxide, Geoffroy Gauneau

Graduate Theses, Dissertations, and Problem Reports

Thermoelectric generators produce electricity by directly converting temperature differences into electrical energy through Seebeck effect. Thermoelectric generators possess many unique features, such as having no moving part and being very reliable with a relatively long lifespan once built. They are solid-state waste heat harvesters. With various waste heat available throughout many industries, thermoelectric generators could offer economically competitive renewable energy. The current state of the art thermoelectric materials includes materials with relatively toxic elements and must work under vacuum, making them quite expensive to produce. Among the various thermoelectric materials, ceramic oxides have been proved to be more chemically stable …

A Study Of Catalytic Microcombustion For A Portable Power Supply Device, Bhanuprakash Reddy Guggilla

Theses and Dissertations

The essential need for portable and dense power sources has been greatly increased with the prevalence of portable electronic devices in the past decade. Catalytic combustion of hydrocarbon and oxygenated fuels has the potential to provide an alternative power source for portable electronic devices by replacing relatively today's heavy battery technology. A successful self-ignition and sustainable catalyst combustion for a variety of fuels using Platinum (Pt)-impregnated substrate was demonstrated in our previous work.

Present work explores the performance of a microcombustion thermoelectric coupled (MTC) device with improved reactor configuration design. Chemically synthesized platinum nanoparticles with particle diameters of approx. 8 …

Driver Cooling System, Joseph Fatin Bolous, Jake Donald Deboer, Alvin Theodore Lau

Mechanical Engineering

This document provides our Final Design Review (FDR) for the Driver Cooling System Project. It contains our background research, which includes current product research, technical research, and information on our sponsor’s needs as a customer as well our manufacturing process, test results, and final design. We created a problem statement to define the scope of the project, discuss sponsor and consumer needs and wants, and technical specifications. After brainstorming, we ultimately selected a thermoelectric cooling system (TEC) after presenting our Preliminary Design Report and Critical Design Report. We built the final prototype, as can be seen in the manufacturing plan, …

Fabrication And Thermoelectric Characterization Of Transition Metal Silicide-Based Composite Thermocouples, Gunes A. Yakaboylu, Rajalekshmi C. Pillai, Katarzyna Sabolsky, Edward M. Sabolsky

Faculty & Staff Scholarship

Metal silicide-based thermocouples were fabricated by screen printing thick films of the powder compositions onto alumina tapes followed by lamination and sintering processes. The legs of the embedded thermocouples were composed of composite compositions consisting of MoSi2, WSi2, ZrSi2, or TaSi2 with an additional 10 vol % Al2O3 to form a silicide–oxide composite. The structural and high-temperature thermoelectric properties of the composite thermocouples were examined using X-ray diffraction, scanning electron microscopy and a typical hot–cold junction measurement technique. MoSi2-Al2O3 and WSi2-Al2O3 composites exhibited higher intrinsic Seebeck coefficients (22.2–30.0 μV/K) at high-temperature gradients, which were calculated from the thermoelectric data of …

Fabrication And Thermoelectric Characterization Of Stretchable Conductive Latex-Based Composites, Cory Michael Arcovitch

Graduate College Dissertations and Theses

Miniaturized stretchable electronic devices that can be bent and strained elastically without breaking, have drawn considerable research interest in recent years for wearable computers and integrated bio-sensor applications. Portable electrical power harvesting remains a critical challenge in flexible electronics materials. One proposed solution has been to convert waste heat from the human body into electricity using thermoelectric materials. Traditionally, however, these materials are brittle ceramic semiconductors with limited fracture resistance under deformation. The primary objective of this thesis is to address this challenge by fabricating and studying the mechanical, thermal and electrical performance of stretchable composites combining natural latex polymer …

Design, Modeling And Simulation Of A Thermoelectric Cooling System (Tec), Pooja Iyer Mani

Masters Theses

Thermoelectric Devices are solid state devices which directly convert thermal energy to electrical energy and vice versa. In the recent past, a lot of effort has been made to improve the performance and also the power generated by a thermoelectric device. This is done by attaching heat sinks on either sides of the device. Optimizing heat sinks improves the overall efficiency of it but on the other hand the device also has to be optimized. TECs are mostly used for electronic cooling where the heated electronic devices serve as target that needs to be cooled while air acts as a …

Optimal Design Of Automotive Exhaust Thermoelectric Generator (Aeteg), Hassan Fagehi

Masters Theses

A consumption of energy continues to increase at an exponential rate, especially in terms of automotive spark ignitions vehicles. About 40% of the applied fuel into a vehicle is lost as waste exhaust to the environment. The desire for improved fuel efficiency by recovering the exhaust waste heat in automobiles has become an important subject. The thermoelectric generator (TEG) has the potential to convert exhaust waste heat into electricity as long as it is improving fuel economy. The remarkable amount of research being conducted on TEGs indicates that this technology will have a bright future in terms of power generation. …

Analytical Modeling And Numerical Simulation Of A Thermoelectric Generator Including Contact Resistances, Shripad Dhoopagunta

Masters Theses

With increasing demand for energy harvesting systems, research has been conducted in different areas in which Thermoelectric Generators (TEG) find their way into the top of many available resources. Out of many energy harvesting systems available, TEGs are comparatively easier to study, to manufacture and also to comprehend while producing enough energy for applications they find use in. They are solid state devices, meaning; they do not have any moving parts and hence makes them durable. Most of the energy that goes out of the automobile as exhaust is reused to power the TEGs. In most of the works that’s …

Analytical Study Of Miniature Thermoelectric Device, Mohammed Dhannoon

Masters Theses

Miniature thermoelectric devices (TE) have been regarded as hopeful devices to attain efficient cooling in microprocessors and other small-scale devices. To recognize the performances of miniature thermoelectric coolers, a thermoelectric cooling module is theoretically analyzed. Particular attention is paid to the impact of the thermoelectric element length effect and the substrate material type influence on the cooling performance. The electrical contact resistance and thermal contact are taken into account.

Furthermore, miniature thermoelectric is compared with large thermoelectric, and effective material properties of miniature thermoelectric are studied. The obtained results also demonstrate power density (cooling/heating power per unit area of the …

Prosthetic Socket Cooling System, Benjamin K. Kraw, Kathy Ha, Derek Piastrelli, Cuong Lai

Mechanical Engineering

A team of four senior-level undergraduate students in the Interdisciplinary Senior Project Design course in the Engineering Department of California Polytechnic State University: San Luis Obispo have worked to develop a prosthetic socket cooling system, namely for veteran Taylor Morris and exclusively for a transfemoral prosthetic socket, under the Quality of Life+ Laboratory. This cooling system will utilize the thermoelectric effect known as the Peltier effect to transmit heat generated from the residual limb to the surrounding environment by means of forced convection over small aluminum heat sinks. Two measurement devices have also been developed to, one, measure the heat …

Simulation And Analysis Of An Integrated Device To Simultaneously Characterize Thermal And Thermoelectric Properties, Collier Miers, Amy Marconnet

International Thermal Conductivity Conference (ITCC) and the International Thermal Expansion Symposium (ITES)

For many applications, multiple material properties impact device performance and characterization of multiple properties using a single sample is desirable. In this article, the authors focus on thermoelectric materials characterization, which requires the thermal conductivity, electrical conductivity, and Seebeck coefficient to be quantified. Specifically, the authors present a design analysis using numerical COMSOL simulations of the 3w technique to optimize a measurement structure for thermoelectric films while also including the capability for electrical measurements to be performed on the same sample without detachment or repositioning. Thermal optimization of the structure is achieved through investigation of temperature spatial uniformity, the …

Role Of Thermal Conductivity For Thermoelectrics With Finite Contacts, Yee Rui Koh, Kazuaki Yazawa, Ali Shakouri

International Thermal Conductivity Conference (ITCC) and the International Thermal Expansion Symposium (ITES)

The role of thermal conductivity in the performance of thermoelectric (TE) devices as compared to other material properties such as Seebeck coefficient and the electrical conductivity will be discussed. A TE energy conversion system that includes thermal contacts for the hot side and the cold side with finite heat transfer performances is considered. Some of the trends in electronics cooling applications have been described. In this article, the effect of material properties as a function of energy current flow direction will be focused.

TEs have an advantage as solid-state heat energy conversion devices especially for applications with spatial constraints. A …

Design And Construction Of A Chemical Engineering (Cheme) Car Using Thermoelectrics, Timothy Barnhill, Sara Davino, Spencer Faltin, Lauryn Jamison, Christina Papadimitrio, Mccall Rogers

Senior Theses

Six chemical engineering undergraduates at the University of South Carolina formed a team to compete in the 2014 AIChE Chem-E-Car competition at the Southern Regional Student Conference in San Juan, Puerto Rico, in March. In the Chem-E-Car competition, students must design and build a vehicle powered by an unconventional form of chemical energy to carry a specified weight over a given distance (1). The group used knowledge gained through undergraduate study to construct a small-scale vehicle that is powered by a set of thermoelectric generators utilizing a heat gradient between boiling water and an ethanol-dry ice mixture (2). An iodine …

Analytical Performance Evaluation Of Thermoelectric Modules Using Effective Material Properties, Sean Lwe Leslie Weera

Masters Theses

Designers often face the predicament of non-standardized forms of performance data provided by thermoelectric module manufacturers. Other than experimental means the only method to evaluate the performance of a product would be through analytical modeling using material properties that are usually undisclosed and unknown. This work studies the theoretical approach of obtaining such material properties using the maximum operating parameters reported by the manufacturers. These values are then analytically employed to evaluate the performances of these thermoelectric modules. Experimental means are also devised and carried out on these test samples to validate the integrity of the results. Three-way comparisons between …

Studies On Structure And Property Of Polymer-Based Nano-Composite Materials, Yun Zhai

University of New Orleans Theses and Dissertations

The mixing of polymers and nanoparticles makes it possible to give advantageous macroscopic material performance by tailoring the microstructure of composites. In this thesis, five combinations of nano inclusion and polymer matrix have been investigated.

The first type of composites is titanium dioxide/ polyaniline combination. The effects of 4 different doping-acids on the microstructure, morphology, thermal stability and thermoelectric properties were discussed, showing that the sample with HCl and sulfosalicylic dual acids gave a better thermoelectric property. The second combination is titanium dioxide/polystyrene composite. Avrami equation was used to investigate the crystallization process. The best fit of the mass derivative …

Novel Automotive Waste Heat Recovery Techniques, John Randall Armstead

Dissertations, Master's Theses and Master's Reports - Open

The United States transportation industry is predicted to consume approximately 13 million barrels of liquid fuel per day by 2025. If one percent of the fuel energy were salvaged through waste heat recovery, there would be a reduction of 130 thousand barrels of liquid fuel per day. This dissertation focuses on automotive waste heat recovery techniques with an emphasis on two novel techniques.

The first technique investigated was a combination coolant and exhaust-based Rankine cycle system, which utilized a patented piston-in-piston engine technology. The research scope included a simulation of the maximum mass flow rate of steam (700 K and …

Analytical Modeling And Optimization Of A Thermoelectric Heat Conversion System Operating Betweeen Fluid Streams, Stephen H. Taylor

Theses and Dissertations

Analytical, closed-form solutions governing thermoelectric behavior are derived. An analytical model utilizing a thermal circuit is presented involving heat transfer into, through, out of, and around a thermoelectric device. A nondimensionalization of the model is presented. Linear heat transfer theory is applied to the model to obtain a series of closed form equations predicting net power output for the thermoelectric device. Fluid streams flowing through shrouded heat sinks with square pin fins are considered for the thermal pathways to and from the device. Heat transfer and pressure drop are characterized in a manner conducive to an analytical model using previously …

Self Assembly In Additive Manufacturing: Opportunities And Obstacles, Nathan B. Crane, J. Tuckerman, G. N. Nielson

Faculty Publications

Purpose

Additive manufacturing offers substantial flexibility in shape, but much less flexibility in materials and functionality—particularly at small size scales. A system for automatically incorporating microscale components would enable the fabrication of objects with more functionality. This paper considers the potential of self assembly to serve as an automated programmable integration method. In particular, it addresses the ability of random self assembly processes to successfully assemble objects with high performance despite the possibility of assembly errors.

Methodology

A self-assembled thermoelectric system is taken as a sample system. The performance expectations for these systems are then predicted using modified one-dimensional models …

Design Of A Microfabricated Device For Ligase Detection Reaction (Ldr), Dwhyte Omar Barrett

LSU Master's Theses

The Ligase Detection Reaction (LDR) is a mutation detection technique used to identify point mutations in deoxyribonucleic acid (DNA). Developed by Francis Barany and associates at Cornell University it is used to find specific low abundant point mutations that may lead to colorectal cancer in the early stages of disease development. The research objective was to design and manufacture a microscale Ligase Detection Reaction (LDR) device in polycarbonate. The LDR module will be incorporated with other microdevices such as: Continuous Flow Polymerase Chain Reaction (CFRCR) and Capillary Electrophoresis (CE) in modular lab-on-a-chip technology. In making the microdevice, the duration of …