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Interfacial Bonding Between Thermoset And Thermoplastic Polyurethane Reinforced Textile Grade Carbon Fiber: Structure Property Relationships, Surbhi Subhash Kore Dec 2021

Interfacial Bonding Between Thermoset And Thermoplastic Polyurethane Reinforced Textile Grade Carbon Fiber: Structure Property Relationships, Surbhi Subhash Kore

Doctoral Dissertations

The research work focused on examining the interfacial adhesion of unsized, epoxy, and urethane-sized textile grade carbon fiber (TCF) reinforced in different classes of polyurethane (PU) thermoplastic (TPU) and thermoset (TSU) polyurethane (PU) through the structure-property relationship. The Carbon Fiber Technology Facility (CFTF) at Oak Ridge National Laboratory (ORNL) has produced TCF to reduce the cost of commercial-grade carbon fiber. The first part of the research examined the fundamental relationships between (a) soft segment thermoplastic polyurethane (S-TPU), (b) hard segment thermoplastic polyurethane (H-TPU), (c) thermoset polyurethane (TSU) and TCF reinforcement’s molecular behavior at the interface using the surface and thermal …


Polymeric Impulsive Actuation Mechanisms: Development, Characterization, And Modeling, Yongjin Kim Oct 2019

Polymeric Impulsive Actuation Mechanisms: Development, Characterization, And Modeling, Yongjin Kim

Doctoral Dissertations

Recent advances in the field of biomedical and life-sciences are increasingly demanding more life-like actuation with higher degrees of freedom in motion at small scales. Many researchers have developed various solutions to satisfy these emerging requirements. In many cases, new solutions are made possible with the development of novel polymeric actuators. Advances in polymeric actuation not only addressed problems concerning low degree of freedom in motion, large system size, and bio-incompatibility associated with conventional actuators, but also led to the discovery of novel applications, which were previously unattainable with conventional engineered systems. This dissertation focuses on developing novel actuation mechanisms …


Mechanical Properties Of Intermetallic Compounds In Electrodeposited Multilayered Thin Film At Small Scale By Nanoindentation May 2015

Mechanical Properties Of Intermetallic Compounds In Electrodeposited Multilayered Thin Film At Small Scale By Nanoindentation

Faculty of Engineering University of Malaya

Mechanical properties of intermetallic compounds (IMCs) which were formed in electrodeposited Cu/Sn and Cu/Ni/Sn multilayered thin film have been investigated. The layers of Cu, Sn and Ni were formed by electrodeposition technique using copper pyrophosphate, tin methanesulfonic and nickel Watts baths, respectively. After synthesis, samples were subjected to high temperature aging at 150 degrees C for 168 h. Two different types of intermetallics Cu3Sn and Cu6Sn5 were formed in Cu/Sn. After adding ultra-thin layer of Ni (70 nm) in between Cu and Sn layers, (Cu, Ni)(6)Sn-5 was formed after aging at similar condition to that of Cu/Sn. Tin whisker growth …


Development Of Optimum Process Parameters And A Study Of The Effects Of Surface Roughness On Brazing Of Copper Mar 2015

Development Of Optimum Process Parameters And A Study Of The Effects Of Surface Roughness On Brazing Of Copper

Faculty of Engineering University of Malaya

Brazing experiments on commercially-pure copper plates, using brazing filler metal (MBF-2005), are conducted at temperatures in the range of 650-750 degrees C for time-durations in the range of 5-15 min. Shear tests for braze-joints involved use of a universal testing machine. Based on the shear-test results, a new brazing cycle has been developed that corresponds to the greatest shear strength of the braze-joint. The brazing cycle has been performed under a controlled dry-argon atmosphere in a tube furnace. Microscopic observations were made by use of both optical and electron microscopes; whereas surface roughness measurements were made by using a TRIO …


Fabrication And Characterization Of Poly(Octanediol Citrate)/Gallium-Containing Bioglass Microcomposite Scaffolds Mar 2015

Fabrication And Characterization Of Poly(Octanediol Citrate)/Gallium-Containing Bioglass Microcomposite Scaffolds

Faculty of Engineering University of Malaya

Bone can be affected by osteosarcomae requiring surgical excision of the tumor as part of the treatment regime. Complete removal of cancerous cells is difficult and conventionally requires the removal of a margin of safety around the tumor to offer improved patient prognosis. This work considers a novel series of composite scaffolds based on poly(octanediol citrate) (POC) impregnated with gallium-based bioglass microparticles for possible incorporation into bone following tumor removal. The objective of this research was to fabricate and characterize these scaffolds and subsequently report on their mechanical and biological properties. The porous microcomposite scaffolds with various concentrations of bioglass …


Fuzzy Logic-Based Approach To Investigate The Novel Uses Of Nano Suspended Lubrication In Precise Machining Of Aerospace Al Tempered Grade 6061 Feb 2015

Fuzzy Logic-Based Approach To Investigate The Novel Uses Of Nano Suspended Lubrication In Precise Machining Of Aerospace Al Tempered Grade 6061

Faculty of Engineering University of Malaya

Temper-grade aluminum alloy Al-6061-T6 is commonly used for many engineering purposes owing to its superior mechanical properties. Due to the practical importance, machining Al-6061-T6 alloy is crucial for different applications. The development of computer numerical control (CNC) of milling machines is in progress by researchers worldwide for its noteworthy advantages. The quality of machining determines the product's appearance, function and reliability. Appropriate lubrication at the machining zone improves the tribological characteristic of Al-6061-T6 alloy, leading to higher product quality. For reasons of ambiguity during machining, the soft computing technique is chosen to predict the output. In this particular research scope, …


Effects Of Playing Surface And Shoe Type Of Acl Tears In Soccer Players, Melissa Mansfield Jun 2014

Effects Of Playing Surface And Shoe Type Of Acl Tears In Soccer Players, Melissa Mansfield

Honors Theses

Anterior Cruciate Ligament injuries have become more common in athletes over the past decade which is believed to result from playing on more artificial turf surfaces. This study tested the playing surface theory by building upon a previous study conducted with Albany Medical Center which tested surface samples using an axial-torsion load frame located at Union College. The motion that causes most ACL noncontact injuries is replicated by the load frame which pushes and rotates a shoe against the playing surface and measures the torque it experiences. The foot position, normal load, degree of rotation and rate of rotation were …


Understanding The Role Of A Bio-Inspired Surface Modification For Delayed Icing, Clayton Schenk Aug 2011

Understanding The Role Of A Bio-Inspired Surface Modification For Delayed Icing, Clayton Schenk

Graduate Theses and Dissertations

Atmospheric icing event is problematic for outdoor structures because it can damage, slow, impede, and danger general routine. For a wind turbine blade, it can damage, disrupt movement, and cause potentially dangerous ice throw. Anti-icing based on a surface texture is advantageous due to the low cost of maintenance and there is no additional requirement of energy output for preventing the icing problem. This work is based on the biomimicry of the superhydrophobic nature of the lotus leaf, whereas the limited wettability supports the water to flow freely from the surface structure. The phenomenon is based on a morphology and …


Interface Engineered Diamond Coatings For Dry Machining Applications, Humberto Arturo Gomez Vega Jan 2011

Interface Engineered Diamond Coatings For Dry Machining Applications, Humberto Arturo Gomez Vega

USF Tampa Graduate Theses and Dissertations

Several studies have been propose to improve the adhesion of diamond films on cemented carbide tool materials, however a systematic study in identifying the role of the factors that affect the final diamond adhesion and the resulting machining performance of the tool under real manufacturing conditions is still unexplored. CVD diamond film's extraordinary qualities bring little benefit if the film fails to adhere sufficiently to the substrate. Inadequate adhesion undermines tool performance and longevity, causing unpredictable behavior under load and possibly leading to unexpected failure of the tool in the production line. This dissertation investigates the effects of different surface …