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Structural Stability Of Thermosets During Material Extrusion Additive Manufacturing, Stian K. Romberg

Doctoral Dissertations

Over the past decade, the scale of polymer additive manufacturing has been revolutionized with machines that print massive thermoplastic parts with greater geometric complexity than can be achieved by traditional manufacturing methods. However, the heat required to print thermoplastics consumes energy and induces thermal gradients that can reduce manufacturing flexibility and final mechanical properties. With the ability to be extruded at room temperature and excellent compatibility with fibers and fillers, thermoset resins show promise to decrease the energy consumption, expand the manufacturing flexibility, and broaden the material palette offered by large-scale polymer additive manufacturing. However, structural instability in the uncured …

Development Of Vegetable Oil Based Nano-Lubricants, Vicente Cortes

Theses and Dissertations

Nowadays, the depletion of crude oil reserves in the world and the global concern in protecting the environment from contamination have renewed interest in developing environment friendly lubricants derived from alternative sources such as vegetable oils. Mineral oil is the most common lubricant, however, it also has poor biodegradable properties. Vegetable oils exhibit good viscosity index, flash point, pour point, tribological properties, and are biodegradable. Furthermore, the use of nanoparticles as additives has shown to improve anti wear and anti-friction properties of the base lubricant. The present research project will evaluate experimentally the rheological and tribological behavior of coconut oil, …

Compressive And Rheological Deformation Analysis Of Large Area Pellet-Fed Material Extrusion 3d Printed Parts In Relation To In Situ Thermal Imaging, Eduardo Meraz Trejo

Open Access Theses & Dissertations

In large area pellet extrusion additive manufacturing, the temperature of the substrate just prior to the deposition of a new subsequent layer has an effect on the overall structure of the part. Warping and cracking occur if the substrate temperature is below a specific threshold, but also deformation and deposition adhesion failure occur if the substrate temperature is above a certain threshold just prior to deposition of a new layer. Currently, Big Area Additive Manufacturing (BAAM) machine users mitigate this problem by trial and error, which is costly and may result in decreased mechanical properties, monetary losses and time inefficiencies. …

Electric-Field Assisted Manipulation And Self-Assembly Of Particle Suspensions, Edison Chijioke Amah

Dissertations

The aim of this dissertation is to model the processes by which particles suspended in liquids and at liquid surfaces self-assemble when they are subjected to uniform and non-uniform electric fields. To understand the role of electric forces, three related problems were studied numerically and experimentally.

In the first problem, particles are assumed to be suspended inside a liquid and a nonuniform electric field is applied using electrodes mounted in the domain walls which causes positively polarized particles to collect in the regions where the electric field intensity is locally maximal and the negatively polarized particles collect in the regions …

Surfactants, Thermal And Surface Energy Effects On Emulsions’ Transport Properties: A Study Using Lattice Boltzmann Method, Wessam Falih Hasan

Wayne State University Dissertations

This work aims to provide an efficient Gunstensen LBM based CFD model, capable of solving complex problems related to droplets behavior in shear and parabolic flows.

Thermal conditions determine the outcome of the physical and transport properties of emulsions during their various processing phases. A better understanding of the intricate relationship between thermal, surfactants and hydrodynamics can help in the optimization of these processes during the production of emulsions. To investigate the outcome of coupling thermal, surfactants and hydrodynamics on emulsions behavior, a robust quasi-steady thermal-surfactants numerical scheme is presented and used here. To validate the model, the rheological behavior …

Rheology Of Cross-Linked Polymers And Polymer Foams: Theory And Experimental Results, John Herman

Wayne State University Dissertations

Typical polymers have a time-dependent response to loading which results in stress relaxation or creep. Models using springs/dashpots or Volterra integrals are capable of predicting the material response, but place little or no emphasis on the reasoning behind the response. This research proposes a microscopic reasoning behind polymer chain movement, while developing a model to predict the creep and stress relaxation of a polymer foam. Based on the theorized slip/stick of polymer chains as they slide past each other, this model successfully predicts the behavior of a PMI polymer foam under tensile loads. This model lends insights into polymer microscopic …

Applying Chaotic Advection To Rheology: An In Situ Structuring Rheometer, Ramaswami Subrahmanian

All Dissertations

A prototype In Situ Structuring Rheometer (ISSR) was designed and implemented to study changes in shear viscosity of polymer blends and composites while processing them in such a way as to control the evolution of microstructure. The ISSR is based on a regime of fluid mechanics known as chaotic advection, in which simple time-periodic flow fields can cause fluid particles to move chaotically. Chaotic advection is also the basis of Smart Blending, a technology employed to process polymer blends having a variety of morphologies at a fixed composition, and polymer composites in which the additives have been arranged into layered …

Manufacture, Characterization, And Application Of Multiwall Carbon Nanotube Composite Crylonitrile-Butadiene-Styrene, Daniel Ray Bortz

University of Kentucky Master's Theses

Carbon nanotubes have been studied for nearly two decades and their amazing properties continue to spur intense investigation in the area of polymer composites. In terms of potential commercialization, mutiwall carbon nanotubes (MWCNTs) are currently the most prevalent and economically viable form of nanotubes. Uncovering innovative means to take full advantage of their properties remains a fundamental issue. In this thesis, viability of their use to reinforce polymeric systems is reported. Acrylonitrilebutadiene- styrene (ABS) was used as the host matrix. MWCNTs were introduced to the ABS matrix via melt compounding. The resulting composite was thoroughly rheologically, thermally, and mechanically characterized. …