Digital Commons Network^™

Purification Of Uranium Tetrafluoride Using Ammonium Bifluoride, Kyle Robert Foster

Theses and Dissertations

Molten salt reactors are being deployed as one of the Generation IV nuclear reactor concepts starting in 2025. While their applications and safety potential are considered extremely advantageous, there is a lack of operating history to draw on, so thorough understanding of proposed molten salt materials’ thermochemical behavior is crucial to their successful implementation.

The most prominent fissile fuel proposed for molten salts is uranium tetrafluoride (UF4) using ²³³U of the thorium fuel cycle. UF₄ is extremely hygroscopic, meaning it will react with moisture and oxygen in its environment, so as-received powders contain significant levels of impurity. In …

Development Of A Rapid Compression And Expansion Machine To Characterize The Ignition Propensity Of Multi-Component Liquid Fuels, Jonathan Joseph Morreale

Theses and Dissertations

Combustion has been the primary source for energy production, whether it be from coal, oil, or natural gas, for a very long time. With increasing population and therefore an increased demand for energy, efficiency is becoming a concern. In order to increase efficiency, engines have been downsized and compression ratios have been increased. In doing so, problems have arisen such as knock and low speed pre-ignition. To better understand these problems, an investigation into how fuels ignite at higher pressures is necessary. Real fuels are comprised of multiple components that exhibit significant variations in their own physical and chemical characteristics. …

Fabrication And Characterization Of Micro/Nanostructured Ceramic Device For Energy Conversion, Yun Gan

Theses and Dissertations

The deteriorating climate is threatening our living habitat and arousing public awareness. To achieve the carbon neutral goal by the middle of 21st century, developing novel technologies to reduce CO₂ emission or promote its capture become urgent. Among them, oxygen permeation membrane (OPM) and solid oxide cell (SOC) are two promising devices for clean energy conversion.

In chapter 1, the background of OPM and SOC are briefly introduced. Fundamental mechanism and application of phase inversion, the key process involved in fabrication of hollow fiber OPM and microtubular SOC are emphatically described. Mixed ionic and electronic conducting (MIEC) perovskites demonstrate …

Development Of Acoustic Metamaterial Noise Barriers And Simultaneously Harvesting Energy Using Smart Materials, Fariha Mir

Theses and Dissertations

In our surroundings abundant energy, we either feel through component vibration or hear noises from acoustic sources. Harvesting these unused and untapped green energy in the form of ambient vibration, and acoustic sounds is an emerging field of research in recent years. Utilization of the energy within a wide band of the frequency spectrum originated from the vibrational sources alone stands as one of the most promising ways to power small electronic devices, smartphones, local structural health monitoring sensors, home, and workshop appliances. These abundant sources of green energy are available in almost all the engineering industries, workshops, manufacturing facilities, …

Effect Of Crystal Size On The Failure Mechanics Of Polymer Bonded Explosives, Chizoba Onwuka

Theses and Dissertations

Polymer bonded explosives (PBXs), typically constitute 80-95% of energetic crystals and 5-20% of a soft polymer binder, are widely used in extreme loading conditions such as rocket propellants and explosive munitions because of their high performance and low sensitivity. The particle size of crystals has a significant effect on the mechanical properties of most polymer particulate composites.

In the study, the effect of particle size on the deformation behavior of PBX under dynamic loading is investigated. The study involves testing polymer bonded sugar (PBS) samples, a well-known mechanical simulant of PBXs, with four different crystal sizes: coarse, intermediate, fine and …

Leveraging Digital Transformation To Build The Technology Of Tomorrow Using Yesterday’S Equipment, Evan Barnett

Theses and Dissertations

Today’s industry sectors are filled with machines developed years ago. Healthcare, manufacturing, sustainment operations, and many others have equipment that may be reliable, but lacks certain capabilities that the newest technology delivers. The digital environment is becoming a necessity for users who want greater insights into how to improve their processes. A solution to this problem would be to purchase the newest equipment that contains robust measures to generate, collect, and analyze data. However, this solution may not be financially feasible for some and for others may sacrifice machine downtime and reliability. To combat these issues, this research focuses on …

Mechanical Strength Of Sic Composite Tubing Under Uniaxial And Multiaxial Loading, Colton Corley

Theses and Dissertations

Silicon carbide fiber reinforced silicon carbide matrix composite is one of the candidate materials for accident tolerant nuclear fuel cladding concepts. In a Nuclear power plant, the reactions between the fuel, cladding, and coolant in a potential loss of coolant accident(LOCA) are of utmost importance to ensure safety in the accident tolerance of such plants. It is for this reason that SiC(silicon carbide) composite tubes have been selected as a possible alternative to the older Zirconium based cladding methods currently used in the industry, which were a partial cause of the Fukushima 2011 meltdown. To serve as fuel cladding, a …

Application Of Digital Transformation In The Water Desalination Industry To Develop Smart Desalination Plants, Ibrahim Yousif

Theses and Dissertations

Fresh water shortage threatens the development and prosperity of many countries including several areas in the United States. Sea and ground water reverse osmosis desalination is rapidly becoming a dominant technology for overcoming water shortage threats by providing cost-effective freshwater production. Digital transformation can be used to help facilitate and advance water treatment technologies by reducing costs and minimizing downtime. Digital transformation is a process that encapsulates digital tools and technologies such as cloud computing, machine learning, artificial intelligence, the internet of things, and virtual/augmented reality. It is a process where objects in the physical world are given virtual replicas …

Multi-Fidelity Surrogate And Reduced-Order Model-Based Microfluidic Concentration Gradient Generator Design, Haizhou Yang

Theses and Dissertations

The microfluidic concentration gradient generator (μCGG) is an important device to generate and maintain concentration gradients (CGs) of biomolecules for understanding and controlling biological processes. However, determining the optimal operating parameters of μCGG is still a significant challenge, especially for complex CGs in cascaded networks. To tackle such a challenge, this study presents multi-fidelity surrogate and reduced-order model-based optimization methodologies for accurate and computationally efficient design of μCGGs.

The surrogate-based optimization (SBO) method is first proposed for the design optimization of μCGGs based on an efficient physics-based component model (PBCM). Various combinations of regression and correlation functions in Kriging and …

Searching Extreme Mechanical Properties Using Active Machine Learning And Density Functional Theory, Joshua Ojih

Theses and Dissertations

Materials with extreme mechanical properties leads to future technological advancements. However, discovery of these materials is non-trivial. The use of machine learning (ML) techniques and density functional theory (DFT) calculation for structure properties prediction has helped to the discovery of novel materials over the past decade. ML techniques are highly efficient, but less accurate and density functional theory (DFT) calculation is highly accurate, but less efficient. We proposed a technique to combine ML methods and DFT calculations in discovering new materials with desired properties. This combination improves the search for materials because it combines the efficiency of ML and the …

An Investigation Of The Ignition Propensities Of Fuels Perturbed By Nitrogen Monoxide, Ackmer Robinson Iii

Theses and Dissertations

Quantitative structure property relationship (QSPR) regression models were developed based on the chemical functional group distribution of toluene reference fuels (TRF, mixtures of n-heptane, iso-octane, and toluene) for RON, MON, and DCN. The QSPR regression models were developed using DCN measurements from this study as well as RON/MON data available in literature. The correlations between RON/MON and DCN were analyzed. The ignition propensity of TRFs perturbed by NO addition was also investigated in this study. The interactions between the chemical functional groups and NO were investigated using an ignition quality tester (IQT). It was found that the increase in the …

Implementation Of Stereo Digital Image Correlation For In-Plane Strain Measurements To Quantify The Anisotropic Behavior, Plastic Flow, And Strain Hardening Of Extruded Aluminum Alloy, Farzana Yasmeen

Theses and Dissertations

The efficient use of metals is important in various industries, including aerospace, automotive, and energy systems. In each case, the type and range of combined loading conditions can be quite different. The approaches to stress analysis of such complex engineering components and assemblies often are limited to elastic conditions. For those cases where components are relatively thin, elastic-plastic conditions are present; there is continuing interest in assessing the accuracy of analytic and computational models for combined loading conditions. In such cases, experiments performed with axial and shear loads (e.g., tension-torsion) provide baseline data regarding the relationship between applied stresses and …

A Multi Physics Integrated Solution For A High-Pressure Stage Turbine Efficiency And Durability, Sanjay Chopra

Theses and Dissertations

World electricity demand is projected to grow at an annual rate of ~ 2.1% to year 2040₁. EIA projects nearly 50% increase in world energy usage by 2050 led by growth in Asia.[28];[29]. It is predicted that the global electricity demand grows at approximately 1.6 % per year from approximately 2008 and forecasted to approximately 2035, twice the rate of primary energy demand. This raises electricity's usage in total final energy consumption from approximately 19% in 2018 to approximately 24% in 2040. Electricity demand growth is set to be particularly strong in developing economies. .[28];[29];[38] As an enabler, to meet …

Simulation-Based And Data-Driven Approaches To Industrial Digital Twinning Towards Autonomous Smart Manufacturing Systems, Kaishu Xia

Theses and Dissertations

A manufacturing paradigm shift from conventional control pyramids to decentralized, service-oriented, and cyber-physical systems (CPSs) is taking place in today’s Industry 4.0 revolution. Generally accepted roles and implementation recipes of cyber systems are expected to be standardized in the future of manufacturing industry. Developing affordable and customizable cyber-physical production system (CPPS) and digital twin implementations infuses new vitality for current Industry 4.0 and Smart Manufacturing initiatives. Specially, Smart Manufacturing systems are currently looking for methods to connect factories to control processes in a more dynamic and open environment by filling the gaps between virtual and physical systems.

The work presented …

Reduced Order Modeling Based On Hybrid Snapshot Simulation, Feng Bai

Theses and Dissertations

Reduced order model (ROM) is an emerging technique for rapid and efficient numerical simulation and computation in science and engineering applications. The ROM consists of two stages: (1) the offline snapshot simulation to produce high-quality snapshot data representative of model trajectories, from which the projection subspace can be extracted and used for ROM construction; and (2) the online simulation to utilize the ROM built in stage 1. The snapshot simulation is traditionally performed with full order model (FOM) and is computationally demanding, which is one of the most critical limiting factors for the development and deployment of ROM in real-world …

Effects Of Overmolding Process Parameters On Bondzone Quality, Vivek Varma Penumetsa

Theses and Dissertations

Urban air mobility (UAM) vehicles refer to small sized systems that transport people or cargo by air. In recent years, the interest in UAM vehicles has risen to combat traffic congestion, provide faster delivery times, or provide easier access to remote places. To meet potential future demand, traditional aircraft manufacturers must introduce manufacturing technologies that can cope with high production rates. One manufacturing technology aircraft manufacturers are investigating is overmolding, a manufacturing technology common to the automotive industry. Overmolding combines the manufacturing and assembly cycles into one by injection molding a component on top of a substrate. The quality of …

Optimizing Heat Pipes With Partially-Hybrid Mesh-Groove Wicking Structures And Its Capillary-Flowing Analysis By Simulation, Guanghan Huang

Theses and Dissertations

Heat pipes are known as efficient two-phase heat transfer devices and widely utilized in thermal management of power plants and electronics. The hybrid mesh-groove wick promises to attain a higher thermal performance of the heat pipe by balancing the permeability and capillarity. However, traditional fully hybrid mesh-groove wick presents considerable condensation thermal resistance due to the condensed quiescent working fluid and thick, saturated wick.

In this study, a novel partially hybrid mesh-groove wick has been proposed to enhance the evaporation of L-shaped copper-ethanol heat pipes. L-shaped heat pipe promotes high-efficient draining of condensed liquid by gravity, while traditional straight-shaped heat …

An Acoustic Emission And Artificial Intelligence Approach To Structural Health Monitoring For Aerospace Application, Joseph Chandler Garrett

Theses and Dissertations

In the area of aerospace and other applications, structural health monitoring (SHM) has been a significant and growing area of research in recent years. Throughout the operational life of aerospace structures, various damage scenarios may manifest, and it is of great concern to the aerospace community to develop methodologies for detecting and assessing these damage scenarios. In this paper, fundamental research on the use of the acoustic emission (AE) approach to SHM for fatigue crack growth is presented. In general, the AE approach to SHM and non-destructive evaluation (NDE) involves the sensing of ultrasonic Lamb waves propagating through a structure. …

Enhanced Flow Boiling And Bubble Dynamics With Hfe7100 & Di Water In Interconnected Microchannels, Jiaxuan Ma

Theses and Dissertations

Flow boiling in microchannels using dielectric fluids is one of the most desirable cooling solutions for high power electronics. Primary two-flow patterns, including bubbly flow, slug flow, and annular flow, have been well established in microchannels. However, it is challenging to promote flow boiling performance, particularly critical heat flux (CHF), due to their unfavorable thermophysical properties. Considering these situations, flow boiling in parallel and isolated microchannels have been extensively studied. In this dissertation, a novel concept that has five parallel microchannels (W=200 µm, H=250 µm, L=10 mm) are interconnected by micro-slots (20 µm wide and 250 µm deep) starting from …

Nano-Engineered High-Performance Copper-Water Heat Pipes, Ahmed A. Abdulshaheed

Theses and Dissertations

Recently, heat pipes have gained an exceptional reputation as passive systems. They have become an attractive choice for many engineering applications due to their simple design, high rate of heat transfer, low weight, and low cost of maintenance [1]. A Heat pipe consists of a vacuumed shell filled partially with a compatible working fluid. Three main sections comprise a heat pipe: evaporator, adiabatic, and condenser section. The heat pipe utilizes the principle of evaporation and condensation for operations, i.e., the phase change of working fluid. Heat pipe allows high heat rates to transfer over considerable lengths with minimum temperature differences …

Nondestructive Evaluation And Structural Health Monitoring Of Manufacturing Flaws And Operational Damage In Composite Structures, Robin James

Theses and Dissertations

Advanced composite materials have begun to be used extensively in the manufacturing of aerospace structures. Composite aerospace structures can develop complex types of damages during the manufacturing stages and operational lifetime. This creates an indispensable demand for appropriate nondestructive evaluation (NDE) and structural health monitoring (SHM) methods that are tailored to specific types of damage. This dissertation addresses innovative methods for NDE and SHM of manufacturing flaws and operational damage in composite structures.

For the NDE of manufacturing flaws in carbon fiber reinforced polymer (CFRP) composites, an eddy current testing (ECT) NDE method has been developed by conducting multiphysics modeling …

Prediction Of Residual Stress And Distortion In Laser Powder Bed Fusion Additive Manufacturing, Bhanuprakash Sairam Kosaraju

Theses and Dissertations

Additive Manufacturing (AM) has its proven advantages to unlock the design space and manufacturing capabilities for complex geometries with lightweights. Distortion is one of the most common defects that occur in Laser Powder Bed Fusion Additive Manufacturing (LPBFAM), which is caused by the significant residual stress during the printing process. This can lead to numerous process iterations to achieve the requisite form and fit tolerances.

In this study, Finite Element (FE) model that utilizes the element birth approach was developed to predict the residual stress and distortion in the LPBFAM process. The methodology leverages a simplified approach where the detailed …

Experimental Investigation Of Spray Cooling Integrated With A Modified Vapor Compression Refrigeration System Using Several Refrigerants, Nabeel Mukhlif Abdulrazzaq

Theses and Dissertations

Spray cooling has gained increasing interest over the last three decades due to its high thermal performance as a direct cooling technique. Researchers are investigating spray cooling in thermal management systems for electronic applications, particularly focusing on the use of dielectric fluids including FC-72, FC-87, ammonia, and refrigerants such as R113 and R134a. Their studies indicate that the usage of dielectric fluids as a working fluid in spray cooling systems is promising and has significant thermal performance enhancement, which is suitable for a wide range of electronic applications. However, several deficiencies have been identified with the working fluids studied thus …

Instrumentation And Experimentation Development For Robotic Systems, Tristan Kyzer

Theses and Dissertations

Localization of robotic systems is a necessity for control of robotic systems and often requires the use of costly sensors and equipment onboard the robot or installed within a facility. GPS or GNSS sensors are effective for localizing robots in GPSaccessible environments, but do not work as well in dense urban areas or inside fully enclosed buildings, such as factories or warehouses. Sensors such as LiDAR can be costly and require substantial experience and knowledge to utilize as well as potential changes to infrastructure for use. Computer vision-based localization systems offer potential as a localization solution for various applications. A …

Multimodal Robotic Health In Future Factories Through Iiot, Data Analytics, And Virtual Commissioning, Clint Saidy

Theses and Dissertations

The manufacturing sector is continuously reinventing itself by embracing opportunities offered by the industrial internet of things and big data, among other advances. Modern manufacturing platforms are defined by the quest for ever increasing automation along all aspects of the production cycle. Furthermore, in the next decades, research and industry are expected to develop a large variety of autonomous robots for a large variety of tasks and environments enabling future factories. This continuing pressure towards automation dictates that emergent technologies are leveraged in a manner that suits this purpose. These challenges can be addressed through the advanced methods such as …

Anisotropic Wave Behavior In Isotropic Material With Orthogonal Surface Perturbation, Khaleda Akter

Theses and Dissertations

Elastic wave propagation in anisotropic media is of great interest in various branches of engineering and applied sciences. In this study, an anisotropic wave propagation behavior in isotropic material with orthogonal surface perturbation is presented. The conventional method of estimating dispersion equations for isotropic material is to apply Helmholtz decomposition on the potential functions for Rayleigh-Lamb wave and Shear Horizontal (SH) waves. However, the presence of isotropic material with orthogonal surface perturbations in two coordinate directions significantly affect the wave propagation behavior due to its direction dependency, and hence, the Helmholtz decomposition of the potential functions cannot be applied to …

Preferential Vaporization Potential Of Crude Oils And Its Impact On Flame Flashback Behaviors, Ayuob Al Wahaibi

Theses and Dissertations

As combined cycle gas turbines for power generation operating on light distillate fuels provide a sufficient energy, there is a global trend in using heavy liquids (e.g. HFO, crude oils) for direct-firing in gas turbine. However, using these heavy fuels imposes many challenges due to their wide range of physical/chemical properties, which control near-limit combustion behaviors, such lean blow-out and flashback. In addition, the ignition propensity of these heavy fuels is not reported in crude assays, and utilizing a simple, with small sample, and quick methodology to characterize the ignition propensity is important in determining the fuel quality.

In this …

Grafting Based Thermoplastic-Thermoset Bonding For Aerospace Structures, Saurabh Vaidya

Theses and Dissertations

The use of carbon fiber composites is rapidly increasing in the aerospace industry. Fiber reinforced plastic composites can primarily be classified as thermoplastic and thermoset, both offer unique advantages over one another. Thermosets cure at relatively low temperature and in general, are lower priced than thermoplastic composites. However, the cost of autoclave for the curing of thermosets is a major drawback. On the other hand, thermoplastics are showing higher damage tolerance. They can be re-melted and re-consolidated and have the potential to be re-used / recycled. The repair of TP composites is not developed yet. Therefore, both the types attract …

Experimental Investigation Of Single And Two-Phase Heat Transfer Performance In Microchannels With Surface Modifications And Multiple Inlet Restrictors, Saad Kadham Oudah

Theses and Dissertations

Due to shrinking component sizes and faster switching speeds, the volumetric heat generation rates and surface heat flux in many advanced power electronic devices have increased exponentially, creating an urgent need for efficient cooling technologies. It has become particularly challenging to maintain an optimal temperature at the device level. Among advanced cooling techniques, single-phase and two-phase microchannel heat sinks show considerable promise in removing a significant amount of heat from a small surface area. Considered one of the most efficient heat dissipaters, the two-phase microchannel heat sink can handle very high heat flux at a small footprint and requires relatively …

Separate Effects Tests For Studying Thermal Gradient Driven Cracking In Uo2 Pellets Undergoing Resistive Heating, Sobhan Patnaik

Theses and Dissertations

A variety of normal operation and accident scenarios can generate thermal stresses large enough to cause cracking in light-water reactor (LWR) fuel pellets. Cracking of fuel pellets can lead to reduced heat removal, larger centerline temperatures, and localized stress in cladding, all of which impact fuel performance. It is important to understand the temperature profile on the pellet before and after cracking to improve cracking models in fuel performance codes such as BISON. However, in reactor observation and measurement of cracking is very challenging owing to the harsh environment and design of fuel rods.

Recently, a state-of-the-art experimental pellet cracking …