Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 1 of 1
Full-Text Articles in Entire DC Network
3-D Numerical Simulation Of Reactive Extrusion And Its Application To Polymerization Of Ε-Caprolactone In Co-Rotating Twin-Screw Extruders, Linjie Zhu
Dissertations
A 3-D numerical simulation model was proposed to predict the polymerization of ε-caprolactone in fully-filled conveying elements and kneading blocks of co-rotating twin-screw extruders, in which the kinetics equation for polymerization is coupled with continuity equation, momentum equation, and energy equation. With the 3-D model, parametric studies have been carried out to investigate the effects of screw configurations, screw diameter, operational conditions, values of heat from reaction, initiator concentration, and heat transfer conditions at barrel surface upon the polymerization progress. Two simulation models for the polymerization in the partially-filled channels were developed based on the conveying mechanisms of the reaction …