Digital Commons Network^™

Evidence Of Long-Wavelength Collective Excitations In Magnetic Superlattices, Nikolay I. Polushkin, Steven A. Michalski, Lanping Yue, Roger D. Kirby

Materials Research Science and Engineering Center: Faculty Publications

We report on a mechanism of dynamic dipolar coupling in magnetic superlattices via long-wavelength nonevanescent fields. In the spin excitation spectra of our heterophase stripe structures, such interactions mediate a singlet ↔ doublet crossover in the frequency regime driven by the orientation of an external static field. This crossover is a new feature observed in collective behavior of superlattices, though there is some analogy of this phenomenon with birefringence taking place in optical superlattices. We envision applying the collective effects described here in microwave photonic devices.

Use Of Friction Stir Processing And Friction Stir Welding For Nitinol Medical Devices, Blair London, Murray Mahoney, Alan Pelton

Materials Engineering

Metallic materials may be joined utilizing a friction stir processing technique. The friction stir processing technique utilizes a shaped, rotating tool to move material from one side of the joint to be welded to the other without liquefying the base material.

Optimizing Production Methods For Artifical Silk Proteins Through Bioreactor And Purification Studies Of Recombinant Proteins Expressed From Pichia Pastoris, Aaron Ramey

All Theses

Advancements in the field of biomaterials are being made to produce an artificial silk fiber. A gene was constructed which utilized components from both the dragline silk of Nephila clavipes and nematode collagen. For this engineered protein, the yeast strain Pichia pastoris was chosen to be the host organism. Previous research has shown P. pastoris to have comparatively low amounts of specific protein productivity. Therefore, this problem must be compensated for by obtaining extremely high cell densities. The main focus of this study was to optimize the fermentation parameters of transgenic yeast cultures within a bioreactor in order to increase …

Influence Of Temperature And Polymer/ Mold Surface Interactions On Micro-Feature Replication At Ambient Pressure In Micro Injection Molding, Varun Thakur

All Theses

This study assesses micro-feature replication at elevated mold temperature and ambient pressure using a variety of polymers. Moldings were made on the surface of stainless steel and silicon wafers containing features as small as 130 nm under isothermal conditions in a heated chamber by allowing polymer to spread over the features at ambient pressure. Feature replication was analyzed via AFM and SEM. Polymer behavior was characterized via melt contact angle and melt viscosity. While feature detail was well replicated, the moldings exhibited poor dimensional accuracy due to shrinkage. In general, polymers with low viscosity and surface tension comparable to the …

Dielectric Properties And Method Of Characterizing Ceramic Powders And Multiphase Composites, Ravi Kiran Kota

All Theses

Barium Titanate was the first developed ferroelectric ceramic material and even today it is widely used. It is also a well-known material used for capacitors. The only reason behind a wide range of applications is that barium titanate boasts of high dielectric properties. A phase transition from cubic to tetragonal at normal working temperatures provides enhanced dielectric properties in this electronic material. For any application and design, the most inquired property is the dielectric constant. Predicting the dielectric constant is very much required as it is the pre-requisite. This is the major objective of the present work. To estimate the …

College Of Engineering Senior Design Competition Fall 2006, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge.

The senior design competition helps to focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects …

Modeling Of The Size Effects On The Behavior Of Metals In Microscale Deformation Processes, Gap-Yong Kim, Jun Ni, Muammer Koc

Gap-Yong Kim

For the accurate analysis and design of microforming process, proper modeling of material behavior at the micro/mesoscale is necessary by considering the size effects. Two size effects are known to exist in metallic materials. One is the “grain size” effect, and the other is the “feature/specimen size” effect. This study investigated the feature/specimen size effect and introduced a scaling model which combined both feature/specimen and grain size effects. Predicted size effects were compared with three separate experiments obtained from previous research: a simple compression with a round specimen, a simple tension with a round specimen, and a simple tension in …

Studies Of The Mechanism Of Electron Beam Induced Deposition (Ebid), Young Ryong Choi

Doctoral Dissertations

The controlled deposition of metals resulting from the passage of an ion beam through an atmosphere of a suitable precursor gas is a well-established procedure for micro scale materials manipulation. While the ion beam technique is rapid and reliable it has the disadvantage that the beam itself can ablate and contaminate the target with Gallium or other materials, and the fact that ion optics are less widely accessible than electron optical columns. We have therefore been investigating the theory and practice of depositing metal using an electron beam and variety of precursor gases. The aim of this work is to …

Thermal Stability Of Binary Cr-Cr3Si And Ternary Nial-Mo Eutectic Alloys, Aravind Gali

Doctoral Dissertations

The thermal stability of multiphase intermetallics at temperatures to 1400°C was investigated by studying two model eutectic systems: Cr-Cr₃Si having a lamellar microstructure and NiAl-Mo having a fibrous microstructure. In drop cast Cr-Cr₃Si, coarsening was found to be interface controlled. The coarsening rate could be significantly reduced by microalloying with Ce and Re, two elements which were chosen because they were expected to segregate to the Cr-Cr₃Si interfaces and decrease their energies. Similarly, directional solidification, which is also expected to lower the Cr- Cr₃Si interfacial energy, was found to dramatically decrease the …

An Investigation Of The Deposition And Characterization Of Materials Formed By Electron Beam Induced Deposition, Wei Li

Doctoral Dissertations

This dissertation deals with EBID – Electron Beam Induced Deposition – a novel bottom up nanofabrication technique. Since EBID was first employed for nano-patterning, a number of empirical factors were investigated to control deposition process. Meanwhile a few theoretical models were proposed based on some fundamental assumptions. So far little work has been done to verify the validity of these assumptions. The main objective of my PhD study, therefore, was to answer whether these assumptions are valid so that unifying the empirical factors and theoretical models would be possible. Electrical resistivity of deposited materials was another interesting topic included in …

A Study Of The Relationship Between Indentation Creep And Uniaxial Creep, James Anthony Lamanna Jr.

Doctoral Dissertations

The purpose of this work is to further the scientific understanding of the relationship between indentation creep and uniaxial creep. The data for this study was obtained by conducting both indentation and uniaxial creep experiments on amorphous selenium. Experiments were designed to collect data over a wide range of creep rates. Specific temperatures were chosen to collect creep data above and below the glass transition temperature of 31°C. The indentation and uniaxial compression data was used to accomplish several objectives.

The first objective was to test the ability of the Oliver-Pharr stiffness equation to predict contact area. The current contact …

Pseudoelasticity And Shape Memory Effect In Single Crystal Fe3Al, Saurabh Kabra

Doctoral Dissertations

Fe₃Al is an intermetallic compound which has shown some excellent engineering properties and has been widely studied for this reason. It also shows interesting mechanical phenomenon like yield stress anomaly and pseudoelasticity. Mechanical behavior and diffraction studies on the pseudoelastic aspect of Fe₃Al have been presented in this work.

Single crystalline, D0₃ ordered Fe₃Al is known to show pseudoelastic behavior at room temperature. Pseudoelastic behavior was seen in both tension and compression with a distinct tension-compression asymmetry. No strain hardening occurred under tension even at high applied strains as opposed to compression, …

Methylsilane Derived Sic Particle Coatings Produced By Fluid-Bed Chemical Vapor Deposition, James Henry Miller

Doctoral Dissertations

This report describes the research effort that was undertaken to develop and understand processing techniques for the deposition of both low and high density SiC coatings from a non-halide precursor, in support of the Generation IV Gas-Cooled Fast Reactor (GFR) fuel development program.

The research was conducted in two phases. In the first phase, the feasibility of producing both porous SiC coatings and dense SiC coatings on surrogate fuel particles by fluidized bed chemical vapor deposition (FBCVD) using gas mixtures of methylsilane and argon was demonstrated. In the second phase, a combined experimental and modeling effort was carried out in …

Effects Of Temperature And Grain Size On The Transformation And The Deformation Behaviors Of The Trip (Transformation Induced Plasticity) Steels, Kaixiang Tao

Doctoral Dissertations

Two types of TRIP steels, a commercial 304L stainless steel and an Fe-10%Cr-5%Ni-8%Mn steel, have been used to investigate the effects of temperature and grain size on the transformation and mechanical behaviors. 304L SS was used to investigate the effects of temperature ranging from 300K to 77K, while the Fe-10%Cr-5%Ni-8%Mn steel was used for the investigation of the effects of the grain size at 300K.

At 203K, the fcc grains of the 304L SS with {200} plane normal parallel to the loading direction are preferred for the fcc to bcc transformation and the {200} plane normals of the newly-formed bcc …

A Lifetime-Prediction Approach To Understanding Corrosion: The Corrosion-Fatigue And The Corrosion Behavior Of A Nickel-Based Superalloy And A Nanocrystalline Alloy, Rejanah Vernice Steward

Doctoral Dissertations

Lifetime-prediction models are useful for simulating a material’s in-service behavior or outcome. Perhaps the greatest advantage of these models is the ability to use the predicted results to help optimize engineering designs and reduce costs. The Hastelloy^® C-2000^® superalloy is a single-phase material and face-centered cubic in structure at all temperatures. The C-2000^® alloy is a commercially designed alloy manufactured to function in both reducing and oxidizing solutions. C-2000^® is used as a fabrication material for heat exchangers, piping for chemical refineries, and storage repositories. The corrosion properties of C-2000^® are excellent, and the ductility …

Ex-Situ Epitaxial Yba2Cu3O7-Δ Films: Precursor Conversion And Film Characterization, Yifei Zhang

Doctoral Dissertations

BaF₂-based precursors were deposited on various substrates by electron beam co- evaporation and trifluoroactates-involved metal organic deposition (TFA-MOD) for fabricating biaxially-textured YBa₂Cu₃O_7-δ (YBCO) films. A low-pressure processing system was established for the conversion of the precursors. High critical current densities near 4 MA/cm² (77 K, self field) were obtained for the first time through the ex-situ conversion under the total pressures as low as 10 mTorr. The viability of the low- pressure conversion may enable a large-scale, cost-effective batch production of YBCO- based high temperature superconductor (HTS) wires.

The effects of the …

A Kinetic Study Of Indentation Pop-Out In Si, Songqing Wen

Doctoral Dissertations

The kinetics of the phenomenon of pop-out during nanoindentation of silicon were studied by a variety of mechanical and structural characterization techniques. Pop- out is commonly viewed to result from the reversal of a unique pressure-induced, volume reducing phase transformation that occurs in silicon and germanium.

The mechanical characteristics were examined by standard nanoindentation methods using a number of triangular pyramidal indenters with centerline-to-face angles varying in the range 35°-85°. The load at which pop-out occurs was systematically measured as a function of indenter angle, loading/unloading rate, and maximum load. Nanoindentation tests were conducted both at a constant loading rate …

Studying The Fatigue Behavior Of Zr-Based Bulk-Metallic Glasses And Composites, Gongyao Wang

Doctoral Dissertations

As excellent candidates for structural materials, the mechanical behavior of bulk metallic glasses (BMGs) is being widely studied. Although their fatigue behavior is very important for engineering applications, there are few studies on their fatigue behavior. Moreover, the understanding of the fatigue behavior is pretty limited.

High-cycle fatigue experiments were conducted on notched Zr-based BMGs under tension-tension loading in air and vacuum at room temperature. A sparking phenomenon was found by infrared camera at the final fracture moment of Zr₅₀Al₁₀Cu₃₀Ni₁₀ in air. The fatigue-endurance limit (983 MPa) of Zr₅₀Cu₃₇Al …

Effect Of Chain Architecture And Surface Energies On The Ordering Behavior Of Lamellar And Cylinder Forming Block Copolymers, V. Khanna, Eric W. Cochran, A. Hexemer, G. E. Stein, G. H. Fredrickson, E. J. Kramer, X. Li, J. Wang, S. F. Hahn

Eric W. Cochran

We investigate the effect of surface energy and chain architecture on the orientation of microdomains in relatively thick films (600-800 nm) of lamellar and cylindrical block copolymers of poly(cyclohexylethylene) (C) and poly(ethylene) (E). The E block has 26 ethyl branches per 1000 backbone carbon atoms. Melt surface energies of the C and E blocks are 22.3 and 20.9 mJ/m 2, respectively. Grazing-incidence small-angle X-ray scattering (GISAXS), scanning force microscopy (SFM), and cross-sectional transmission electron microscopy (TEM) show that cylindrical and lamellar CEC triblock copolymers orient their microdomains normal to the surface throughout the film thickness. However, a lamellar CE diblock …

Severe Plastic Deformation Using Friction Stir Processing, And The Characterization Of Microstructure And Mechanical Behavior Using Neutron Diffraction, Wanchuck Woo

Doctoral Dissertations

Friction-stir welding (FSW) is a solid-state joining process, which utilizes a cylindrical rotating tool consisting of a concentric threaded tool pin and tool shoulder. The strong metallurgical bonding during the FSW is accomplished through: (1) the severe plastic deformation caused by the rotation of the tool pin that plunges into the material and travels along the joining line; and (2) the frictional heat generated mainly from the pressing tool shoulder. Recently, a number of variations of the FSW have been applied to modify the microstructure, for example, grain refinements and homogenization of precipitate particles, namely friction-stir processing (FSP). Applications of …

Titanium Alloyed With Boron, Seshacharyulu Tamirisakandala, Daniel B. Miracle, Raghavan Srinivasan, Jay S. Gunasekera

Mechanical and Materials Engineering Faculty Publications

Small additions of boron to conventional titanium alloys have been found to produce significant changes to the microstructures and associated properties. Grain refinement and improved strength and stiffness are first-order effects, which lead to possibilities for developing novel and affordable processing methodologies and to enhance performance over conventional titanium alloys. In this article, we introduce this new class of titanium alloys and describe unique formability benefits achieved via engineering microstructures.

Development Of Flame Retardant Polyphosphoric Acid Coating Based On The Polyelectrolyte Multilayers Technique, K Srikulkit, C Iamsamai, S T. Dubas

Journal of Metals, Materials and Minerals

Polyelectrolyte multilayer (PEM) thin films were deposited on silk by sequential deposition of Chitosan and polyphosphoric acid. This PEM composition takes advantage of synergetic effect of the phosphorus and the nitrogen to provide an efficient coating, which prevents fiber decomposition at high temperature. Prior to the PEM assembly on silk fibers, the growth of the film was initially monitored using an atomic force microscopy (AFM). Films formed on silicon wafer after 10, 20, 30, 40 and 60 layers showed somewhat linear increase, which is consistent with the PEM technique. A total thickness ranging from 10 to 107 nm for the …

Uv Radiation Energy Consumption In Curing Process Of Epoxidized Sunflower Oil-Organoclay Hybrid Coatings, N Jiratumnukul, R Intarat

Journal of Metals, Materials and Minerals

Epoxidized sunflower oil (ESO) can be cured with ultraviolet radiation using either cationic or hybrid initiation. The organoclay was prepared by the cationic exchange process, in which sodium ions were replaced by alkyl ammonium ions. Organoclay was incorporated into epoxidized sunflower oil UVcurable systems. The effects of diluents and types of photo initiators were studied. It was found that the formulations with a hybrid photoinitiator required less energy in the curing process than those with a cationic photoinitator. Moreover, the formulations without diluent can be cured with lower radiation energy than those with diluent.

Ph Dependant Coating For Microfluidics Devices, L Limsavarn, C Panithipongwut, P Thongkorn, S T. Dubas

Journal of Metals, Materials and Minerals

The layer-by-layer technique was used to coat the channels of PDMS microfluidics devices. The coating was based on the sequential deposition of polydiallyldimethylammonium chloride (PDADMAC) with a copolymer of polystyrene sulfonate and maleic acid (CoPSS-Maleic) into polyelectrolyte multilayer (PEM). The possible deposition of PEM coating on PDMS was confirm by contact angle which showed the clear transformation of the PDMS surface from hydrophobic to hydrophilic. The later deposition of the PEM coating inside the micro-channels was confirmed by change in electroosmotic flow direction (EOF) and intensity as a function of the number of deposited layers. The EOF measurements revealed that …

Techniques To Improve Coating Adhesion Of Superhard Coatings, N Panich, P Wangyao, N Vattanaprateep, S Yong

Journal of Metals, Materials and Minerals

This work addresses the development of different techniques in fabricating TiB2 coatings with increased adhesion to the substrate and with retained high hardness. Titanium diboride (TiB2) coatings were deposited on high-speed steel substrates by magnetron sputtering of a TiB2 target. Attempts to enhance the coating adhesion to the substrate of the TiB2 coatings by controlling the deposition conditions and parameters are presented, such as effect of substrate rotation; annealing temperature; using deposited Cr as an interlayer material and Ti/TiB2 multilayer system. The structure of the coatings was examined by X-ray diffraction, field-emission scanning electron microscopy, and atomic force microscopy. The …

Electrochemical Oxidation Process For Mineralization Of Solvent, A Charoensri, F Kobayashi, A Kimura, J Ishii

Journal of Metals, Materials and Minerals

A silver mediated electrochemical oxidations is a promising technique for the destruction of organic compounds. The destruction of 30%tributyl phosphate in dodecane in a nitric acid medium containing electrogenerated Ag(II) to carbon dioxide was studied by using a laboratory scale electrochemical oxidation cell. The electrolyte used in this system was 0.5 M AgNO3 in the range of 3 - 7 M HNO3, at operating temperatures of 60ºC ± 5ºC, under ultrasonic agitation and the output of a DC power supply at constant the current was 60 A, respectively. Electrolysis was carried out for 5 hours. The results show that, in …

Investigation Of The Band Structures And Optical Properties Of Super Lattices, Sheikha Ahmed Awad Alnaeme

Theses

Group III nitrides are highly attractive materials because of their great potential for the development of optoelectronic devices in short wavelength, semiconductor lasers and optical light-emitters and detectors. GaN, AlN and InN are considered as the most important compounds in this class of materials. In this work, we present a theoretical investigation of the electronic properties (band structure, density of state and contour maps of the charge density distribution) and optical properties (refractive index, absorption and dielectric constants). Also, we investigate the band structures and optical properties of AlN/GaN and InN/GaN super lattices. A full-potential linearized plane-wave (FPLAPW) method is …

Reheat Treated Microstructures And Gamma Prime Particle Coarsening Behaviour At 900˚C Of Cast Nickel Based Superalloy In-738, S Polsilapa, P Sopon, N Panich, N Chuankrerkkul, A Thueploy

Journal of Metals, Materials and Minerals

Long-term isothermal exposure tests were conducted on IN-738 alloy to evaluate the variation of gamma prime particle coarsening behavior after different rejuvenated heat treatment conditions. The longterm thermal exposure tests (up to 2,500 hours) were conducted at 900˚C to assess gamma prime particle coarsening behavior. Metallographic work had been performed on isothermally aged samples to characterize gamma prime coarsening as a function of heating time. At all investigated heating times, the gamma prime particles in all tested specimens were coarser than the initial reheat treated ones. The gamma prime particles appeared to coarsen more into a round shape or agglomerated …

Effect Of Decarburization On Microstructure Of Dc-Plasma Nitrided H 13 Tool Steel, P Visuttipitukul, C Paa-Rai, K Hideyuki

Journal of Metals, Materials and Minerals

Decarburization may occur during heat treatment of H13 steel resulting in carbon deficiency near the specimen surface. Microstructures and properties of H13 tool steel after surface treatment such as plasma nitriding can be affected by decarburization. This study is focused on the microstructure of plasma nitrided H13 steel. Decarburized and non-decarburized H13 steel was plasma nitrided for 36-72 ks at temperatures varying from 773 to 823 K. The microstructure of the plasma nitrided layer was analyzed by an optical microscope and Electron Probe Micro Analysis (EPMA). The thickness of the nitriding layer is measured. The microstructures of the decarburized and …

The Influence Of The Strain Rate On The Material Properties Of The Zinc-Coated Sheet, Z Vadasová, M Mihaliková

Journal of Metals, Materials and Minerals

In this paper the influence of the strain rate on the material properties of the zinc-coated sheet of the thickness (1; 1.5; 1.8) mm made from low-alloyed steel ZINKODUR 340 was analyzed. Increasing the strain rate is one of the possible ways to increase cold mechanical work in products. The tensile test is the most useful method for determining the material characteristic such as ductility. This contribution analyzes the influence of loading rate in range from 1 to 1000mm/min on material characteristics of tested steel during the tensile test. Strain rate is one of the most significant factors, which affected …