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Magnetic Field Assisted Milli-Scale Robotic Assembly Machine: An Approach To Massively Parallel Swarm Robotic Automation Systems, Yan Liu

Dissertations

The vision of highly parallel, automated manufacturing systems that can build macroscopic products by heterogeneous assembly of many small devices will have a major impact in manufacturing. In this study, a novel milli-scale robotic assembly machine with parallel capabilities, assisted with programmable magnetic field, is developed. The machine prototype consists of a 16x16 array of electromagnets. The dimensions of the electromagnets are 5mm high with an inner diameter of 1.1mm and outer diameter of 2.5mm. All the electromagnets are driven by a 16x16 array of H-Bridges, and an Arduino microcontroller is used to control and program the arrays.

Using the …

Development Of Flexible Nickel-Zinc And Nickel-Iron Batteries, Xianyang Meng

Dissertations

The fabrication of flexible nickel-zinc batteries using a facile mixing of electroactive components for electrode preparation is presented. Polytetrafluoroethylene (PTFE) is found to be an effective binder by reducing concentration polarization, providing chemical/physical stability and enhancing flexibility. The zinc electrode containing PTFE maintains its original porous morphology even after hundreds of cycles while polymers such as PEO show morphology change. Each component, as well as the assembled flexible cells show desired flexibility and stability even under bending conditions.

The fabrication of flexible nickel-iron batteries using printable composite electrodes embedded with multiwalled carbon nanotubes (CNT) is also presented. All the metal …

Analysis Of 3d Printed Ndfeb Polymer Bonded And Organic Based Magnets, Chimaobi Ibeh

Theses

Additive manufacturing (AM), or commonly known as 3D printing, has introduced to the manufacturing and commercial sectors novel ways of reducing production times, decreasing material waste, and enabling end products with multi-material configuration and complex geometric designs. From industrial scale to customer-based printers, AM has revolutionized the approach to manufacturing, prototyping, and designing in the field of medical, automotive, aerospace, biomedical, electronics and customizable products. Recently, additive manufacturing has crossed over to the area of applications in magnetism due to the economic push for the miniaturization of electronic and mechanical devices, reduction in production costs and material & design flexibility. …

Metal Thin Film Stiffness Extraction Technique For Surface Acoustic Wave Filters, Travis R. Weismeyer

Electronic Theses and Dissertations

Accurate knowledge of the surface acoustic wave (SAW) properties propagating at the surface of a piezoelectric substrate with thin films, electrodes or temperature compensated films, is critical in SAW filter design to meet the target frequency response, power durability and performance prior to device fabrication. While reliable material constants exist for substrates such as LiNbO3 used in SAW filters, the absolute elastic constants associated with operational thin films used for electrodes or temperature compensation do not exist. Although the bulk values of the constituent materials are known, the composite film/substrate properties are difficult to predict since they depend strongly on …

Modeling And Simulation Of The Thermoforming Process In Thermoplastic-Matrix Composite Materials, Philip M. Bean

Electronic Theses and Dissertations

Thermoplastic-matrix composite materials have unique advantages over traditional thermosets including faster processing, improved fracture toughness, and recyclability. These and other benefits have caused increasing interest in the use of these materials in both aerospace and automotive industries. Due to the differences in behavior, these materials require a different type of manufacturing process to thermoset matrix composites. This manufacturing process generally involves using pre manufactured tape-layers. These layers, containing both thermoplastic-matrix and fiber-reinforcement, are aligned to the desired orientation, and stacked up into a “tailored blank” using an automated tape layup machine. They are then heated to the thermoplastic melting temperature …

Strategies For The Stabilization Of Metal Anodes For Li And Na Metal Batteries, Yang Zhao

Electronic Thesis and Dissertation Repository

Li-metal batteries (LMBs) and Na-metal batteries (NMBs) are considered as the promising candidates to replace the conventional Li-ion batteries (LIBs) due to their high theoretical energy density. For LMBs and NMBs, Li metal and Na metal are the ultimate choices to achieve their high energy density due to the high specific capacity, low electrochemical potential and lightweight. However, as alkali metals, both Li and Na metal anodes suffer from serious challenges including 1) Li/Na dendrite formations and short circuits; 2) Low Coulombic efficiency (CE) and poor cycling performance; and 3) Infinite volume changes. This thesis mainly focuses on the design …

Electroless Nickel Plating And Spark Plasma Sintering Of Nano Zro2 For Mechanical Property Enhancement, Kunlong Jia

McKelvey School of Engineering Theses & Dissertations

A new approach of combined electroless nickel plating (ENP) and spark plasma sintering (SPS) was used to determine the feasibility of fracture toughness improvement of ZrO2. Nano-grained yttria stabilized zirconia (YSZ) particles of 100nm average diameter were coated with about 1-5 nm of nickel coating by ENP. To reduce nano particle agglomeration throughout the ENP process; vigorous agitation with an ultrasonic horn was used. The coated powder was characterized using Scanning Electron Microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDX) and Transmission electron microscopy (TEM) to study the microstructure and coating characteristics. The coating was identified to be predominantly nickel and of …

Elevated Temperature Progressive Damage And Failure Of Duplex Stainless Steel, Darren P. Luke

Civil Engineering ETDs

Ductile failure of metals has been the focus of research efforts within academia and industry for many years since it is tremendously important for understanding the failure of structures under extreme loading conditions. However, limited research has been dedicated to elevated temperature ductile failure, which is critical for evaluating catastrophic events such as industrial, structural or shipping vessel fires. A detailed investigation was conducted on the structural response of Duplex Stainless Steel at elevated temperatures. The temperature dependence of elastic modulus, yield strength, ultimate strength, and ductility was measured up to 1000°C and a continuum damage plasticity model was developed. …

Tunable Electronic And Optical Properties Of Low-Dimensional Materials, Shiyuan Gao

Arts & Sciences Electronic Theses and Dissertations

Two-dimensional (2D) materials with single or a few atomic layers, such as graphene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMDCs), and the heterostructures or one-dimensional (1D) nanostructures they form, have attracted much attention recently as unique platforms for studying many condensed-matter phenomena and holds great potentials for nanoelectronics and optoelectronic applications. Apart from their unique intrinsic properties which has been intensively studied for over a decade by now, they also allow external control of many degrees of freedom, such as electrical gating, doping and layer stacking. In this thesis, I present a theoretical study of the electronic and …

Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …

Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang

McKelvey School of Engineering Theses & Dissertations

Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …

Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang

McKelvey School of Engineering Theses & Dissertations

Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …

Linking Structure And Dynamics In Metallic Liquids: A Combined Experimental And Molecular Dynamics Approach, Robert Ashcraft

Arts & Sciences Electronic Theses and Dissertations

A major outstanding problem in condensed matter physics is the nature of the glass transition, in which a rapidly cooled liquid can bypass the transition into a crystalline state and the liquid structure is "frozen-in" due to kinetic arrest. To characterize the fundamental features behind this transition the liquid, both in the high temperature (equilibrium) and supercooled state, needs to be better understood. By examining the relationship between structure and dynamics a better characterization of the liquid state and a determination of the mechanisms that are ultimately important for the formation of the glass can be gained. In this dissertation, …

Corrosion Dynamics Of Carbon Steel In Used Fuel Container Environments, Dan Guo

Electronic Thesis and Dissertation Repository

The current Canadian used nuclear fuel container (UFC) design uses a pressure‑grade carbon steel (CS) vessel with its outer surface coated with a thin layer of copper. One concern regarding the structural integrity of the UFC design is the potential internal corrosion of the CS vessel. Moisture trapped inside a UFC could condense within the gap between the hemispherical head and the cylindrical body of the vessel. The internal UFC environment will be exposed to a continuous flux of ionizing radiation arising from the decay of radionuclides trapped in the used UO₂ fuel matrix.

This thesis research project investigates …

Improving Ductility Of Slender Reinforced Concrete Shear Walls With Frp Sheets And Splay Anchors, Luke M. Ostrom

Architectural Engineering

The Sylmar earthquake of 1971 caused significant damage to slender, non-ductile reinforced concrete (RC) shear wall buildings in California. A later survey by the Concrete Coalition in 2011, under the guidance of EERI members, indicated that there are over 3000 vulnerable concrete buildings in California [8]. This led to City of Los Angeles (LA) Ordinance 193893 enacted in 2015, which requires mandatory upgrades to these concrete buildings by 2035. Current practice to meet the requirements of this ordinance, with respect to RC wall buildings, involves adding new shear walls to the building plan or increasing the cross-sectional area of existing …

Fabrication Of Silver-Doped Zinc Oxide Thin Films Through Optimized Sol-Gel Deposition And Nanoparticle Wetting Process, Reed T. Heintzkill

Theses and Dissertations

Zinc Oxide (ZnO) has been of significant interest as a Transparent Conductive Oxide (TCO) given its sizable direct band-gap, and as a potential substitute for Indium-Tin Oxide for use in opto-electronic and piezo-electric devices, due to its comparatively abundant and nontoxic precursor materials. Sol-gel processing is an easy, low-energy method for fabricating ZnO thin films, and there has been increasing interest in doping the compound such to give it p-type semiconductive character.

This thesis thoroughly investigates sol-gel processing of ZnO thin solid films, with focus on wet-chemistry (sol-gel) methods of doping the material with silver (both as elemental ions and …

In Silico Analysis Of Advanced Processing Methods For Light-Weight Alloys Powders, Marjan Nezafati

Theses and Dissertations

Light-weight Al and Mg-based metal-matrix nanocomposites (MMNCs) are lauded as one of the most promising structural materials for vehicle, military, and construction applications. These MMNCs are often synthesized using the powder metallurgy (PM) process under liquid nitrogen cryogenic environments to control the grain sizes. It is believed that proper incorporation of the nitrogen species into the bulk lattice during processing could strongly enhance the mechanical properties of MMNCs by forming N-rich dispersoids. In this work, using the density-functional theory (DFT), the adsorption, absorption and diffusion behavior of nitrogen molecule/atoms have been studied and related to t Al and Mg MMNC …

Synthesis And Performance Analysis Of Polyethersulfone (Pes) Nanocomposite Membrane Grafted With Functionalized Iron (Ii, Iii) Oxide Nanoparticles For Arsenate Removal, Jiyoung Rowley

Theses and Dissertations

Arsenic (As) is one of the detrimental elements in nature, which has negative effect on human health as well as the environment. High levels of arsenic concentration in the drinking water can cause skin, bladder, lung liver, and prostate, as well as cardiovascular, pulmonary, immunological, neurological and endocrine diseases. Arsenic pollution in the water has been reported in many countries as a worldwide problem, including the United States.

To develop a separation method for removing Arsenic, various treatment technologies including precipitation, coagulation with ferric chloride or aluminum sulfate coagulants, ion exchange and adsorption with modified nanocomposite material have been extensively …

Measuring Characteristic Shrinkage Variability Due To Metal Loading Effects In Low Temperature Co-Fired Ceramic Using Image Processing, John Ezekiel Zumbro

Graduate Theses and Dissertations

Low temperature co-fired ceramic (LTCC) has many benefits when it comes to electronic packaging due to the low dielectric loss, reliability in extreme environments, and high breakdown voltage. Though the ceramic has a lot of benefits it is not widely used due to the high cost and complexities associated with manufacturing. One of these issues with manufacturing is compensating for the shrinkage of the ceramic, this is accomplished by using an expansion factor, creating the “green” or manufactured design. This expansion factor is approximated through knowledge of the ceramic factors such as the metal loading, layers of ceramic tape, firing …

Application Of Silicon Nanohair Textured P-N Junctions In A Photovoltaic Device, Michael Small

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for a silicon photovoltaic device which incorporates a nanohair textured p-n junction. The silicon nanowires are etched into a silicon wafer, comprising an epitaxial p-layer on n-substrate, via metal-assisted chemical etching (MACE). The resulting nanowires contain p-n junctions that lie along the length of the vertical nanowires. This construct has the potential to increase the optical bandwidth of a silicon photovoltaic device by allowing a greater amount of short wavelength light to reach the junction. In addition, the MACE method of nanofabrication has the potential for decreasing …

Optimization Of The Practice Of Slow Cooling Steel Bars: A Redesign And Modernization Of Materials, Eryn Johnston

Mechanical Engineering Undergraduate Honors Theses

Throughout the process of steel making, certain grades of steel are a higher risk for defects caused by the inability to quickly diffuse hydrogen through the steel when cooled to room temperature at a normal rate based on the ambient air temperature. To reduce the hydrogen flaking defects that are caused due to hydrogen entrapment in the steel, the process of slow cooling is utilized. This process reduces the cooling rate of steel bars by keeping them at a higher temperature for extended periods and in turn gives the hydrogen a chance to fully dissipate from the steel. In many …

Young’S Modulus As A Measurement To Estimate Damage Related With Alkali-Silica Reaction In Concrete., Anazaria J. Ortega Gonzalez

Civil Engineering Undergraduate Honors Theses

The main purpose of this research is to compare two nondestructive methods to assess Alkali-Silica reaction (ASR) in concrete. Fifteen concrete prisms were cast using aggregates with different Alkali-Silica reactivity such as Jobe sand and Van Buren sand. The change in strain, shear wave velocity and Young’s modulus were determined according to ASTM C129 and ASTM C215, respectively. This data was collected by Dillon K Self, who determined that the shear wave velocity and strain are inversely proportional. However, when single cracking in the concrete specimen transition to map cracking, the shear wave velocity dropped significantly, whereas the strain value …

Novel Engineered Porous Materials For The Removal Of Lead From Water, Mohsen Hajipour Hajipour Manjili

Theses and Dissertations

The estimated average blood lead level for the population younger than 5 years in the United States is approximately 100 times higher than ancient background levels, indicating that substantial sources of lead exposure exist in the environment. This research is focused on the removal of lead from water with a functionalized zeolite. Functionalization improves adsorption behavior to achieve adsorbent materials with high capacity and stability with potential multiple re-uses.

The lead sorption from water onto an Australian zeolitic mineral (clinoptilolite) unmodified and modified with sulfide-based reagents is investigated with batch and fixed bed column experiments. The effect of solution pH, …

Fabrication And Characterization Of Electrochemical Glucose Sensors, Mohammed Marie

Graduate Theses and Dissertations

Electrochemical sensors based on the nanostructure of the semiconductor materials are of tremendous interest to be utilized for glucose monitoring. The sensors, based on the nanostructure of the semiconductor materials, are the third generations of the glucose sensors that are fast, sensitive, and cost-effect for glucose monitoring.

Glucose sensors based on pure zinc oxide nanorods (NRs) grown on different substrates, such ITO, FTO, and Si/SiO2/Au, were investigated in this research. Silicon nanowire (NW)- based glucose sensors were also studied. First, an enzyme-based glucose sensor was fabricated out of glass/ITO/ZnO NRs/BSA/GOx/nafion membrane. The sensor was tested amperometrically at different glucose concentrations. …

Growth And Characterization Of Silicon-Germanium-Tin Semiconductors For Future Nanophotonics Devices, Bader Saad Alharthi

Graduate Theses and Dissertations

The bright future of silicon (Si) photonics has attracted research interest worldwide. The ultimate goal of this growing field is to develop a group IV based Si foundries that integrate Si-photonics with the current complementary metal–oxide–semiconductor (CMOS) on a single chip for mid-infrared optoelectronics and high speed devices. Even though group IV was used in light detection, such as photoconductors, it is still cannot compete with III-V semiconductors for light generation. This is because most of the group IV elements, such as Si and germanium (Ge), are indirect bandgap materials. Nevertheless, Ge and Si attracted industry attention because they are …

Growth And Behaviors Of Inn/Gan Multiple Quantum Wells By Plasma-Assisted Molecular Beam Epitaxy, Chen Li

Graduate Theses and Dissertations

Fully realizing the potential of InGaN semiconductors requires high quality materials with arbitrary In-content. To this date the growth of In-rich InGaN films is still challenging since it suffers from the low growth temperatures and many detrimental alloying problems. InN/GaN multiple quantum wells (MQWs) and super lattices (SLs) are expected to be promising alternatives to random InGaN alloys since in principle they can achieve the equivalent band gap of InGaN random alloys with arbitrarily high In-content and at the same time bypass many growth difficulties.

This dissertation focuses on studying the growth mechanisms, structural properties and energy structures of InN/GaN …

Comparative Study Of Power Semiconductor Devices In A Multilevel Cascaded H-Bridge Inverter, Kenneth Mordi

Graduate Theses and Dissertations

This thesis compares the performance of a nine-level transformerless cascaded H-bridge (CHB) inverter with integrated battery energy storage system (BESS) using SiC power MOSFETs and Si IGBTs. Two crucial performance drivers for inverter applications are power loss and efficiency. Both of these are investigated in this thesis. Power devices with similar voltage and current ratings are used in the same inverter topology, and the performance of each device is analyzed with respect to switching frequency and operating temperature. The loss measurements and characteristics within the inverter are discussed. The Saber® simulation software was used for the comparisons. The power MOSFET …

Polyhedral Oligomeric Silsesquioxane-Phosphate Glass Matrix Nanocomposites With Additional Chapter On Phosphate Glass-Poly(Ethylene Terephthalate) Matrix Composites, Kyoungtae Kim

Dissertations

Preparation and characterization of tin fluorophosphate glass (Pglass) matrix nanocomposites incorporating polyhedral oligomeric silsesquioxane (POSS) were investigated on the structural, thermal, morphological, mechanical, and rheological properties. Various processes including synthesis, extrusion and sintering processes were applied to prepare the nanocomposite samples. Another application of POSS with hydrophobic functional groups on the well-structured nanoscale silicate cage with three silanol groups was investigated to present the feasibility to use POSS molecule as a coating material on the surface of the hydrophilic inorganic glass. In addition, Poly(ethylene terephthalate) polymer matrix composites incorporating Pglass was studied to present the benefits of the Pglass with …

Hydrogen Bond Mediated Water Structuring, Diffusion, And Elastic Properties In Acrylamide Copolymer Glycohydrogels, April Levu Fogel

Dissertations

Glycohydrogels have recently gained considerable interest as biocompatible and high water content hydrogels that have similar physicochemical nature to the cell membrane, making them ideal materials for targeted biomedical and personal care applications (e.g., drug delivery systems, biosensors, and contact lenses). Regardless of the specific application, water-polymer and water-water hydrogen bonding interactions have been shown to dictate hydration stability and diffusional properties in traditional hydrogel architectures (e.g., crosslinked HEMA). However, due to the development of glycohydrogel materials within the past two decades, most literature focuses on synthetic techniques and general hydration characteristics. Furthermore, scant literature examines the effect of hydrophobically …

Reinventing The Wheel, Esther K. Unti, Ahmed Z. Shorab, Patrick B. Kragen, Adam M. Menashe

Mechanical Engineering

Reinventing the Wheel selected tires and designed wheels for the 2018 Cal Poly, San Luis Obispo Formula SAE combustion vehicle. Available tire options were evaluated for steady-state and transient performance as well as vehicle integration. A single-piece composite wheel with hollow spokes was designed to meet stiffness, strength, and tolerance requirements. A detailed study of wheel loading and geometric structural efficiency was performed. Finite element analysis was used to iterate the geometry and laminate. A two-piece male mold was designed and machined to manufacture the wheel. Removable silicone inserts were used to create the hollow spokes.