Digital Commons Network^™

Thermal And X-Ray Analysis On The Origin Of Double Melting Phenomena Of Poly(L-Lactic Acid) Films, Xiaoyun Ling

Doctoral Dissertations

Thermal analysis is one of the most commonly used techniques to characterize the structure and properties of semicrystalline polymers. Unfortunately, the interpretation of thermal events is not always straightforward, but can be quite complicated. However, the complexity involved is often overlooked, leading to erroneous or, at least, questionable results and interpretations. In the present study we carry out an extensive investigation of the thermal behavior of poly(L-lactic acid), PLLA, films prepared under a wide range of crystallization conditions, including isothermal and non-isothermal crystallization from both the glassy state and the melt. The primary techniques used were differential scanning calorimetry (DSC), …

High-Temperature Low-Cycle-Fatigue And Crack-Growth Behaviors Of Three Superalloys: Hastelloy ® X, Haynes ® 230, And Haynes ® 188, Yulin Lu

Doctoral Dissertations

Extensive smooth-bar low-cycle-fatigue (LCF) and fatigue crack growth (FCG) experiments on three solid-solution-strengthened superalloys HASTELLOY X, HAYNES 230, and HAYNES 188 have been conducted at 816 and 927 C. Limited tests were run at 649 C, 871 C, and 982 C to study the temperature effect. The LCF tests were performed under a total-strain-range-control mode at Solar Turbines Inc., Metcut Research Inc., and The University of Tennessee (UT). The FCG tests were done under both the constant-load-range and constant-stress-intensity-factor-range modes at Westmoreland Testing Inc. and UT. Various hold times were imposed at the maximum strain or load in both the …

The Effect Of Ultrasonic Vibration On The Solidification Of Light Alloys, Xiaogang Jian

Doctoral Dissertations

This exposition presents the novel thermodynamical and microstructural modification to light alloys, such as aluminum alloys and magnesium alloys, by ultrasonic vibrations during their solidification processes. Ultrasonic vibration has proven to be effective in controlling columnar dendritic structure, reducing the size of equiaxed grains, and under some conditions, producing globular non-dendritic grains. Despite this, the solidification process under the effect of ultrasonic vibration was not clear. Not only was there no such research on how ultrasonic vibration affected its solidification thermodynamically, but also its effects on the as-cast microstructure, including the primary fcc phase, the eutectics, and the secondary phases, …

Experimental, Theoretical, And Device Application Development Of Nanoscale Focused Electron-Beam-Induced Deposition, Steven Jeffrey Randolph

Doctoral Dissertations

To elucidate the effects of beam heating in electron beam-induced deposition (EBID), a Monte-Carlo electron-solid interaction model has been employed to calculate the energy deposition profiles in bulk and nanostructured SiO₂. Using these profiles, a finite element model was used to predict the nanostructure tip temperatures for standard experimental EBID conditions. Depending on the beam energy, beam current, and nanostructure geometry, the heat generated can be substantial. This heat source can subsequently limit the EBID growth by thermally reducing the mean stay time of the precursor gas. Temperature dependent EBID growth experiments qualitatively verified the results of the …

Effect Of Hydrogenon On Mechanical Behavior Of A Zircaloy-4 Alloy, Elena Garlea

Masters Theses

Hydride formation is one of the main degradation mechanisms of zirconium alloys in hydrogen-rich environments. When sufficient hydrogen is present, zirconiumhydride precipitates can be formed. Cracking of the brittle hydrides near a crack tip can initiate the growth of a crack leading to the premature failure of the material. Hydride formation is believed to be enhanced by the presence of residual or applied stresses. Therefore, the increase in the stress field ahead of a crack tip may promote precipitation of additional hydrides. In order to verify these phenomena, the effect of internal stresses on the zirconium-hydride-precipitate formation, and in turn, …

The Development Of Qualification Standards For Cast Super Duplex Stainless Steel (2507 Wrought Equivalent), Vasudevan Hariharan

Masters Theses

The objective of the program is to determine the suitability of ASTM A923 “Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels” for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A).

Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived …

An Experimental Evaluation Of The Constant Β Relating The Contact Stiffness To The Contact Area In Nanoindentation, Jeremy Harper Strader

Masters Theses

Measurements of mechanical properties by nanoindentation with triangular pyramidal indenters like the Berkovich rely heavily upon the relationship between the contact stiffness, S, the contact area, A, and the reduced elastic modulus, E_r . This relationship is often written in the form: S = 2βEr(A/π)1/2, where βis a constant that depends on the geometry of the indenter. Although the most common values for βused in experimental measurements are 1.000 and 1.034, various theoretical analyses have yielded values as small as 1.00 or as large as 1.2, depending on the assumptions made to model the deformation. Here the most appropriate …

Synthesis, Microstructure, And Mechanical Behavior Of Fe-Cu Composites, Jin-Woo Jeon

Masters Theses

The synthesis, microstructure, and mechanical properties of ball-milled nanocrystalline (nc) Fe powder and immiscible Fe-Cu alloy composites are investigated in this thesis. Experimental approaches are described for the characterization of the grain size and hardness of nc Fe powders and the internal stress state of bulk Fe-Cu alloy composites are presented.

The grain size measurements of ball-milled Fe powders obtained from the XRD line broadening analysis (15 nm) and TEM observation (18 nm) showed good agreement between two results. From the nanoindentation tests, the hardness values of the ball-milled Fe powders were increased from 3.5 to 10.5 GPa as the …

Fatigue Behavior Of A Zirconium-Based Bulk Metallic Glass, William Hutchison Peter

Doctoral Dissertations

Although the mechanical behavior of Zr-based bulk metallic glasses (BMGs) has been studied, fatigue studies in controlled environments and testing conditions have not been adequately performed or understood. Early fatigue examinations of rectangular bar specimens tested in bending had resulted in fatigue strengths substantially lower than anticipated [1,2,3,4,5]. Preliminary work performed by Peter et al. and Wang et al. on uniaxial button-head specimens have yielded in very different fatigue behavior with fatigue-endurance limits comparable to conventional high-strength, crystalline alloys [6,7,8,9,10]. Between all S-N results studied, the fatigue-endurance limits for Zr-based BMGs have been observed to range from 150 MPa to …

The Mechanical And Electrochemical Properties Of Bulk Metallic Glasses, Mark Lee Morrison

Doctoral Dissertations

Bulk metallic glasses (BMGs) represent an emerging class of materials with an amorphous structure and a unique combination of properties. Some of these outstanding properties include exceptionally high strength, large elastic deformation, near-net-shape formability, and superplasticity. However, these materials are not commonly used in structural applications because of a lack of plasticity and a lack of clarity in terms of deformation and failure mechanisms. Furthermore, the electrochemical behavior of these materials with and without loading is not well defined. Thus, the objectives of this study were to define and model the electrochemical and mechanical behaviors of BMGs, in addition to …

Microstructural Evolution Of Tial-Intermetallic Alloys Containing W And B, Lan Huang

Masters Theses

The TiAl alloys have been considered as promising candidates for structural-materials applications at around 800⁰C. In this work, new TiAl alloys, containing tungsten (W) and boron (B), have been developed. Using the scanning-electron microscopy (SEM), electron-microprobe, and transmission-electron microscopy (TEM), the effects of W and B on the microstructural evolution of TiAl alloys, including the colony size and lamellar spacing, were analyzed. It is important to point out that fine uniform microstructures (with the colony size smaller than 50 mm) can be conveniently developed after Hot-Isostatic Pressing (HIP) the as-cast alloys at 1,250⁰C and 150 MPa …

Thin Film Sputtering Of Gadolinium And Chromium-Doped Yttrium Aluminum Garnet, Yuepeng Deng

Doctoral Dissertations

Rare-earth and transition metal-doped yttrium aluminum garnet (Y₃A1₅O₁₂ or YAG) phosphors have been widely used because of very stable chemical, mechanical properties of YAG and subsequent high efficiency of doped YAG phosphors. However, to synthesize pure YAG materials by different approaches such as solid-state reaction, sol-gel, spray pyrolysis, co-precipitation, and combustion method. But nearly all of these techniques require high temperature (>1600C) and prolonged processing time.

In this work, rf magnetron reactive sputtering was used to synthesize YAG thin films at relatively low temperature and short processing period. An appropriate post heat treatment, 10 …

Fabrication And Characterization Of Nanoelectronic Devices For Electron Beam Lithography Applications, Xiaojing Yang

Doctoral Dissertations

Vertically aligned carbon nanofibers (VACNFs) have shown promise for use as field emission electron sources. Dual-gate field emission structures (triodes) have been fabricated and characterized. The electron beams can be successfully focused in these triodes. These studies show VACNF based field emission devices are promising for electron beam lithography applications. In this thesis, work is continued on triode device investigation. Methods to improve the device fabrication, to understand/optimize the device performance, and to repair defective triodes are presented.

Numerical simulation of the triode performance is included. Depth of field (DOF) of these triode structures is calculated by simulation and is …

Charge Transport Measurements Of Vertically Aligned Carbon Nanofiber, Lan Zhang

Doctoral Dissertations

Vertically aligned carbon nanofibers (VACNFs) have found a variety of electronic applications. To further realize these applications, a good understanding of the charge transport properties is essential. In this work, charge transport properties have been systematically measured for three types of VACNF forests with Ni as catalyst, namely VACNFs grown by direct current PECVD, and inductively coupled PECVD at both normal pressure (3.6 Torr) and low pressure (50 mTorr).

The structure and composition of these nanofibers have also been investigated in detail prior to the charge transport measurements. It has been found that the dc VACNF body consists of three …

Investigation Of A Phase Transition In Pure And Magnesia- And Titania-Substituted Hexacelsian, Melanie Jean Kirkham

Masters Theses

Hexacelsian, the hexagonal polymorph of BaAl_{2Si2O8, experiences a phase transition near 300ºC with an accompanying large volume change, which can lead to cracking and thermal shock, limiting the potential applications of hexacelsian. It has previously been reported that certain additions, including MgO and TiO2, can suppress the undesirable phase transition. Room-temperature neutron and high-temperature X-ray diffraction have been used to study the structure and thermal behavior of hexacelsian, both pure and substituted with varying amounts of MgO and TiO2. The diffraction data of the pure sample was refined using the}

P-3 space group. Attempting to refine the substituted sample …

Fundamental Studies Of Stabilization Of Polyacrylonitrile Precursor, Stephen Alan White

Masters Theses

The purpose of this study was to examine the stabilization of polyacrylonitrile precursor. Currently, the stabilization of polyacrylonitrile is the limiting step in the production of carbon fibers because of its cost and time requirements. By furthering the understanding of the stabilization process, it may be possible to reduce the cost and time required, allowing the widespread use of carbon fiber in several industries to be achieved.

In this study, the effects of temperature, time, environment, and pressure on the stabilization of polyacrylonitrile were examined. Once fiber samples were heat treated, four experimental techniques were used to examine the samples. …