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Materials Science and Engineering

University of Central Florida

Solar cells

Publication Year

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Correlation Between Preparation Parameters And Properties Of Molybdenum Back Contact Layer For Cigs Thin Film Solar Cells, Eigo Takahashi Jan 2010

Correlation Between Preparation Parameters And Properties Of Molybdenum Back Contact Layer For Cigs Thin Film Solar Cells, Eigo Takahashi

Electronic Theses and Dissertations

Molybdenum (Mo) thin film back contact layers for thin film CuIn(1-x)GaxSe2 (CIGS) solar cells were deposited onto soda lime glass substrates using a direct current (DC) planar magnetron sputtering deposition technique. Requirements for the Mo thin film as a back contact layer for CIGS solar cells are various. Sheet resistance, contact resistance to the CIGS absorber, optical reflectance, surface morphology, and adhesion to the glass substrate are the most important properties that the Mo thin film back contact layer must satisfy. Experiments were carried out under various combinations of sputtering power and working gas pressure, for it is well known …


Preparation Of Efficient Cuin1-Xgaxse2-Ysy/Cds Thin-Film Solar Cells By Optimizing The Molybdenum Back Contact And Using Diethylselenide As Selenium Precursor, Ankur Kadam Jan 2006

Preparation Of Efficient Cuin1-Xgaxse2-Ysy/Cds Thin-Film Solar Cells By Optimizing The Molybdenum Back Contact And Using Diethylselenide As Selenium Precursor, Ankur Kadam

Electronic Theses and Dissertations

High efficiency CuIn1-xGaxSe2-ySy (CIGSS)/CdS thin-film solar cells were prepared by optimizing the Mo back contact layer and optimizing the parameters for preparing CIGSS absorber layer using diethylselenide as selenium source. The Mo film was sputter deposited on 2.5 cm x 10 cm soda-lime glass using DC magnetron sputtering for studying the adhesion and chemical reactivity with selenium and sulfur containing gas at maximum film growth temperature. Mo being a refractory material develops stresses, nature of which depends on the deposition power and argon pressure. It was found that the deposition sequence with two tensile stressed layers deposited at 200W and …


Solar Driven Photoelectrochemical Water Splitting For Hydrogen Generation Using Multiple Bandgap Tandem Of Cigs2 Pv Cells And Thin Film Photocatalyst, Anant Jahagirdar Jan 2005

Solar Driven Photoelectrochemical Water Splitting For Hydrogen Generation Using Multiple Bandgap Tandem Of Cigs2 Pv Cells And Thin Film Photocatalyst, Anant Jahagirdar

Electronic Theses and Dissertations

The main objective of this research was to develop efficient CuIn1-xGaxS2 (CIGS2)/CdS thin film solar cells for photoelectrochemical (PEC) water splitting to produce very pure hydrogen and oxygen. Efficiencies obtained using CIGS2 have been lower than those achieved using CuInSe2 and CuIn1-xGaxSe2. The basic limitation in the efficiencies is attributed to lower open circuit voltages with respect to the bandgap of the material. Presently, the main mechanism used to increase the open circuit voltage of these copper chalcopyrites (CuInSe2 and CuInS2) is the addition of gallium. However, addition of gallium has its own challenges. This research was intended to (i) …