Digital Commons Network^™

Studies Of The Mechanism Of Electron Beam Induced Deposition (Ebid), Young Ryong Choi

Doctoral Dissertations

The controlled deposition of metals resulting from the passage of an ion beam through an atmosphere of a suitable precursor gas is a well-established procedure for micro scale materials manipulation. While the ion beam technique is rapid and reliable it has the disadvantage that the beam itself can ablate and contaminate the target with Gallium or other materials, and the fact that ion optics are less widely accessible than electron optical columns. We have therefore been investigating the theory and practice of depositing metal using an electron beam and variety of precursor gases. The aim of this work is to …

Thermal Stability Of Binary Cr-Cr3Si And Ternary Nial-Mo Eutectic Alloys, Aravind Gali

Doctoral Dissertations

The thermal stability of multiphase intermetallics at temperatures to 1400°C was investigated by studying two model eutectic systems: Cr-Cr₃Si having a lamellar microstructure and NiAl-Mo having a fibrous microstructure. In drop cast Cr-Cr₃Si, coarsening was found to be interface controlled. The coarsening rate could be significantly reduced by microalloying with Ce and Re, two elements which were chosen because they were expected to segregate to the Cr-Cr₃Si interfaces and decrease their energies. Similarly, directional solidification, which is also expected to lower the Cr- Cr₃Si interfacial energy, was found to dramatically decrease the …

An Investigation Of The Deposition And Characterization Of Materials Formed By Electron Beam Induced Deposition, Wei Li

Doctoral Dissertations

This dissertation deals with EBID – Electron Beam Induced Deposition – a novel bottom up nanofabrication technique. Since EBID was first employed for nano-patterning, a number of empirical factors were investigated to control deposition process. Meanwhile a few theoretical models were proposed based on some fundamental assumptions. So far little work has been done to verify the validity of these assumptions. The main objective of my PhD study, therefore, was to answer whether these assumptions are valid so that unifying the empirical factors and theoretical models would be possible. Electrical resistivity of deposited materials was another interesting topic included in …

A Study Of The Relationship Between Indentation Creep And Uniaxial Creep, James Anthony Lamanna Jr.

Doctoral Dissertations

The purpose of this work is to further the scientific understanding of the relationship between indentation creep and uniaxial creep. The data for this study was obtained by conducting both indentation and uniaxial creep experiments on amorphous selenium. Experiments were designed to collect data over a wide range of creep rates. Specific temperatures were chosen to collect creep data above and below the glass transition temperature of 31°C. The indentation and uniaxial compression data was used to accomplish several objectives.

The first objective was to test the ability of the Oliver-Pharr stiffness equation to predict contact area. The current contact …

Pseudoelasticity And Shape Memory Effect In Single Crystal Fe3Al, Saurabh Kabra

Doctoral Dissertations

Fe₃Al is an intermetallic compound which has shown some excellent engineering properties and has been widely studied for this reason. It also shows interesting mechanical phenomenon like yield stress anomaly and pseudoelasticity. Mechanical behavior and diffraction studies on the pseudoelastic aspect of Fe₃Al have been presented in this work.

Single crystalline, D0₃ ordered Fe₃Al is known to show pseudoelastic behavior at room temperature. Pseudoelastic behavior was seen in both tension and compression with a distinct tension-compression asymmetry. No strain hardening occurred under tension even at high applied strains as opposed to compression, …

Methylsilane Derived Sic Particle Coatings Produced By Fluid-Bed Chemical Vapor Deposition, James Henry Miller

Doctoral Dissertations

This report describes the research effort that was undertaken to develop and understand processing techniques for the deposition of both low and high density SiC coatings from a non-halide precursor, in support of the Generation IV Gas-Cooled Fast Reactor (GFR) fuel development program.

The research was conducted in two phases. In the first phase, the feasibility of producing both porous SiC coatings and dense SiC coatings on surrogate fuel particles by fluidized bed chemical vapor deposition (FBCVD) using gas mixtures of methylsilane and argon was demonstrated. In the second phase, a combined experimental and modeling effort was carried out in …

Effects Of Temperature And Grain Size On The Transformation And The Deformation Behaviors Of The Trip (Transformation Induced Plasticity) Steels, Kaixiang Tao

Doctoral Dissertations

Two types of TRIP steels, a commercial 304L stainless steel and an Fe-10%Cr-5%Ni-8%Mn steel, have been used to investigate the effects of temperature and grain size on the transformation and mechanical behaviors. 304L SS was used to investigate the effects of temperature ranging from 300K to 77K, while the Fe-10%Cr-5%Ni-8%Mn steel was used for the investigation of the effects of the grain size at 300K.

At 203K, the fcc grains of the 304L SS with {200} plane normal parallel to the loading direction are preferred for the fcc to bcc transformation and the {200} plane normals of the newly-formed bcc …

A Lifetime-Prediction Approach To Understanding Corrosion: The Corrosion-Fatigue And The Corrosion Behavior Of A Nickel-Based Superalloy And A Nanocrystalline Alloy, Rejanah Vernice Steward

Doctoral Dissertations

Lifetime-prediction models are useful for simulating a material’s in-service behavior or outcome. Perhaps the greatest advantage of these models is the ability to use the predicted results to help optimize engineering designs and reduce costs. The Hastelloy^® C-2000^® superalloy is a single-phase material and face-centered cubic in structure at all temperatures. The C-2000^® alloy is a commercially designed alloy manufactured to function in both reducing and oxidizing solutions. C-2000^® is used as a fabrication material for heat exchangers, piping for chemical refineries, and storage repositories. The corrosion properties of C-2000^® are excellent, and the ductility …

Ex-Situ Epitaxial Yba2Cu3O7-Δ Films: Precursor Conversion And Film Characterization, Yifei Zhang

Doctoral Dissertations

BaF₂-based precursors were deposited on various substrates by electron beam co- evaporation and trifluoroactates-involved metal organic deposition (TFA-MOD) for fabricating biaxially-textured YBa₂Cu₃O_7-δ (YBCO) films. A low-pressure processing system was established for the conversion of the precursors. High critical current densities near 4 MA/cm² (77 K, self field) were obtained for the first time through the ex-situ conversion under the total pressures as low as 10 mTorr. The viability of the low- pressure conversion may enable a large-scale, cost-effective batch production of YBCO- based high temperature superconductor (HTS) wires.

The effects of the …

A Kinetic Study Of Indentation Pop-Out In Si, Songqing Wen

Doctoral Dissertations

The kinetics of the phenomenon of pop-out during nanoindentation of silicon were studied by a variety of mechanical and structural characterization techniques. Pop- out is commonly viewed to result from the reversal of a unique pressure-induced, volume reducing phase transformation that occurs in silicon and germanium.

The mechanical characteristics were examined by standard nanoindentation methods using a number of triangular pyramidal indenters with centerline-to-face angles varying in the range 35°-85°. The load at which pop-out occurs was systematically measured as a function of indenter angle, loading/unloading rate, and maximum load. Nanoindentation tests were conducted both at a constant loading rate …

Studying The Fatigue Behavior Of Zr-Based Bulk-Metallic Glasses And Composites, Gongyao Wang

Doctoral Dissertations

As excellent candidates for structural materials, the mechanical behavior of bulk metallic glasses (BMGs) is being widely studied. Although their fatigue behavior is very important for engineering applications, there are few studies on their fatigue behavior. Moreover, the understanding of the fatigue behavior is pretty limited.

High-cycle fatigue experiments were conducted on notched Zr-based BMGs under tension-tension loading in air and vacuum at room temperature. A sparking phenomenon was found by infrared camera at the final fracture moment of Zr₅₀Al₁₀Cu₃₀Ni₁₀ in air. The fatigue-endurance limit (983 MPa) of Zr₅₀Cu₃₇Al …

Severe Plastic Deformation Using Friction Stir Processing, And The Characterization Of Microstructure And Mechanical Behavior Using Neutron Diffraction, Wanchuck Woo

Doctoral Dissertations

Friction-stir welding (FSW) is a solid-state joining process, which utilizes a cylindrical rotating tool consisting of a concentric threaded tool pin and tool shoulder. The strong metallurgical bonding during the FSW is accomplished through: (1) the severe plastic deformation caused by the rotation of the tool pin that plunges into the material and travels along the joining line; and (2) the frictional heat generated mainly from the pressing tool shoulder. Recently, a number of variations of the FSW have been applied to modify the microstructure, for example, grain refinements and homogenization of precipitate particles, namely friction-stir processing (FSP). Applications of …

Processing And Characterization Of Oxide Dispersion Strengthened 14ywt Ferritic Alloys, Michael Keith West

Doctoral Dissertations

Oxide dispersion strengthened (ODS) ferritic steels are currently being investigated as candidate materials for nuclear applications due to their increased high temperature strength and low activation characteristics. Recent studies have shown that ODS ferritic steels containing Ti exhibit enhanced high temperature properties due to the formation of a very fine dispersion of nanometer-sized oxide clusters based on Ti, Y, and O. Studies are currently underway to examine so called 14YWT alloys with nominal compositions of Fe-14Cr-3W-0.4Ti (wt. %) mechanically alloyed with 0.25 (wt.%) Y₂O₃. The focus of this study was to investigate how the early stages …

Cellulosic Fibers And Nonwovens From Solutions: Processing And Properties, Atul Dahiya

Doctoral Dissertations

Cellulose is a renewable and bio-based material source extracted from wood that has the potential to generate value added products such as composites, fibers, and nonwoven textiles. This research was focused on the potential of cellulose as the raw material for fiber spinning and melt blowing of nonwovens. The cellulose was dissolved in two different benign solvents: the amine oxide 4-N-methyl morpholine oxide monohydrate (NMMO•H₂0) (lyocell process); and the ionic liquid (IL) l-butyl- 3-methylimidazolium chloride ([C₄MIM]Cl). The solvents have essentially no vapor pressure and are biologically degradable, making them environmentally advantageous for manufacturing processes. The objectives …

Chemical Characterization Of Pan Based Carbon Fibers Produced By Microwave Assisted Plasma (Map) Technology And Effect Of Plasma Treatment On Carbon Fiber Surface And Interphase With Polymer Matrix, Xiaoyu Luo

Doctoral Dissertations

The first objective of this research was to chemically characterize the surface of conventional carbon fiber and carbon fiber produced by microwave assisted plasma (MAP) manufacturing process. The chemical composition and functional groups on the surface of the fibers were determined by X-ray photoelectron spectroscopy (XPS). The untreated unsized MAP carbon fibers were compared to untreated unsized conventional carbon fibers and showed a significant amount of oxygen. Comparison between treated unsized MAP carbon fiber and treated unsized conventional carbon fiber reveal a 100% enhancement of oxygen elemental concentration.

Two plasma systems, remote applicator and atmospheric plasma were used to treat …

Nondestructive Evaluation Of Loading And Fatigue Effects In Haynes® 230® Alloy, Tarik Adel Saleh

Doctoral Dissertations

Nondestructive evaluation is a useful method for studying the effects of deformation and fatigue. In this dissertation I employed neutron and X-ray diffraction, nonlinear resonant ultrasound spectroscopy (NRUS), and infrared thermography to study the effects of deformation and fatigue on two different nickel based superalloys. The alloys studied were HAYNES 230, a solid solution strengthened alloy with 4% M₆C carbides, and secondarily HASTELLOY C-2000 a similar single phase alloy.

Using neutron and X-ray diffraction, the deformation behavior of HAYNES 230 was revealed to be composite-like during compression, but unusual in tension. The carbides present in this alloy do …

Nanodot-Based Organic Memory Devices, Zhengchun Liu

Doctoral Dissertations

In this study, resistor-type, diode-type, and transistor-type organic memory devices were investigated, aiming at the low-cost plastic integrated circuit applications. A series of solution-processing techniques including spin-coating, inkjet printing, and self-assembly were employed to fabricate these devices.

The organic resistive memory device is based on a novel molecular complex film composed of tetracyanoquinodimethane (TCNQ) and a soluble methanofullerene derivative [6,6]-phenyl C61-butyric acid methyl ester (PCBM). It has an Al/molecules/Al sandwich structure. The molecular layer was formed by spin-coating technique instead of expensive vacuum deposition method. The current-voltage characteristics show that the device switches from the initial 'low' conduction state to …

Designing And Modeling Of A New Continuous Steelmaking Process, Jörg Peter

Doctoral Dissertations

"Continuous steel production has the potential to lower the cost of steelmaking as compared to current batch operations. However, experiences from past attempts to develop and commercialize continuous steelmaking processes show that there are several engineering hurdles to overcome. The objective of this research was the development of a fully continuous steelmaking process that would incorporate the lessons from past experiences, address the foreseen challenges, and meet the requirements to justify the possible replacement of the current EAF-LMF steelmaking route.

The design of the new process consists of five interconnected vessels. Preheated scrap would be continuously charged, melted, and superheated …