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Materials Science and Engineering

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Clemson University

Theses/Dissertations

2021

Alumina

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Investigation And Characterization Of New Optically Stimulated Luminescence (Osl) Dosimetric Materials, Linyu Pan Dec 2021

Investigation And Characterization Of New Optically Stimulated Luminescence (Osl) Dosimetric Materials, Linyu Pan

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Optically stimulated luminescence (OSL) dosimeters have attracted increasing attention due to advantages over TL dosimeters, including no thermal quenching and higher sensitivity. Nevertheless, currently, there are only two commercially available OSL dosimeters, BeO and Al2O3:C. An OSL dosimeter requires low effective atomic number (Zeff < 16), at least one type of recombination center and one type of trap, and UV~blue emission. In this dissertation, motivated by the search of new OSL dosimetric materials, a systematic investigation of alumina (Zeff = 11.3) and magnesium aluminate spinel (Zeff = 11.2) based materials was performed in terms of the engineering of the recombination centers and electronic traps. Microstructural characterization was executed by means of X-ray diffraction (XRD) and Raman spectroscopy. Luminescence was characterized under X-ray excitation (radioluminescence; RL) at ambient and …