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Life Sciences

University of Wollongong

2010

Water

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Specific Cellular Water Dynamics Observed In Vivo By Neutron Scattering And Nmr., Moeava Tehei, Marion Jasnin, Andreas Stadler, Giuseppe Zaccai Jan 2010

Specific Cellular Water Dynamics Observed In Vivo By Neutron Scattering And Nmr., Moeava Tehei, Marion Jasnin, Andreas Stadler, Giuseppe Zaccai

Faculty of Science - Papers (Archive)

Neutron scattering, by using deuterium labelling, revealed how intracellular water dynamics, measured in vivo in E. coli, human red blood cells and the extreme halophile, Haloarcula marismortui, depends on the cell type and nature of the cytoplasm. The method uniquely permits the determination of motions on the molecular length (Ba˚ ngstrøm) and time (pico- to nanosecond) scales. In the bacterial and human cells, intracellular water beyond the hydration shells of cytoplasmic macromolecules and membrane faces flows as freely as liquid water. It is not ‘‘tamed’’ by confinement. In contrast, in the extreme halophile archaeon, in addition to free and hydration …


Catalytic Solar Water Splitting Inspired By Photosynthesis. Homogeneous Catalysts With A Mechanical ("Machine-Like") Action, Gerhard F. Swiegers, G Charles Dismukes, Leone Spiccia, Robin Brimblecombe, Annette Koo, Jun Chen, Gordon G. Wallace Jan 2010

Catalytic Solar Water Splitting Inspired By Photosynthesis. Homogeneous Catalysts With A Mechanical ("Machine-Like") Action, Gerhard F. Swiegers, G Charles Dismukes, Leone Spiccia, Robin Brimblecombe, Annette Koo, Jun Chen, Gordon G. Wallace

Faculty of Science - Papers (Archive)

Chemical reactions may be controlled by either: the minimum threshold energy that must be overcome during collisions between reactant molecules / atoms (the Activation Energy, Ea), or: the rate at which reactant collisions occur (the Collision Frequency, A) (for reactions with low Ea). Reactions of type (2) are governed by the physical, mechanical interaction of the reactants. Such mechanical processes are unusual, but not unknown in molecular catalysts. We examine the catalytic action and macroscopic properties of several abiological mechanical catalysts and show that they display distinct similarities to enzymes in general. An abiological model of the Photosystem II Water …


Book Review: "Troubled Waters: Confronting The Water Crisis In Australia's Cities" By Patrick Troy (Ed.), Leah M. Gibbs Jan 2010

Book Review: "Troubled Waters: Confronting The Water Crisis In Australia's Cities" By Patrick Troy (Ed.), Leah M. Gibbs

Faculty of Science - Papers (Archive)

Troubled Waters is a collection of essays edited by Patrick Troy, Emeritus Professor and Visiting Fellow at the Fenner School of Environment and Society, Australian National University. The papers are contributed by a multidisciplinary group of authors, from the fields of economics, history, geography, environmental and social policy and law. As a result, the book does not present a single theoretical or methodological approach and in this regard it is refreshing. The book is published by the ANU E Press; a publisher that makes academic output from the ANU freely available from its website, as well as for purchase through …