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Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Post-Wildfire Effects On A Headwater Stream In The San Bernardino National Forest, Kelley Giron

Electronic Theses, Projects, and Dissertations

Southern California has experienced prolonged drought conditions that have supported frequent wildfires that adversely impact ecosystems, natural resources, and human development. A primary consequence of these events is the impact on water quality and quantity. Of equal concern is evaluating how diverse land use configurations within a watershed can alter the physio-chemical properties of headwater reaches where drought and wildfire conditions are prevalent. To better understand the extent to which wildfires impact water quality and quantity across a headwater watershed, this study investigates wildfire impacts from the 2021 South Fire to Lytle Creek, a headwater stream of the Santa Ana …

How Akron Affects The Water Quality Of The Cuyahoga River, Allyson Darst

Williams Honors College, Honors Research Projects

The purpose of this study was to analyze whether the city of Akron had negative effects on the Cuyahoga river, and determine if the Cuyahoga River was naturally able to remediate these effects downstream. The pollutants measured in this study include hardness, bromine, residual chlorine, iron, copper, lead, nitrate, nitrite, ammonium chloride, total chlorine, fluoride, carbonate, pH, total alkalinity and cyanuric acid. This study was done using water testing strips (JNW Direct) to test the water at four different locations along the Cuyahoga River downstream (North) of Akron. This study found that the city of Akron does have a negative …

Winter Dynamics Of Storm Water Management Ponds And Winter Tolerance In Three Aquatic Plant Species, Patrick Strzalkowski

Theses and Dissertations (Comprehensive)

The vast majority of the research into the performance of stormwater management ponds (SWMPs) has been performed in warm regions or during the warmer seasons in temperate regions. It is presumed that SWMPs are inactive in the winter as any potential stormwater is trapped in snow and ice. The main goal of this thesis was to test this presumption and to study the dynamics and performance of three SWMPs during the winter. Remote water level loggers were installed into the three SWMPs and daily grab samples from the influents and effluents were taken and analyzed for total phosphorus (TP), chloride, …

Sewer System Infrastructure And Stressors On Water Quality In Streams Within The Alplaus Watershed In Upstate Ny, Camryn Ragland

Honors Theses

Healthy aquatic ecosystems require clean water, but many creeks and streams may be impaired by human activity. This study is focused on surface water quality of the Alplaus, and Indian Kill streams located within the Alplaus Watershed in Schenectady and Saratoga Counties (NY). The primary goal of this study is to understand the extent of water quality impairment within the Alplaus and Indian Kill using a range of indicators to understand the impacts of failing infrastructure and stressors to surface water. Sixty-five water samples were collected in the fall of 2021 from six locations in the Alplaus and Indian Kill …

Water Quality Responses To A Semi-Arid Beaver Meadow In Boise, Idaho, Luise Bayer Winslow

Boise State University Theses and Dissertations

Beavers have been instrumental in shaping the North American riverine landscape. However, land use change and beaver trapping have caused large decreases in beaver populations, resulting in fundamental changes to river morphology, hydrology, and biogeochemical function. Effective river restoration and remediation of arid western rivers relies on a comprehensive interpretation of how beaver activity influences water quantity and quality. In this study, I compared two stream reaches with and without beaver dams in a semi-arid watershed, to quantify the effects of beaver activity on hydrology and biogeochemistry. Within each reach, I combined dilution gauging and stream tracer experiments to determine …

A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega

MSU Graduate Theses

The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …

Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen

LSU Doctoral Dissertations

The Mississippi River Delta is threatened by a growing pressure to support large human populations in the United States both with food production, navigation systems, and urban development in the Mississippi River Basin. Nitrate-nitrogen load in the Mississippi River, up to 100 Tg N yr^-1 from agricultural and urban runoff, leads to phytoplankton blooms and hypoxia across the Louisiana continental shelf, creating dead zones of low dissolved oxygen threatening a significant commercial fishery. Along the coast and river corridors, floodplain ecosystems have the capacity to retain and remove nitrate. This dissertation explores the role of productive, actively growing coastal …

Evaluation Of The Relationship Between Land Use And Water Quality In Kittitas County, Wa, Lindsay Schulz

All Master's Theses

Water in Kittitas County is extremely valuable since it supports farming, recreation, and cultural activities, as well as environmental processes and a diversity of biological life while providing many ecosystem services. However, land conversions required by agricultural and urban land uses can negatively impact water quality and the biological function of the stream. I studied how forested, agricultural, and urban land use affect six streams. Fourteen sites were sampled, once each in July, August, and September 2019. Land use was calculated as a percentage of forested, agricultural, and urban land use within a 100-m buffer of the stream, upstream of …

Relating Recharge Mechanisms To Chemical Changes In An Updip Appalachian Coal Mine Discharge: A Case Study From Lambert Run, West Virginia, Matthew Lewis Bell

Graduate Theses, Dissertations, and Problem Reports

Impaired drainage from active and abandoned mines degrades the water quality of receiving streams and aquifers. Coal mine drainage (CMD) has been studied for decades in Appalachia, but unknowns and uncertainties are still present, including the influence of mine hydrogeology on the outflow chemistry of above-drainage mines. To evaluate the influence of recharge type on above-drainage mine chemistry, samples were collected every two weeks at a CMD outflow treatment system in Harrison County, West Virginia.

Samples were collected to measure geochemical changes taking place in the mine workings and along the flowpath of the passive treatment system. Samples were divided …

Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber

Theses and Dissertations (Comprehensive)

The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …

The Spatial Distribution Of Elevated Uranium In The Treasure Valley Aquifer System, Southwest Idaho, Lloyd A. Womeldorph

Boise State University Theses and Dissertations

The Treasure Valley Aquifer System (TVAS) in southwestern Idaho contains well-documented uranium concentrations over the U.S. Environmental Protection Agency maximum contaminant level of 30 µg/L. With a population in the Treasure Valley projected to reach 1.6 million by 2065, in-depth horizontal and vertical spatial knowledge of the contaminant is needed. This study evaluates the horizontal and vertical spatial nature of uranium in the TVAS and interprets those observations to provide both a conceptual model of uranium behavior, and recommendations for water resource management. A large water quality dataset was compiled, and supplemented by data collected during a field sampling campaign, …

Improved Estimates Of Tributary Nitrogen Load To Casco Bay, Maine, Whitley J. Gray

Electronic Theses and Dissertations

Over the past two decades, total nitrogen (TN) concentrations have increased in Casco Bay (CBEP 2015). The sources of the increased nitrogen are poorly understood but occur with simultaneous population growth and land use changes. The total riverine nitrogen load to Casco Bay was previously estimated by Liebman and Milstead (2012) using the United States Geologic Survey’s (USGS) SPAtially Referenced Regression On Watershed attributes (SPARROW) model. The SPARROW model uses watershed characteristics, regional monitoring data and nitrogen source data to estimate nitrogen loading but was not validated using measurements of nitrogen in the Casco Bay watershed. This study attempts to …

Rating Curve Development For The Upper James Fork, Lower James Fork And Hinkle Jones Creek In The Upper Poteau River Watershed In Arkansas, Meagan O'Hare

Biological and Agricultural Engineering Undergraduate Honors Theses

Stream discharge is necessary to estimate loads and calibrate and validate watershed models. Access to long-term water quality data and discharge measurements allows for modeling of water quality changes across a watershed over time. However, discharge monitoring stations are often expensive to install and maintain, particularly in small rivers. A more cost-effective method for monitoring streamflow has been implemented in the Upper Poteau River Watershed (UPRW) in Arkansas. This method consists of an SonTek acoustic doppler instrument for measuring storm stream flow, with is combined with manual baseflow discharge measurements. The combined stormflow and baseflow measurements are combined with a …

The Impacts Of Land Use And Land Cover Change On Water Quality In The Big Sioux River: 2007-2016, Dinesh Shrestha

Electronic Theses and Dissertations

Between 2006 and 2012, conversion of 485,000 acres of grassland to cropland in eastern South Dakota was reported. In 2012, the Big Sioux River (BSR) running through most of eastern South Dakota was listed among the dirtiest rivers in the nation. This rating convinced state authorities to study trends of land cover changes in the BSR watershed and its association with BSR water quality with respect to increases in nitrate levels. This research i) quantifies spatial and temporal changes in the land cover types within the BSR watershed, and ii) identifies any correlation between these changes and changes in BSR …

Evaluation Of A Sequential Pond System For Detention And Treatment Of Runoff At Skypark, Santa's Village, Elizabeth Caporuscio

Electronic Theses, Projects, and Dissertations

Understanding the extent to which human activities impact surface water resources has become increasingly important as both human population growth and related landscape changes impact water quality and quantity across varying geographical scales. Skypark, Santa’s Village is a 233.76-acre tourism-based outdoor recreation area located in Skyforest, California residing within the San Bernardino National Forest. The park is situated at Hooks Creek, the headwaters of the Mojave River Watershed, and is characterized by a diverse landscape that includes forest cover and human development, including impervious surfaces, a restored meadow, and recreational trails. In 2016, Hencks Meadow was considered degraded by human …

Nutrient Transport And Storage In A Karst Spring-Reservoir System During Baseflow, Missouri Ozarks, Heather A. Moule

MSU Graduate Theses

Urban and agricultural land uses are important sources of nitrogen and phosphorus which, if in excess, can cause eutrophication in lakes and rivers. There have been few studies of nutrient transport and storage in karst spring and reservoir connected stream systems draining the Missouri Ozarks. This study aims to link the baseflow nutrient contributions of Sanders Spring to downstream reservoir outflow and the Headwaters South Dry Sac River Watershed in Springfield, Missouri. Water samples were collected seasonally and analyzed for total nitrogen (TN), total phosphorus (TP), and several other water quality parameters. Discharge was also monitored to calculate water and …

Watered Down: The Challenges Of Managing Water Resources In Montana, Beau E. Baker

Graduate Student Theses, Dissertations, & Professional Papers

Like much of the American West, Montana sits in the cross hairs of climate change. State drought resiliency projects and cooperative watershed management are on the rise in the face of decreased snowpack, early runoff, precipitation variability and lower seasonal stream flows. Population growth, land use practices, recreation and tourism all contribute to pressures on state water supplies.

Montana is faced with the arrival of invasive species that threaten the ecological health of its lakes, rivers and streams. State budget constraints and depressed agency capacity are hurting our ability to fend off these threats. There’s a lack of public education …

Assessing The Impact Of A Constructed Wetland Biome On The Ecosystem Health Of Cedar Run, Thomas Vasilopoulos, Casey Lee

Senior Honors Projects, 2010-2019

A wetlands ecosystem is defined as “an area saturated by surface or groundwater at a frequency or duration sufficient to support...a prevalence of vegetation typically adapted for life in saturated soil conditions” (Batzer and Sharitz, 2007). Wetlands serve as biofilters and thus have been used to treat sewage and wastewater, as well as to restore the health of polluted water systems. Solly Walker and Lorinda Palin, owners of a certified natural and biodynamic farm called Avalon Acres located in Broadway, Virginia, constructed a wetland two years ago, using the stream, Cedar Run, that flows through their property. Pollution from agricultural …

Optical Water Quality And Human Perceptions Of Rivers, Amie West

Graduate Theses and Dissertations

Understanding water quality dynamics in recreational rivers is integral in shaping management strategies that maintain ecosystem health, perceived value and appeal, and regional economic significance in a changing environment. Optical water quality describes the behavior of light in water as governed by its physical and chemical composition, and is among the strongest influences on human perceptions of water quality. Ethnohydrology is the study of culturally constructed knowledge and understanding of water. This work is the culmination of an interdisciplinary approach to water resources research—integrating optical water quality and ethnohydrology methods to recognize the intersection between measured water quality and visible …

Effect Of Bioenergy Crops And Fast Growing Trees On Hydrology And Water Quality In The Little Vermilion River Watershed, Tian Guo

Open Access Dissertations

Energy security and sustainability require a suite of biomass crops, including woody species. Short rotation woody crops (SRWCs) such as Populus have great potential as biofuel feedstocks. Quantifying biomass yields of bioenergy crop and hydrologic and water quality responses to growth is important should it be widely planted in the Midwestern U.S. Subsurface tile drainage systems enable the Midwest area to become highly productive agricultural lands, but also create environmental problems like nitrate-N contamination of the water it drains. The Soil and Water Assessment Tool (SWAT) has been used to model watersheds with tile drainage, but the new tile drainage …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Uncertainty In Climatic Change Impacts On Multiscale Watershed Systems, Olga V. Tsvetkova

Open Access Dissertations

Uncertainty in climate change plays a major role in watershed systems. The increase in variability and intensity in temperature and precipitation affects hydrologic cycle in spatial and temporal dimensions. Predicting uncertainty in climate change impacts on watershed systems can help to understand future climate-induced risk on watershed systems and is essential for designing policies for mitigation and adaptation. Modeling the temporal patterns of uncertainties is assessed in the New England region for temperature and precipitation patterns over a long term. The regional uncertainty is modeled using Python scripting and GIS to analyze spatial patterns of climate change uncertainties over space …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Nutrient Dynamics In Stormwater Runoff From Green Roofs With Varying Substrate, John Michael Fohner

Graduate Theses and Dissertations

One major concern with urban development is the increasing amount of stormwater runoff from large expanses of impervious surfaces. These impervious surfaces reduce the ability of stormwater to infiltrate into the soil and eventually groundwater, which leads to greater amounts of surface runoff. Green technology serves as a viable solution to many of the environmental problems presented by modern development. Fifteen mock, extensive green roofs were built in the fall of 2008 at the Watershed Research and Education Center in Fayetteville, Arkansas. The goals of this project were to (1) measure the amount of stormwater runoff from varying treatments and …

Nutrient Concentrations At Baseflow Conditions In The Upper White River Basin, Southwest Missouri And Northwest Arkansas, Gopala G. Borchelt

MSU Graduate Theses

The Upper White River Basin (UWRB) is becoming increasingly vulnerable to water quality degradation from urban/population growth and increased agricultural production. This study examines the relationships among nutrient levels, water chemistry and watershed characteristics of 19 watersheds in the UWRB. Water samples were collected during baseflow conditions each month for one year at USGS continuous-flow gage stations. Watershed characteristics evaluated were land use, geology, drainage area, flow discharge, and wastewater treatment plant discharge (WTP). Measured chemical water quality indicators include total nitrogen (TN), total phosphorus (TP), specific conductivity, turbidity, pH and dissolved oxygen. Rapidly expanding urban areas are associated with …

Nutrient Loads In An Urban Ozark Watershed: Jordan, Fassnight And Upper Wilson's Creeks, Springfield, Missouri, Ronald B. Miller

MSU Graduate Theses

The study watershed includes Jordan Creek, the primary stream draining the central downtown area of Springfield, Missouri, and also Fassnight and upper Wilson Creeks. Ten sample sites were established within the watershed and water samples and were collected during baseflow and storm runoff events between August 1, 2004 and July 31, 2005. Samples were tested for total nitrogen (TN), total phosphorus (TP) and selected heavy metals (zinc, arsenic, lead, copper and cadmium) and the parameters pH, specific conductance, turbidity, temperature and dissolved oxygen. Rating curves were used to correlate discharge and water quality variables. Separate rating curves were developed for …

Soil Phosphorus Levels In Residential Lawns And Comparisons Among Four Land Uses In Springfield, Missouri, Timothy R. Davis

MSU Graduate Theses

Eutrophication of surface waters due to high phosphorus (P) concentrations is an important water quality concern in Greene County, Missouri. Phosphorus enrichment has been linked to a variety of non-point sources including runoff from both agricultural and urban land uses. Soil P has been shown to be a source of P in runoff. The differences in soil P among different land uses may provide insight into which land use contributes more P in runoff. This study examines the soil composition, geochemistry and total P concentration of surface soil (0-5cm) in four land uses in Greene County, Missouri. The land uses …

Consequences Of Reservoir Drainage On Downstream Water Chemistry, Suspended Sediment, And Nutrients, Southwest Missouri, Mark W. Bowen

MSU Graduate Theses

Construction and subsequent draining of reservoirs can have dramatic affects on the release of nutrients and sediments to waterways. This study describes how the temporary draining of a small reservoir for dam repair influences downstream water quality. The Valley Mill Reservoir has a surface area of 6.1 hectares and volume of 150,000 m3 when filled. Water chemistry monitoring and water sampling were performed at six sites during baseflow and ten sites during runoff events for one year. Water samples were analyzed for total nitrogen (TN), total phosphorous (TP), and total suspended sediment (TSS) concentrations. Results indicate that draining of Valley …