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The Oxidation State Of Hawaiian Magmas, Michael Vollinger

Masters Theses

In order to estimate the oxygen fugacity of Hawaiian lavas I have measured the ferric/ferrous ratios of samples from the 1984 eruption of Mauna Loa volcano and from the ongoing (1983-2017) Puu Oo eruption of Kilauea volcano. Fifteen samples were studied from the 21 day Mauna Loa eruption and 86 samples, erupted between 1983 and 2004, of the 34 year long Kilauea eruption. Both studies show that, in order to obtain reliable estimates of oxygen fugacity when, where, and how basaltic lava is sampled is of critical importance. Water-quenched lavas and spatter sampled at, or near vents, are less oxidized …

Exploring Long-Term Fault Evolution In Obliquely Loaded Systems Using Tabletop Experiments And Digital Image Correlation Techniques, Kevin Toeneboehn

Masters Theses

This thesis focuses on the use of scaled physical experiments to better understand the development and long-term evolution of fault systems that are otherwise impossible to observe directly. The document is divided into three chapters. The first chapter documents the implementation of an inexpensive stereo vision method for acquiring high resolution three-dimensional strain data for table-top experiments. The second chapter applies the stereo vision method to a tectonic problem—the development of slip partitioning in obliquely loaded crustal systems. Slip partitioned fault systems accommodate oblique convergence with different slip rake on two or more faults and are well documented in the …

Petrogenesis And Concentric Zonation Of The Belchertown Intrusive Complex, West-Central Massachusetts, Karen June Van Wagner

Masters Theses

The Belchertown Intrusive Complex is a ~164 km2 Devonian pluton that intruded Paleozoic metasedimentary and metavolcanic rocks in west-central Massachusetts. Intrusion of the pluton was synchronous with Acadian deformation (Ashwal, 1974). The complex is concentrically zoned, with a core of orthopyroxene-biotite monzodiorite, a middle zone of clinopyroxene-hornblende-biotite granodiorite, and an outermost zone of hornblende-biotite granodiorite. Zoning from a more to less hydrous mineral suite from the outside to the inside of the pluton led Ashwal (1974) to suggest that metamorphic hydration most strongly affected the outermost zones of the complex. Basaltic inclusions occur most commonly near the edges of …

Determining Sources Of Nitrate In The Semi-Arid Rio Grande Using Nitrogen And Oxygen Isotopes, Diego Alberto Sanchez Hernandez

Masters Theses

The Rio Grande, a semi-arid river in the American Southwest, is a major source of surface water for agriculture and drinking supplies in New Mexico and Texas. In addition to increasing salinity, considerable increases of NO₃^- [nitrate] have been observed in the semi-arid portion of the Rio Grande. It is possible that elevated water salinity inhibits denitrification on irrigated fields and, thus, fails to mediate excess nutrient load from anthropogenic activities. Therefore, two major goals of this project were to 1) characterize and quantify major NO₃^- sources, and 2) assess whether elevated water salinity affects microbial …

Evaluation Of Non-Ionic Surfactants With And Without Hydrogen Peroxide For The In-Situ Remediation Of Napl Contaminants, Charles E. Holada

Masters Theses

Laboratory studies were conducted on Quillaja saponins and nine other surfactants commonly used to remove non-aqueous phase liquids (NAPLs) from soils and aquifers. The NAPL contaminant tested was diesel fuel. Static batch reactors containing an aged diesel-contaminated soil was treated with saponins and nine other commercially available surfactants to determine how much diesel fuel could be removed with the pore fluids after 1 day and 10 days of contact time. Of all the surfactants tested, saponins achieved the greatest removal of diesel fuel after 1 day and 10 days. There was large disparity in the diesel fuel removed by the …

Gravity And Passive Seismic Methods Used Jointly For Understanding The Subsurface In A Glaciated Terrain: Dowling And Maple Grove Quadrangles, Barry County, Michigan, Scott A. Feldpausch

Masters Theses

The Horizontal to Vertical Spectral Ratio (HVSR) passive, single sensor seismic technique has been used together with gravimetry to study the topography hidden below the glacial drift of two 7.5’ quadrangles in Barry Co., MI. 265 stations were observed with both instruments along roads at nominal spacings of about 0.4 to 0.8 km. Occasional water wells and oil wells with documented penetrations of the base of glacial were used to calibrate the local power law regression calibration. This was also compared with the statewide calibration curve previously established. Results are presented as maps of Simple Bouguer Anomaly, Residual Bouguer Anomaly, …

Volatiles In Subglacially Erupted Basaltic Glasses And Their Use In Reconstructing Paleo-Ice Thicknesses, Carver Lee

Masters Theses

Volatile concentrations in basaltic tuyas, edifices that form during a subglacial eruption and remain once the ice sheet has retreated, have been used to calculate the thickness of the overlying ice sheet at the onset of the eruption (Tuffen, 2010). However, subglacial eruptions are complex events and this technique does not always provide a clear answer (Schopka et al., 2006; Edwards et al., 2009). The purpose of this research is to evaluate this technique and investigate constraints on the quality of data collected by attempting to calculate the minimum ice thickness under which Hlöðufell, a tuya in south-central Iceland, erupted. …

Hydrogeochemical Controls On Reactive And Nonreactive Solute Transport In Heterogenous Porous Media, Mahta Gholizadeh Ansari

Masters Theses

"This work examines how physical and chemical heterogeneity can affect reactive and non-reactive transport in porous media. The effect of heterogeneity of the porous media is investigated both on dissolution rate of magnesite and attenuation time of nonreactive contaminants in non-reactive media. Various spatial distribution were created using statistical parameters in PETREL.A total of 6793 transport modeling simulations were run using CrunchFlow. Lasso regression was used to select most significant features and those features are then used in linear regression and deep learning models.

The magnesite dissolution simulations were performed under different permeability ratios (magnesite /sand permeability) and inlet pH. …

Assessment Of Rockfall Rollout Risk Along Varying Slope Geometries Using The Rocfall And Crsp Software, Mariam S. Al E'Bayat

Masters Theses

"Most routes in mountainous areas suffer from rock falling, rolling and bouncing risk. There are many computer programs concerned with simulating the rockfall problem, and whereas they have the same purpose, they however differ in the input data that's needed to simulate the problem, and they also differ in the way of processing and kind of output.

This study used Rocfall® and the Colorado Rockfall Simulation Program (CRSP®) to simulate sixty-three models of varying slope geometry, where only the slope geometry is changed with the same material properties for both the slope and the rocks.

Both programs were fast and …

Deformation Processes At The Leading Edge Of The Sevier Fold And Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Masters Theses

"Deformation processes leading to formation and abandonment of 'triangle zones' along the leading edge of the Sevier fold and thrust belt are investigated near Kanarraville, Utah through construction of a detailed geologic map and cross-section along Spring Creek. Here the eastern limb of the Kanarra fold, a Sevier structure, is well exposed along the Hurricane Cliffs due to uplift and erosion of the footwall of the Hurricane Fault. The east-verging Kanarra fold changes from upright to overturned within Spring Creek. Within the fold limb, parasitic folds, minor thrust faults, and duplex structures result in local tectonic overthickening of units and …

Structural And U-Pb Detrital Zircon Geochronologic Constraints On The Origin Of The Condrey Mountain Schist, California - Oregon, Joseph Reid Coons

Masters Theses

"The Condrey Mountain Schist (CMS) of the Klamath Mountains (northern California and southern Oregon) represent low grade oceanic and terrigenous sediments thrust beneath higher grade ophiolitic rocks of the Rattlesnake Creek Terrane (RCT). This study presents new U-Pb detrital zircon dates from the CMS, and from the possibly correlative basin rocks of the Galice Formation and accretionary rocks of the South Fork Mountain Schist. The Galice Formation yields a maximum depositional age of ca. 152 Ma with prominent date distributions of ca. 150-200 Ma (39% of analyzed grains), 200-600 Ma (1%), 600 - 1000 Ma (2%), and 1000-3200 Ma (58%). …

Provenance And Depositional Environments Of Fluvial-Lacustrine Deposits In A Non-Marine Rift Basin, Lower-Triassic Jiucaiyuan And Shaofanggou Low-Order Cycles Bogda Shan, Nw China, Jaimeson Grigaitis Fredericks

Masters Theses

"The uppermost Carboniferous to Lower Triassic eolian-fluvial-lacustrine deposits of Turpan-Junggar Basin, NW China, record the non-marine sediment-filling processes in a continental rift basin in mid-latitude NE Pangea. This study focuses on the fluvial-lacustrine strata of the Lower Triassic Jiucaiyuan (JCY) and Shaofanggou (SFG) low-order cycles (LCs) in multiple half grabens at the southern and northern foothills of Bogda Shan. Outcrop, paleocurrent, and petrographic analyses indicate a southern provenance. Intermediate to felsic volcanic lithics and metamorphic lithics are interpreted as being derived from Tian Shan to the south while the sedimentary lithics originate from the local rift shoulders. The basaltic lithics …

Evaluation Of Swelling And Re-Swelling Of Preformed Particle Gels (Ppg) When Exposed To Co₂, Sujay Suresh

Masters Theses

"Long term water/gas flooding induces high permeability channels in reservoirs. Reservoir heterogeneity becomes the most prominent challenge faced in mature oil fields. Gel treatment has been a proven solution to counter the problem of reservoir heterogeneity, to provide in-depth treatment and improve the sweep efficiency for reservoirs. Preformed particle gels (PPGs) were developed as an alternative to in-situ gels as they preferentially penetrate and shutoff high permeability zones, leaving the low permeability zones undamaged. These gels have been predominantly used in water flooding projects, but have not been employed in carbon dioxide (CO₂) flooding projects. CO₂ Resistant …

Development Of A Variogram Approach To Spatial Outlier Detection Using A Supplemental Digital Elevation Model Dataset, Zane Daniel Helwig

Masters Theses

"When developing a ground water model, the quality of the dataset should first be evaluated. Spatial outliers can lead to predictions which are not representative of actual conditions. In order to isolate misrepresentative points, a method is presented which examines the experimental variogram of a ground water elevation dataset. To define a threshold variance between pairs of ground water elevation measures, ground elevation values from a digital elevation model (DEM) are used to determine a maximum reasonable variance expected to occur on the experimental variogram. To determine appropriate DEM parameters, a separate study was also done which observed characteristic behavior …

Crustal Thickness And Vp/Vs Ratio Of Yellowstone, Eastern Snake River Plain, Wyoming Province, And The Northern Basin And Range Province Through Receiver Function Analysis, Avikant Dayma

Masters Theses

"For decades, numerous studies have been conducted and contradictory results were achieved about the origin and evolution of the Yellowstone supervolcano and the Eastern Snake River Plain. Whether the 640 km long time-progressive chain of rhyolitic calderas was formed due to mantle-plume or a result of lithospheric extension allowing the emergence of melt on the surface is still a debate. Using receiver function analyses, this study determines the crustal thickness and the Vp/Vs ratio below the Yellowstone Plateau, Wyoming Province (WP), Idaho Batholith (IB), Eastern Snake River Plain (ESRP), and the northern Basin and Range Province (BRP). The thickness is …

Mining Asteroids For Volatile Resources: An Experimental Demonstration Of Extraction And Recovery, Egboche Christopher Unobe

Masters Theses

"Gaseous compounds trapped within carbonaceous asteroids may prove to be important targets for prospective space miners in the near-term. Volatile release is from hydrated, hydroxylated and carbonated phases present, making such bodies attractive as feedstock for the production of H₂O, CO₂ and simple organic compounds. A source of these species in orbit provides an opportunity to locally produce space-craft propellant and other life-support gases through the application of In-situ Resource Utilization (ISRU).

For this study, an experimental vacuum system was modified and used to test the technical validity of radiatively heating asteroid simulants to extract contained gaseous …