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The Impact Of Upland Development And Marsh Width On Groundwater Composition In Estuarine Tidal Creeks In The Southeastern Coastal United States, Meghan Shanahan

Theses and Dissertations

Coastal upland development has been shown to negatively impact surface water quality in tidal creeks along the southeastern coastal United States, but the impact of development on groundwater quality is not well understood. Increases in impervious cover associated with development has the potential to increase groundwater contamination as well as reduce fresh rainwater infiltration into the subsurface, which may decrease discharge of fresh groundwater to the estuary. We hypothesized that groundwater nutrient concentrations and salinity ranges would be higher in developed watersheds than in undeveloped watersheds.

Groundwater discharging from coastal uplands often travels through salt marshes before discharging to tidal …

Organic Acids And Amino Acids In Serpentinization Related Fluids From The Atlantis Massif, Nicholas Camper

Theses and Dissertations

Serpentinization is a low temperature, low pressure process that occurs when water reacts with ultramafic rocks. Fluids that have interacted with serpentinites have elevated concentrations of hydrogen and reduced carbon species that can fuel chemolithoautotrophy. International Ocean Discovery Program Expedition 357 drilled a series of boreholes into the Atlantis Massif with the goal of investigating how serpentinization impacts carbon cycling and sustains life in the subseafloor. Bottom water samples (CTD), fluids flushed from the boreholes during drilling (Rock Drill), and fluids that were trapped in the liners of the cores (Liner fluids) were collected. The changes and distributions of organic …

The Sedimentary Record Of Eocene Deformation In The Interior Of The Southern Canadian Cordillera, Erica May Rubino

Theses and Dissertations

Eocene sedimentary strata exposed in the interior of the southern Canadian Cordillera (SCC) in British Columbia (BC) and northernmost Washington (WA) record a poorly understood history of extension-related deformation in the hinterland of the orogen. Today these strata are exposed in isolated, distinct outcrop belts, although the nature of the original basin(s) is unknown. We examined 650 m of Eocene strata, analyzed 2,995 detrital zircons for uranium-lead (U-Pb) ages, and measured 67 detrital zircons for Hf isotope systematics in an effort to better understand the physiography of the SCC during this time period. Eocene strata consist of clast- and matrix-supported …

Re-Evaluation Of The Extent And Tectonic History Of The Helena Banks Fault Zone, Offshore South Carolina, Ahmet Postaagasi

Theses and Dissertations

The Helena Banks Fault Zone (HBFZ), first identified in the early 1980’s offshore Charleston, S.C., was originally interpreted to be a major, high-angle, basin-bounding normal fault associated with Mesozoic rifting. Subsequent work suggests that (1) Mesozoic rift basins are not present on the continental shelf of South Carolina, (2) the HBFZ originated as a strike-slip fault within Paleozoic sedimentary rocks of the Suwannee Basin sequence, (3) a mafic intrusion inferred from aeromagnetic data is coincident with a broadly circular zone of highly-complex faulting along the north-eastward continuation of the HBFZ where (4) up to 300 m of local relief can …

Salt Tectonism In The Carolina Trough, Ceren Postaagasi

Theses and Dissertations

The Carolina Trough is a major linear sedimentary basin along the eastern continental margin of North America which formed as a result of tectonic and thermal subsidence during continental rifting in Mesozoic time (Hutchinson et al., 1982). The Carolina Trough is unique along the southeastern U.S. margin where the only known evaporite deposits are found, and this salt basin may reserve large amounts of oil and gas (Carpenter & Amato, 1992). Therefore, analysis of 2D multichannel seismic reflection surveys that were conducted in the Mid-South Atlantic Ocean in 1982 plays an important role in Petroleum industry. In addition, current interpretations …

Assessment Of Upper Cretaceous Strata For Offshore Co2 Storage: Southeastern United States, Khaled F. Almutairi

Theses and Dissertations

This is the first assessment of Upper Cretaceous strata for offshore CO2 storage resources in the southeastern United States outer continental shelf. This research focuses on Upper Cretaceous geological units using legacy industry 2-D seismic reflection and well data. It provides an integrated description and reliable subsurface evaluation of Upper Cretaceous potential storage reservoirs. In addition, it provides a detailed evaluation on how rock porosities and permeabilities are distributed across the Upper Cretaceous strata restricted to the South Georgia Embayment (SGE). Structure and thickness (isochore) maps were generated for the main potential reservoirs and seals on a regional and local …

Glacial To Holocene Changes In Eastern Equatorial Pacific Deep-Water Chemistry And Circulation, Natalie E. Umling

Theses and Dissertations

It has been hypothesized that the oceans store CO2 during glacial periods and then release it to the atmosphere, causing the onset of warm interglacial periods (Sigman and Boyle, 2000). Documenting this past transfer of CO2 between the oceans and atmosphere is of utmost importance for better understanding the impact that anthropogenic CO2 has and will have on Earth’s climate. The last deglaciation is a good analogue to modern increases in CO2 and temperature and is recent enough to be studied using radiocarbon. This period provides important insights into the nature of climate changes during the transition from glacial to …

Subsurface Transport In A North Inlet, South Carolina Salt Marsh: A Porewater Salinity Model, Carolyn Ryan

Theses and Dissertations

Subsurface transport in coastal salt marshes influences the nutrient budget of coastal environments, but is not fully understood. To expand our understanding of this transport, a simple numerical model was developed. The model simulated vertical transport of salt through the surficial muds at a North Inlet marsh on the coastal plain of South Carolina. To improve the model, a tracer study was utilized to calculate the average velocity of groundwater flow through the system. The model was compared with porewater salinity measured using tension samplers and passive diffusion samplers. Each method produced different, uncorrelated results. However, accounting for macro-pores in …

The Summerville Formation: Evidence For A Sub-Horizontal Stratigraphic Sequence Below The Post-Rift Unconformity In The Middleton Place Summerville Seismic Zone, Joseph Edward Getz

Theses and Dissertations

The Middleton Place Summerville Seismic Zone (MPSSZ) near Summerville, South Carolina was the site of renewed extensive investigation, beginning in the 1970’s, for the source of the 1886 Charleston earthquake. Reactivation of faults associated with a putative fault-bounded Triassic rift basin through analysis of seismic reflection, seismic refraction, and well data has since become the favored interpretation for the source of MPSSZ seismicity. Critical to this interpretation is the association of continental redbed sedimentary rocks in Triassic basins throughout the North American Atlantic margin. Reanalysis of 18 seismic reflection profiles and 25 seismic refraction profiles within the MPSSZ suggests that …

Utilizing Structure-From-Motion Photogrammetry And Unmanned Aerial Vehicles To Characterize Variability In Fluvial Deposits From The Salt Wash Member Of The Morrison Formation, East-Central Utah, John Chesley

Theses and Dissertations

Modern fluvial systems are highly variable, often containing the entire spectrum of fluvial styles (e.g., braided to meandering). This variability is difficult to capture in ancient fluvial deposits due to limited 1- and 2-dimesional exposures, which provide only a snapshot of the depositional history at one location. As a result, researchers are forced to interpolate between exposures and develop regional scale models that often underestimate the complexity and variability seen in modern environments. Outcrops of the Upper Jurassic Salt Wash Member of the Morrison Formation in east-central Utah, USA provide a relatively unique opportunity to examine ancient fluvial sandstone bodies …

Drivers Of Sediment Accumulation And Nutrient Burial In Coastal South Carolina Residential Stormwater Detention Ponds, William Schroer

Theses and Dissertations

Stormwater detention ponds are widely utilized as control structures to manage runoff waters during storm events. These sediments also represent significant sites of organic carbon and nutrient burial. Here, carbon (C) and nutrient sources and burial rates were determined in 14 residential stormwater detention ponds throughout coastal counties of South Carolina. Bulk sediment accumulation was directly correlated with catchment impervious surface coverage (R2 = 0.90) with sediment accumulation rates ranging from 0.06 to 0.50 cm y-1. These rates of sediment accumulation and subsequent pond volume loss are lower than expected indicating that required maintenance dredging schedules be reassessed. Strong, positive …

Serpentinization And Synthesis: Searching For Abiotic And Biotic Non-Volatile Organic Molecules In The Subsurface Of The Atlantis Massif, Katherine A. Hickok

Theses and Dissertations

High concentrations of hydrogen created during serpentinization can promote the formation of abiotic organic carbon molecules such as methane, formate, and short chain hydrocarbons and, in laboratory experiments, larger molecules containing up to 32 carbon atoms. Subsurface archaeal and bacterial communities can use these reduced compounds for metabolic energy. International Ocean Discovery Project Expedition 357 drilled 17 boreholes into the Atlantis Massif with the goals of investigating carbon cycling and the presence of life in a zone of active serpentinization. The expedition recovered multiple lithologies including gabbros, basalts, carbonate sands, and serpentinites. A subset of contrasting lithologies were analyzed for …

Carbon Sources To Microbes And Cryoconite On Alaskan Alpine Glacier Surfaces, Drake Mccrimmon

Theses and Dissertations

Cryoconite are depressions in the ice surface filled with diverse microorganisms and dark debris, which are reducing albedo and increasing glacier melt. In order to understand cryoconite carbon composition and carbon sources to microorganisms living on glacier surfaces, bulk organic carbon and microbial lipids from supraglacial cryoconite sediment within the ablation zones of Spencer, Matanuska, and Mendenhall glaciers in southern Alaska have been coupled with radiocarbon (14C) analyses. The microbial lipids analyzed in these studies, phospholipid fatty acids (PLFA), are components of microbial membranes, quickly degrade after cell death, and give a snapshot of the viable microbial community. PLFA structure …

High Resolution Gravity, Helicopter Magnetic, And Electromagnetic Study, Haile Gold Mine, South Carolina, Saad Saud Alarifi

Theses and Dissertations

The goal of this research was to calibrate and test geophysical methods for the detection of disseminated sulfides in the area of the Haile Gold Mine, South Carolina. The work focused on the calibration of high resolution gravity, and helicopter electromagnetic (EM) and magnetic data provided by OceanaGold. While high resolution potential field data (gravity and magnetics) has not been proven to be effective at small scales in exploration for disseminated sulfides, there is a strong regional correlation between high amplitude gravity and magnetic anomalies and the most productive gold mines in the Carolina terrane. Helicopter EM methods have been …