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Shock Effects Recorded By The U-Pb Radiometric System In Zircons Of Apollo 17 Impact Breccias And By Raman Spectroscopy In Enstatite Meteorites, Bidong Zhang

Electronic Thesis and Dissertation Repository

Impact cratering processes and formations are ubiquitous on the rocky planets within the Solar System. The Earth-Moon system was formed by a massive planetary impact, and numerous impacts afterwards significantly reshaped the topography and lithology of the Moon surface. This dissertation focuses on studying some specific geochemical, geochronological, and geophysical signatures of impact processes preserved in lunar rocks and asteroidal meteorites.

The zircon U-Pb radiometric system is one of the most reliable geochronometers in measuring geological time. Recently, unsupported radiogenic Pb enrichment has been reported to compromise the accuracy and precision of zircon U-Pb geochronometer in terrestrial rocks. In Chapter …

An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal

MSU Graduate Theses

Rigorous study of the speciation distribution of uranyl-chloride bearing solutions under hydrothermal conditions is important to understand the transport mechanism of uranium underground, which is of uttermost interest to parties studying the geological uranium deposits and those studying the possibilities of geological repositories for spent nuclear waste. I report an in-situ Raman spectroscopic study of the speciation distribution of aqueous uranyl-chloride complexes upto 500°C conducted using a HDAC as the high PT spectroscopic cell. The samples studied contained the species UO₂²⁺, UO₂Cl⁺, UO₂Cl₂⁰ and UO₂Cl₃^{- …}

Local Environmental Controls On Sulfur Isotope Ratios In Marine Sedimentary Iron Sulfide Minerals, Roger Nicholas Bryant

Arts & Sciences Electronic Theses and Dissertations

The controls on the bulk sulfur isotopic composition of marine sedimentary iron sulfides (often referred to simply as pyrite; δ34Spyr) are poorly understood. Nevertheless, many have employed δ34Spyr in efforts to reconstruct the past operation of the biogeochemical sulfur cycle, from the planetary scale down to individual microbial metabolisms. This practice has been thrown into doubt by a growing body of evidence that suggests δ34Spyr is strongly controlled by local environmental conditions. This dissertation describes efforts to determine the mechanisms responsible for the link between local environmental conditions and δ34Spyr. In order to do this, we developed novel laboratory procedures …