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Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan Aug 2014

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …


Investigating Telogenetic Karst Aquifer Processes And Evolution In South-Central Kentucky, U.S., Using High-Resolution Storm Hydrology And Geochemistry Monitoring, Nicholas Lawhon May 2014

Investigating Telogenetic Karst Aquifer Processes And Evolution In South-Central Kentucky, U.S., Using High-Resolution Storm Hydrology And Geochemistry Monitoring, Nicholas Lawhon

Masters Theses & Specialist Projects

Recent studies have investigated the hydrological and geochemical characteristics of karst aquifers in different settings; however, telogenetic karst aquifer processes remain poorly understood. In south-central Kentucky, the iconic Lost River Cave and Valley represents a large, complex telogenetic karst drainage basin with a series of discharge points along a collapsed section of the cave. Two Campbell Scientific® CR1000 automated dataloggers were installed at Blue Hole Four, a primary discharge point of the Lost River Karst Aquifer (LRKA). These dataloggers recorded spring discharge, water temperature, specific conductance (SpC), and pH at ten-minute intervals from January to November, 2013. During the year, …


Impacts Of Carbonate Mineral Weathering On Hydrochemistry Of The Upper Green River Basin, Kentucky, Laura Leigh Osterhoudt May 2014

Impacts Of Carbonate Mineral Weathering On Hydrochemistry Of The Upper Green River Basin, Kentucky, Laura Leigh Osterhoudt

Masters Theses & Specialist Projects

Kentucky’s Upper Green River Basin has received significant attention due to the area’s high biodiversity and spectacular karst development. While carbonate bedrock is present throughout the watershed, it is more extensive and homogenous along the river between Greensburg and Munfordville than upstream from Greensburg where the geology is more heterogeneous. This research quantitatively evaluated how lithological differences between the two catchment areas impact hydrochemistry and inorganic carbon cycling. This first required correcting catchment boundaries on previous US Geological Survey Hydrologic Unit Maps to account for areas where the boundaries cross sinkhole plains. Basin boundaries using existing Kentucky Division of Water …


Geologic Factors Affecting Hydrocarbon Occurrence In Paleovalleys Of The Mississippian-Pennsylvanian Unconformity In The Illinois Basin, Jeremy Taylor London May 2014

Geologic Factors Affecting Hydrocarbon Occurrence In Paleovalleys Of The Mississippian-Pennsylvanian Unconformity In The Illinois Basin, Jeremy Taylor London

Masters Theses & Specialist Projects

Paleovalleys associated with the Mississippian-Pennsylvanian unconformity have been identified as potential targets for hydrocarbon exploration in the Illinois Basin. Though there is little literature addressing the geologic factors controlling hydrocarbon accumulation in sub-Pennsylvanian paleovalleys basin-wide, much work has been done to identify the Mississippian-Pennsylvanian unconformity, characterize the Chesterian and basal Pennsylvanian lithology, map the sub-Pennsylvanian paleogeology and delineate the pre-Pennsylvanian paleovalleys in the Illinois Basin. This study uses Geographic Information Systems (GIS) to determine the geologic factors controlling the distribution of hydrocarbon-bearing sub-Pennsylvanian paleovalley fill in the Illinois Basin. A methodology was developed to identify densely-drilled areas without associated petroleum …