Digital Commons Network^™

Searching For The Hyperobject: Crystals As Transscalar Vehicles, Jay Costello

Masters Theses

When I touch the street outside my house, I'm touching Los Angeles—a contiguous vector of material bisecting a continent. A slab, a stone, dust and oil, a googolplex of tightly packed anisotropic particles... At nightfall, I sneak to the edge of the highway and break off a piece. 'What does it mean for a worm to be aware of the scale of the planet?' Bruno Latour's evocative questioning of scalar jumps prompts an existentialism that places me somewhere between the hyperlocal and the massively distributed. Like a cosmic traveler floating through the universe, I feel adrift. I look around, grasping …

Numerical And Experimental Constraints On Trace Element Fractionation During Lunar Magma Ocean Solidification, Dian Ji

Masters Theses

Traditional lunar magma ocean (LMO) theory suggests the anorthositic lunar crust formed by floating of buoyant plagioclase, one of the major products of LMO solidification, on the surface of LMO. To test this model, after applying experimentally determined LMO solidification sequences, we compared calculated Rare Earth Element (REE) concentrations of lunar plagioclase to plagioclase in Apollo ferroan anorthosites and lunar anorthositic meteorites. Several initial LMO compositions, and lunar-relevant mineral-melt partition coefficient predictive models were tested (where the partition coefficient is the concentration ratio of a specific element between two phases). Compared with plagioclase in the natural samples, modeled plagioclase directly …

Evaluating Bulk Carbon And Nitrogen Isotope Compositions Of Acidic Hydrothermal Sediments On Earth– Implications For Mars Astrobiology, Chance Sturrup

Masters Theses

Carbon isotopes have been widely used as unique biosignatures because biologic processes commonly result in distinctive negative delta ¹³C values (-35 to -10 ‰) within organic material on Earth. However, the bulk delta ¹³C analysis in Gale crater sediments on Mars revealed a wider range of values, from -25 to +56 ‰ (Franz et al., 2020), which suggests a more complex origin. To determine if bulk isotope analysis can be successfully used to detect a microbial signature in a martian analog environment, we analyzed concentrations and isotope compositions of C within hydrothermal sediments in Iceland (Námafjall, Krýsuvík, Hveragerdi) …

Concept Validation: Collecting Composite Samples To Understand The Presence Of Per- And Polyfluoroalkyl Substances (Pfas) In Michigan Forested Areas, Nicole Renee Sanabria

Masters Theses

This research discusses the results of a state-wide study conducted by The Michigan Department of Environment, Great Lakes, and Energy to assess the presence of PFAS in shallow soils of state-owned forested areas in Michigan utilizing a composite sampling method. One sample collected from each of Michigan’s 83 counties reveals the presence of PFAS in all but one sample, with total PFAS concentrations ranging from non-detect to 2.016 μg/kg (dry weight). PFOS is generally detected at the highest concentrations, ranging from non-detect to 0.88 μg/kg, followed by PFBA, with concentrations ranging from non-detect to 0.69 μg/kg, and PFOA, with concentrations …

Using Sedimentary Mercury Geochemistry To Evaluate The Niagara-Salina Transition, Silurian Michigan Basin, Usa, Sara Hayes

Masters Theses

The Niagara-Salina boundary in the Michigan Basin is marked by an abrupt transition from carbonates to evaporites. Though the cause is uncertain, previous work suggests the onset of Salina evaporites was driven by basin restriction, but the presence of several global carbon isotope excursions (CIE) suggest a global driver. This study builds on this discussion using two relatively new geochemical proxies - elemental mercury concentrations [Hg] and Hg isotopes.

Mercury concentrations [Hg] were measured in 88 samples from the State Kalkaska #2-15 core from 6604.03 ft to 6797.42 ft. [Hg] ranges from 0.11 to 0.62 mg/kg and [Hg]/TOC from 0.038 …

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …

Experimental Alteration Of Venusian Surface Basalts In A Hybrid Co2-So2 Atmosphere, Robert B. Reid

Masters Theses

Venus’ surface and interior dynamics remain largely unconstrained, due in great part to the major obstacles imposed by its 470°C, 90 bars surface conditions and its thick, opaque atmosphere. Orbiter-based thermal emission data provide an opportunity to characterize the Venus surface. However, interpretations of such spectra critically depend on understanding interactions between the planet’s surface basaltic rocks and its caustic, SO₂-bearing CO₂ atmosphere. Several studies, using remote sensing, thermodynamic modeling, and laboratory experiments have placed constraints on alteration mineralogies and rates. Yet constraint with respect to SO₂-mediated reactions with basalts of contrasting compositions remains incomplete. …

Multiple Generations Of Phlogopite In An Alnöite Diatreme: Insights Into The Petrogenesis Of The Avon Alkaline Igneous Province, Missouri, Nathan Gregory Limbaugh

Masters Theses

“Alkaline Ultramafic Carbonatite (AUC) complexes, although rare, are valued for diamonds and REEs, and as windows into subcontinental and mantle processes as recorded by rock fabrics, mineral spatial relationships, and mineral compositions. We report specifically on olivine and phlogopite petrographic relationships and compositions from the Devonian alnoite diatreme-facies of the Avon Alkaline Igneous Province, Missouri. The diatreme alnoite is a mixture of domains of olivine magmaclasts (OM) set in a crystal-rich melilite matrix. OM are highly fractured, serpentinized olivine pseudomorphs with variable amounts of pristine olivine fragments. Larger olivine domains typically exhibit clear crystal faces and irregular “channels” indicative of …

Relationships Among Mineralogy, Geochemistry, And Oil And Gas Production In The Tuscaloosa Marine Shale, Hayley Roxana Beitel

Masters Theses

"The Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir located in southeast Louisiana and southwest Mississippi. Limited mineralogical and geochemical data for the TMS have been published. The data that do exist indicate that the formation is heterogeneous. Consequently, previous investigators and oil and gas companies have not managed to effectively link mineralogical and chemical changes to oil and gas production in the TMS. These linkages are critical to establish for future exploration efforts. In this study, we attempt to establish these relationships by gathering all existing mineralogical and chemical data in the TMS, including newly acquired data from …

Carbon Metabolism In Cave Subaerial Biofilms, Victoria E. Frazier

Masters Theses

Subaerial biofilms (SABs) grow at the interface between the atmosphere and rock surfaces in terrestrial and subterranean environments around the world. Multi-colored SABs colonizing relatively dry and nutrient-limited cave surfaces are known to contain microbes putatively involved in chemolithoautotrophic processes using inorganic carbon like carbon dioxide (CO₂) or methane (CH₄). However, the importance of CO₂ and CH₄ to SAB biomass production has not been quantified, the environmental conditions influencing biomass production and diversity have not been thoroughly evaluated, and stable carbon and nitrogen isotope compositions have yet to be determined from epigenic cave SABs. …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Mineral Compositions Of Meteorite Samples Alha 77005, Nwa 7397, Nwa 5480, And Ausson: Implications For Geodynamic Processes On Their Parent Bodies And Meteorite Reclassification, Kaylin Agnata Tunnell

Masters Theses

“This study investigates the major, minor, and trace element compositions of minerals from a series of meteorites which represent different stages of planetary evolution including two sample from Mars (ALHA 77005 and NWA 7397), one sample from Vesta (NWA 5480), and one ordinary chondrite (Ausson). The goal of this study is to investigate if petrogenetic tracers commonly employed to understand terrestrial samples can also be applied to extraterrestrial samples. The data presented here show that mineral trace element data allow for novel insight into the magmatic history of meteorite samples. For example, V/Sc and Fe/Mn ratios in olivine provide insight …

Exploration For Alteration Halos Around The Ag-W Deposits In Southeastern Missouri, Usa, Daniel Joseph Warbritton

Masters Theses

"The St. Francois Mountains in SE Missouri are an extensive terrane of granitic ring complexes and associated rhyolites. They were an important source of Ag, W, and Sn and mined intermittently from the 1800s until the 1950s. The Ag-W ores occur in the Silvermine Granite and rhyolite roof rocks. The deposits are classified as a xenothermal ore system with mineralization occurring in quartz veins and surrounding greisen (up to 2.5 m). Exploration for hydrothermal ore deposits often focuses on the identification of alteration halos in the surrounding host rocks. In the vast majority of xenothermal ore deposits, such as in …

Geochemical And Petrological Investigation Of The Prospective Ni-Cu-Pge Mineralization At The Echo Lake Intrusion In The Upper Peninsula Of Michigan, Usa, Alexander J. Koerber

Masters Theses

The Echo Lake Intrusion is located in Houghton and Ontonagon counties in the Upper Peninsula (UP) of Michigan. The intrusion is approximately 200 m below the surface and covers approximately 18 km2 in lateral extent. It is associated with the magmatic activities of a 1.1 Ga geologic event called the Midcontinent Rift. The rift is responsible for the formation of Ni-Cu ± PGE deposits in the Lake Superior Region. Based on its association with the Midcontinent Rift and a Cu and PGE enriched layer, the Echo Lake intrusion is identified as a prospect for an economic magmatic sulfide deposit.

The …

Development Of Nuclear Underground Engineered Test Surrogates For Technical Nuclear Forensics Exploitation, Robert Boone Gilbreath

Masters Theses

A method for formulation and production of Nuclear UnderGround Engineered Test Surrogates (NUGETS) based on notional improvised nuclear device (IND) detonations in an underground environment analogous to the Nevada National Security Site (NNSS) is presented. Extensive statistical analyses of precursory geochemical and geophysical characteristics are combined with an augmented surrogate debris cooling technique and predictive IND contributions from the ORIGEN Fallout Analysis Tool. Precursory and resultant elemental compositions, cooling curve calculations, and visual comparison of NUGETS to genuine underground debris are reported. Application of NUGETS methodology to future studies in urban, underground post-detonation technical nuclear forensic (TNF) analysis is suggested.

Determining Sources Of Nitrate In The Semi-Arid Rio Grande Using Nitrogen And Oxygen Isotopes, Diego Alberto Sanchez Hernandez

Masters Theses

The Rio Grande, a semi-arid river in the American Southwest, is a major source of surface water for agriculture and drinking supplies in New Mexico and Texas. In addition to increasing salinity, considerable increases of NO₃^- [nitrate] have been observed in the semi-arid portion of the Rio Grande. It is possible that elevated water salinity inhibits denitrification on irrigated fields and, thus, fails to mediate excess nutrient load from anthropogenic activities. Therefore, two major goals of this project were to 1) characterize and quantify major NO₃^- sources, and 2) assess whether elevated water salinity affects microbial …

Role Of Sorting On The Composition Of Siliciclastic Sediment: Implications For Interpreting Provenance After Limited Transport In An Arid Climate, Forrest Christopher Driscoll

Masters Theses

This study tested whether transport distances (< 500 m) have the capacity to shape the geochemistry of sediments across multiple grain-size populations due to sorting derived from a single source. In the Stepladder Mountains, Mojave Desert, CA, a < 1 km² [square kilometers] watershed allows for a controlled study to understand how modern sediments acquire their composition from a single granodioritic source in an arid climate where there is no chemical weathering. Sediments are naturally sorted into distinct grain-size populations, with modes ranging from very fine sand to gravel within a single, alluvial channel. Sediment samples representative of each population were petrographically and geochemically analyzed in order to test the effectiveness of commonly used discrimination diagrams. Sediments became proportionally enriched in plagioclase and biotite and depleted in K-feldspar and quartz with decreasing grain …

Geochemical And Petrological Characterizations Of Peridotite And Related Rocks In Marquette County, Michigan, Andrew Lloyd Sasso

Masters Theses

This study characterizes the following rock units in Marquette County, Michigan in terms of geochemistry and petrology: (1) Presque Isle Peridotite, (2) Deer Lake Peridotite, (3) Yellowdog Peridotite, and (4) Black Rock Point Gabbro. Analyses were conducted to determine if any petrological or geochemical relationships exist between these units, and to assess the potential of these units to host magmatic sulfide deposits.

The generated data and chosen geotectonic proxies indicate that Black Rock Point Gabbro and Deer Lake Peridotite crystallized from unrelated magmas, probably during the formation of the Great Lakes Tectonic Zone (2.7-1.85 Ga). No evidence was found which …

Geochemical And Petrological Studies On The Origin Of Nickel-Copper Sulfide Mineralization At The Eagle Lntrusion In Marquette County, Michigan, Benjamin Davis Hinks

Masters Theses

The Eagle magmatic intrusion is located in the Upper Peninsula of Michigan in Marquette County. It hosts a high grade magmatic nickel-copper sulfide ore deposit. Country rocks surrounding the Eagle intrusion are metamorphosed slate and greywacke of the Proterozoic Michigamme Formation and Archean granite-gneiss. The aim of this thesis is to characterize the magmatic sulfide mineral deposit at Eagle and to establish its relationship to the surrounding host rocks of the Baraga Basin area.

The Eagle East intrusion is located 600 meters east of the Eagle intrusion. These two intrusions are similar in composition and sulfide mineralization. Sulfide textural domains …

Avon Alkaline Igneous Province, Missouri: Characterization Of Subcontinental Mantle Source And Evolution Via Chemical Analysis Of Olivine, Zachary William Freeman

Masters Theses

"This article presents the crystallization age of, and composition of olivine phenocrysts within an alnoite of, the Avon Alkaline Igneous Province (AAIP) of Ste. Genevieve County, Missouri. The AAIP is an ultramafic igneous province consisting of approx. 80 known intrusives of diverse lithology and texture. ⁴⁰Ar/³⁹ Ar geochronology indicates an emplacement age of 386 +/- 1 Ma, which establishes the AAIP as the only known Devonian-age ultramafic igneous body in the Midwestern U.S. Study of the AAIP provides a unique opportunity to characterize the Devonian-age subcontinental mantle and the processes that generated the suite of ultramafic rocks present …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Petrological And Geochemical Evaluation Of The Sturgeon Falls Intrusive Body, Jonathan Michael Haynes

Masters Theses

The Sturgeon Falls Intrusive Body (SFIB) is a gabbroic intrusion located along the Michigan-Wisconsin border just south of the town of Norway, MI. The SFIB is bounded to the north by the Niagara Shear Zone and the Michigamme Formation (Schulz and Cannon, 2006) and to the south by an unnamed thrust fault zone and the Quinnesec Formation (Sims and Schulz, 1993). Field mapping has shown that the SFIB is composed almost entirely of metagabbro metamorphosed to greenschist facies, with isolated outcrops of clinopyroxenite, which are thought to be xenoliths.

The origin of the SFIB is controversial. Schulz and LeBerge (2003) …

Environmental Controls On The Diversity And Distribution Of Endosymbionts Associated With Phacoides Pectinatus (Bivalvia: Lucinidae) From Shallow Mangrove And Seagrass Sediments, St. Lucie County, Florida, Thomas Walters Doty

Masters Theses

Lucinid bivalves are capable of colonizing traditionally inhospitable shallow marine sediments due to metabolic functions of bacterial endosymbionts located within their gills. Because lucinids can often be the dominant sediment infauna, defining their roles in sediment and pore fluid geochemical cycling is necessary to address concerns related to changes in coastal biological diversity and to understanding the sensitivity of threatened coastal ecosystems over time. However, there has been limited research done to understand the diversity and distribution of many lucinid chemosymbiotic systems. Therefore, the goals of this thesis were to evaluate the distribution of Phacoides pectinatus and its endosymbiont communities …

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

A Geochemical Investigation Of Co₂ Sequestration And Site Characterization At Two Missouri Locations, Robert Allen Swain

Masters Theses

"The feasibility of sequestering CO₂ in saline aquifers of Lamotte Formation sandstone was investigated at wells located near Thomas Hill power plant, Moberly, MO and Sioux City Power Plant in Florissant, MO. Governing factors of using aquifers for CO₂ disposal include water salinity, potential for carbonic acid buffering, rate of precipitation of carbonate minerals following CO₂ introduction into the host aquifer, and the integrity of the Davis and Derby-DoeRun shale as a trap rock to prevent migration of the CO₂ phase and carbonic acid into the overlying potable Ozark Aquifer.

Both in situ and laboratory methods …

Calcitized Evaporites In The Precambrian: Deposition And Diagenesis In A Low Sulfate Ocean, Ashley René Manning Berg

Masters Theses

One of the most profound byproducts of the Great Oxidation Event (GOE) was the onset of oxidative weathering on land and the riverine delivery of sulfate to marine systems. The marine sulfur system therefore plays a critical role in reconstructing the oxygenation of the early Earth. Although the exact nature of marine oxygenation in aftermath of GOE remains uncertain, examination and modeling of marine sulfate suggest that sulfate concentrations remained below 2 millimolar (mM) until at least the middle Mesoproterozoic, and may have only reached about 10 mM in the latest Neoproterozoic. Such a low concentration of marine sulfate had …

Mineralized Microbialites As Archives Of Environmental Evolution Of A Hypersaline Lake Basin: Laguna Negra, Catamarca Province, Argentina, Joy Buongiorno

Masters Theses

Environmental fluctuations related to climate, biological productivity, and evaporation can be recorded by sedimentary archives within lacustrine depositional systems. Sediments within terminal, closed-basin lakes are amongst the most sensitive paleoenvironmental indicators, and have great potential for permitting detailed reconstruction of environmental conditions via a variety of geochemical and isotopic proxies. Microbialites, however, have been largely overlooked as repositories of paleoenvironmental data. Here, we investigate mineralized microbialites within Laguna Negra, a high-altitude (4100 meters above sea level) hypersaline, closed-basin lake in the Argentinian Puna region and explore the potential recovery of environmental signals from these unique sedimentary archives. Mineralized microbialites within …

Characterizing The Relationship Of Part Of The Inner Piedmont And Pine Mountain Window, Georgia, From Detailed Geologic Mapping, Geochemistry, Geochronology, And Structural Analysis At The Southwestern End Of The Cat Square Terrane, Justin Randolph Rehrer

Masters Theses

Geologic investigations at the southwestern end of the Cat Square terrane (CSt) in central Georgia provided new insight into the complex tectonic history of the Pine Mountain window (PMw) and neighboring Inner Piedmont terranes. Detailed 1:24,000-scale geologic mapping of an approximately 180 km2 area near Barnesville, Georgia has provided the foundation for further geochemical, geochronologic, and structural analyses refining models for tectonic development and emplacement of the CSt and PMw.

Whole-rock geochemical analyses of several CSt amphibolites yielded data suggesting a continental back-arc setting for genesis of the Cat Square basin (CSb). Major element data confirm derivation from a basaltic …

Hydrogeology Of The Little River Animal Agriculture Environmental Research Unit And Impacts Of Dairy Operations On Groundwater, Robert Wesley Hunter

Masters Theses

This thesis describes the development of an integrated hydrogeologic/hydrologic site assessment and groundwater/surface water quality monitoring program at the University of Tennessee – Little River Dairy Farm, located near Townsend, TN. Hydrologic/hydrogeologic investigations of streams and groundwater at the site have been underway for more than 5 years, and these are expected to provide background data for assessing impacts of dairy wastes. The lower half of the ~180 ha site consists of low-relief fields used for row crops, which are underlain by 4 – 9 m of alluvial deposits on top of black shale or limestone that include sinkhole features. …

Surface Complexation Modeling Of Cr(Vi) Absorption On Mineral Assemblages, Ann M. Gilchrist

Masters Theses

Hexavalent chromium (Cr(VI)) is a waste product of many anthropogenic processes. Because it is highly mobile, the improper disposal of Cr(VI) has caused widespread contamination. Because reduction and adsorption reactions may reduce the bioavailability and mobility of Cr(VI) in environmental systems, a better understanding of Cr(VI) adsorption behavior will improve remediation efforts.

Subsurfaces and soils are heterogeneous, however most studies focus on single sorbate/sorbent interactions to develop surface complexation models (SCM) for prediction of heavy metal adsorption. Theoretically, combining the SCMsdeveloped for single sorbate/sorbent systems should yield accurate predictions of adsorption in more complex systems (i.e., the component additivity approach …