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Distribution Of Trace Elements In Cumberland River Basin Reservoir Sediments, Laura Mahoney Benneyworth

Masters Theses & Specialist Projects

The U.S. Army Corps of Engineers, Nashville District, maintains ten reservoirs in the Cumberland River Basin in Kentucky and Tennessee, and has been monitoring sediment chemistry in the reservoirs since 1994. The purpose of this study is to evaluate the sediment data collected from the reservoirs from 1994 to 2010 to determine if there are any spatial patterns of the trace elements: arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, and zinc. The results indicated that trace element levels were consistent with national baseline concentrations measured by the U.S. Geological Survey. Center Hill reservoir had the greatest number of trace …

Multiple Storm Event Impacts On Epikarst Storage And Transport Of Organic Soil Amendments In South-Central Kentucky, Sean M. Vanderhoff

Masters Theses & Specialist Projects

The groundwater in agricultural karst areas is susceptible to contamination from organic soil amendments and pesticides. During major storm events during 2011, dye traces were initiated using sulphorhodamine-B, fluorescein and eosine in a groundwater recharge area where manure was applied to the ground. Fecal coliform samples were collected from significant storm events from January-September 2011. Water samples and geochemical data were collected every four hours before, during, and between the storm events from a waterfall in Crumps cave flowing from the known recharge area to track the transport and residence time of the epikarst water and organic soil amendments during …

Determining The Viability Of A Hybrid Experiential And Distance Learning Educational Model For Water Treatment Plant Operators In Kentucky, Jana R. Fattic

Masters Theses & Specialist Projects

Drinking water and wastewater industries are facing a nationwide workforce shortfall of qualified treatment plant operators due to factors including the en masse retirement of baby boomers and the tightening of regulatory requirements regarding the hands-on experience required prior to licensure. Rural areas are hardest hit due to the lack of educational and experiential opportunities available to them within a reasonable proximity. Using a variety of demographic and industry data, a geographic analysis of Kentucky was conducted to assess the viability of the traditional classroom delivery model versus a hybrid experiential and distance learning educational model (HEDLEM). Although this analysis …

National Park Service Cave And Karst Resources Management Case Study: Great Smoky Mountains National Park, Daniel C. Nolfi

Masters Theses & Specialist Projects

As discussed in the National Parks Service’s (NPS) Directors Orders/Natural Resources Management Reference Manual #77 and the 2006 NPS Management Policy Handbook, implementing a management plan specifically for cave and karst resources within a national park is paramount to afford these resources appropriate protection. With support from the Federal Cave Resources Protection Act and the National Park Service Organic Act of 1906, management actions protecting caves has begun to place significant importance outside the traditional cave environment onto a broader karst landscape. The need to understand and protect the karst environment and caves as a karst resource has taken a …

Determining The Lon-Exchange Mechanism Of Strontium Into A Niobium Doped Titanosilicate, Samantha Jane Kramer

Masters Theses & Specialist Projects

A 25% niobium substituted sitinakite was exchanged with strontium as time resolved X-ray diffraction data was collected. The structural modeling of this data by Rietveld method1 has lead to the determination of the atomic positions of the ions and unit cell parameters as strontium occupancy increases.

The starting material of the exchange experiment is the protonated phase, H2Nb0.67Ti1.33SiO7·1.9 H2O, with space group P42/mcm2,3. Once strontium (Sr2+) enters the unit cell, extra-framework H2O molecules shift to provide the necessary hydration coordination. These new positions of H2O result in a lowering of symmetry to the P-42m space group, and it is thought …