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Environmental Sciences

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Theses/Dissertations

2009

Photochemistry

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Metal Oxide And Mercuric Sulfide Nanoparticles Synthesis And Characterization, Xin Xu Dec 2009

Metal Oxide And Mercuric Sulfide Nanoparticles Synthesis And Characterization, Xin Xu

All Dissertations

Increasing applications of nanoparticles (NPs), such as metal oxide and mercuric sulfide NPs, lead to heightened environmental concern. Challenges to the study of natural and engineered NPs include the physical and chemical characterizations.
Commercially available and laboratory-synthesized metal based NPs, iron oxide (Fe2O3), copper oxide (CuO), titanium dioxide (TiO2), zinc oxide (ZnO) and mercuric sulfide (HgS) were studied by comprehensive characterizations methods. The general synthesis process was modified sol-gel method. The size and morphology of NPs could be influenced by temperature, sonication, calcination, precursor concentration, pH and types of reaction media. In the synthesis of nZnO in ethanol, the essential …


Cavity Ring-Down Spectroscopic Study Of Gas-Phase Photolysis Of Unsaturated Dicarbonyls And Aromatic Aldehydes, And Surface Photolysis Of Acetaldehyde, Bin Xiang Jan 2009

Cavity Ring-Down Spectroscopic Study Of Gas-Phase Photolysis Of Unsaturated Dicarbonyls And Aromatic Aldehydes, And Surface Photolysis Of Acetaldehyde, Bin Xiang

Legacy Theses & Dissertations (2009 - 2024)

Photochemical smog is a phenomenon associated with pollution in urban atmospheres arising from the photochemical oxidation of volatile organic compounds (VOCs) in the presence of nitrogen oxides. The oxidation process can lead to ozone and secondary air pollutants including particle formation which reduce visibility. The term "photochemical smog" is used to describe this pollutant mixture. The further degradation of secondary air pollutants could also have an impact on the atmospheric oxidation capacity. However, the atmospheric degradation mechanisms of the secondary pollutants are still not fully understood. In this dissertation, cavity ring-down spectroscopy combined with laser photolysis and Fourier transform infrared …