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Carbon Dynamics In Peat Bogs: Insights From Substrate Macromolecular Chemistry, Kuder Tomasz, Michael A. Kruge Sep 2001

Carbon Dynamics In Peat Bogs: Insights From Substrate Macromolecular Chemistry, Kuder Tomasz, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The macromolecular compositions of subfossil plants from boreal Sphagnum bogs and restiad bogs (New Zealand) have been studied by pyrolysis-gas chromatography/mass spectrometry to evaluate the extent of degradation in the anoxic zone (catotelm) of a peat bog. Degradation of vascular plant polysaccharides was apparent only into the upper catotelm. Sphagnum was degraded more slowly than vascular plants, but no cessation of degradation was observed. The inferred rate of degradation varied depending on type of plant, extent of aerobic, precatotelmic degradation, and mode of litter deposition (rooting versus at the surface). Environmental forcing on anaerobic carbon dynamics would potentially be largest …


An Environmental Geochemical Study Of Connecticut Marsh Sediments, Nicole A. Heller, Michael A. Kruge, Johan C. Varekamp, Tabitha Zierzow Mar 2001

An Environmental Geochemical Study Of Connecticut Marsh Sediments, Nicole A. Heller, Michael A. Kruge, Johan C. Varekamp, Tabitha Zierzow

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Core material from Spartina-dominated Housatonic and Connecticut River estuarine sites (ranging from low to high marsh) were investigated in order to test the hypothesis that organic and inorganic pollutants preferentially accumulate in the low marsh environment. Radiometric data indicate that the low marsh setting experienced sedimentation rates an order of magnitude greater than that of the mid to high marsh. The low marsh sediments from the Housatonic tend to have significantly higher concentrations of trace metals (e.g., Cu and Zn, likely contributed by brass mills formerly active upstream). Petrographic examination of the samples under reflected white and blue light …


Use Of Py-Gc/Ms Analysis Techniques In Animal Waste Management: A Preliminary Survey Of Dairy Manures, Daniel L. Vaughn, Michael A. Kruge Jan 2001

Use Of Py-Gc/Ms Analysis Techniques In Animal Waste Management: A Preliminary Survey Of Dairy Manures, Daniel L. Vaughn, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The increasing practice of industrial-scale agriculture tends to concentrate large masses of animal waste in relatively compact areas, potentially leading to excessive release of polluting nutrients into waterways during major storms. Anaerobic treatment conditions are generally favored to conserve nitrate N as an agricultural commodity. However, overall N contents in waste are often in excess of crop fertilization needs: storing excess N in soluble nitrate form increases pollution potential. Thus the perceived needs of agriculture and society-at-large become at odds. Organic nitrogen forms (e.g., proteins) are more environmentally stable and are less subject to unintentional release. Although U.S. farmers tend …