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Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma

Dissertations

Facet engineering of nanomaterials, especially metals and metal oxides has become an important strategy for tuning catalytic properties and functions from heterogeneous catalysis to electrochemical catalysis, photocatalysis, biomedicine, fuel cells, and gas sensors. The catalytic properties are highly related to the surface electronic structures, surface electron transport characteristics, and active center structures of catalysts, which can be tailored by surface facet control. The aim of this doctoral dissertation research is to study the facet-dependent properties of metal or metal oxide nanoparticles using multiple advanced characterization techniques. Specifically, the novel atomic force microscope-scanning electrochemical microscope (AFM-SECM) and density functional theory (DFT) …

Bioremediation Of Petroleum Hydrocarbons In Coastal Sediments, Charbel Abou Khalil

Dissertations

The biodegradation of dispersed crude oil in the ocean is relatively rapid (a half-life of a few weeks). However, it is often much slower on shorelines, usually attributed to low moisture content, nutrient limitation, and higher oil concentrations in beaches than in dispersed plumes. Another factor may be the increased salinity of the upper intertidal and supratidal zones since these parts of the beach are potentially subject to prolonged evaporation and only intermittent inundation. Therefore, two laboratory experiments are conducted to investigate whether such an increase in porewater salinity results in additional inhibitory effects on oil biodegradation in seashores.

In …

Reduction Of Embodied Carbon In Buildings Through Use Of Low Carbon Strategies And Standardization And Enforcement Of Life Cycle Assessment, Bhargavi Sai Sudhakar

Master's Projects and Capstones

The building and construction industry is energy intensive and as of 2021, this industry is responsible for 37% of the total global greenhouse gas emissions. In previous studies of conventional buildings, the operational energy of a building contributed to 80% and the embodied energy contributed to 20% of the total life cycle energy. With increase in policies and standards that focus on reducing the operational energy, low energy and certified green buildings have emerged where the operational energy has considerably reduced. The relative and absolute share of embodied energy in these energy efficient buildings have increased due to excessive use …

Polyelectrolyte Functionalized Forward Osmosis For Water Reclamation From Synthetic Spacecraft Wastewater, Alina Ripp

Electronic Theses and Dissertations, 2020-

This study investigated the application of a polyelectrolyte (PE)-assisted metallic iron nanoparticle-integrated forward osmosis (FO) membrane to treat synthetic spacecraft wastewater comprising urea, ammonium carbonate, and linear alkylbenzene sulfonate (LAS). The draw solution (MgSO4) diluted via the FO operation was further treated using a nanofiltration (NF) membrane aimed at producing potable quality water by the FO-NF hybrid process. A cellulose triacetate FO membrane was functionalized by layer-by-layer deposition of polyallylamine hydrochloride (PAH) and polyacrylic acid (PAA) followed by incorporating zero valent iron nanoparticles (ZVINP) within the "bilayers". It required 14 bilayers to ensure a uniform coating as demonstrated via scanning …

Evaluation For Using Expended Bioelectrochemical Systems As Soil Amendments For Improved Corn Plant Growth And A Drought Resistant Soil., Jackson Lee Sauers

Theses and Dissertations

A long-held practice is to mix agricultural soil with a soil amendment to improve growing conditions in crops. A common soil amendment is biosolids produced from both municipal and dairy wastewater due to the macro- and micronutrients within it. Both the agricultural and wastewater industries are participating in the Circular Economy concept (CEC). Two experiments explored using expended bioelectrochemical systems (BES) that treated either synthetic dairy wastewater (DWW) or synthetic municipal wastewater (SWW) as soil amendments to improve corn plant growth when treated with three different nutrient treatments: 100%- 50%- and 0% Hoagland Nutrient Solutions. Biochar and used terracotta clay …

Resiliency Of Levee-Protected Power Networks To Flooding In A Changing Climate Integrating Environmental Justice, Seyed Saeed Miraee-Ashtiani

Theses and Dissertations

Electric power system (EPS) is an integral part of infrastructure systems. Ensuring its resiliency to extreme weather events and natural hazards is crucial to protect the safety, economy and public health. Recorded and projected data show an increase in the frequency and severity of extreme weather events and natural hazards attributed to a changing climate. It is critical to ensure the integrity of the aging infrastructure systems and to promote environmental justice by shrinking the energy-equity gap to lower power outages in disadvantaged communities.

An important aspect is the resiliency interdependency of EPS to other critical infrastructure systems, an aspect …

Effects Of Climate Change On The Probability Of Urban Tree Failures From Wind Gusts, Samuel J. Woolsey

Electronic Thesis and Dissertation Repository

Trees grown in urban environments provide environmental, economic and psychological benefits to their surrounding communities. However, urban trees also pose significant risks since damaged trees can cause serious harm to people, housing, and infrastructure by falling on sidewalks, roads, houses or power lines. To better understand the risk posed to trees by wind, models have been developed that estimates the required wind speed needed to damage a tree or group of trees, and the likelihood that such a wind speed is met or exceeded annually. The importance of such models is rising each year as the associated risk grows as …

Microbial Ecology Of Urban Sewers, Emily Lou Lamartina

Theses and Dissertations

Municipal sewage provides a glimpse into the health and activities of a human society. For more than a century, sewage exploration has helped expose the sources of disease outbreaks and track disease progression over time. Recent advancements in wastewater surveillance born from the COVID-19 pandemic have potential to enhance mitigation efforts against the decades-long global health crisis of microbial antibiotic resistance. However, critical knowledge gaps exist in wastewater surveillance, stemming from a lack of understanding in sewer microbial ecology. Ecology reveals trends in how communities respond and adapt to change, which has far-reaching implications for identifying effective strategies for disease …

Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos

Open Access Theses & Dissertations

An interpenetrating polymer network (IPN) for cation exchange applications was synthesized from a blend of styrene-ethylene/butylene-styrene (SEBS) and acrylonitrile butadiene styrene (ABS), which was 3D printed, grafted with crosslinked polystyrene (PS), and sulfonated. A method for styrene grafting was applied to reduce the damage to polymer phases caused by the sulfonation reaction. Styrene and divinylbenzene monomers were introduced to the IPN and induced with heat treatment to polymerize in situ. The graft copolymerization reaction was enhanced with varying quantities of benzoyl peroxide as a chemical initiator. The samples were subsequently sulfonated with chlorosulfonic acid in dichloroethane and functionalized for ion …

Influence Evaluation On Near-Road Concentrations Of Pm2.5 During Covid-19 Pandemic, Marcos Alan Banda Morales

Open Access Theses & Dissertations

SARS-CoV-2, also known as COVID-19, was discovered in Wuhan, China in late 2019and spread rapidly worldwide in 2020. The COVID-19 pandemic and its quarantine periods influenced the number of people using their vehicles and the number of miles traveled, which correspondingly influenced the air quality of urban areas. The influence of the restrictions caused by the quarantine period on air quality differs from location to location. Previous research accounted for countries, but no research was done at the state level individually. This research attempts to evaluate the transportation-related air quality during the COVID-19 pandemic period using data from the Texas …

Direct Potable Reuse Piloting: Optimizing Chloramination, Operationalizing Ultrafiltration, And Understanding Zero Liquid Discharge Options, Marcela Carolina Herrera

Open Access Theses & Dissertations

A pilot study was deployed at the John T. Hickerson Water Reclamation facility to analyze the viability of high recovery direct potable water reuse (DPR), aiming for zero liquid discharge (ZLD). This pilot consists of a chloramination system and ultrafiltration (UF) as pretreatment for reserve osmosis (RO) followed by UV-peroxide, granular activated carbon (GAC), and concentrate-enhanced recovery reverse osmosis (CERRO). Stabilizing the chloramination and UF system was the first step to ensure efficiency during the downstream processes. The formation of monochloramine is essential for the mitigation of biofouling of the UF membranes. The formation of monochloramine occurs by specific liquid …

A Case Study In Design, Construction, And Operation Of A Meromictic Solar Pond In Texas, Usa, Bianca Paola Meneses Brassea

Open Access Theses & Dissertations

Over the last four decades, meromictic solar ponds have been the subject of limnological studies and engineering research. A case of practical interest is the salinity gradient solar pond (SGSP). SGSP science and technologies have been systemically advanced in El Paso, Texas. This dissertation aims to share lessons learned in designing, constructing, and operating the El Paso Solar Pond, a NaCl-based solar pond that achieved high-temperature performance over two decades, commencing in 1984. Many of the practical lessons learned have not been published and are thus not readily available in archival journals, and this contribution provides a remedy. The value …

Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar

Graduate Theses and Dissertations

Environmental sustainability and human health impact of pulses produced and consumed in the United States was assessed using life cycle assessment (LCA). The study included three objectives 1) to estimate environmental impact of current production and consumption practices in the United States using attributional LCA; 2) to estimate environmental and human health impact of iso-caloric diets containing varying amounts of pulses using Hybrid-LCA and Combined Nutritional and Environmental-LCA (CONE-LCA); and 3) to estimate environmental impact of increased demand for pulses using consequential LCA. Scope of the study varied for each objective with system boundary encompassing cradle-to-grave activities for objective 1 …

Characterization And Composition Of Corrosion Scales In Drinking Water Distribution Systems, Adam Schmidt

Theses and Dissertations

Internal corrosion of drinking water pipes has received considerable attention recently in the media and in academic studies due to compliance and monitoring regulations with the Lead and Copper Rule (LCR) established by the EPA in 1991. Notable health crises involving municipalities exceeding the LCR in Washington D.C. and Flint, Michigan occurred when corrosion scale conditions changed from stable to soluble lead compounds due to changing water chemistry, leaching high amounts of lead into consumers drinking water. Understanding the role of the corrosion scale in the process of leaching lead and other toxic trace metals such as arsenic is vital …

Ligand-Promoted Dissolution Of Uranyl Phosphate Across Scales, Brennan Ferguson

All Dissertations

The formation of uranyl phosphate precipitate is a remediation strategy because the low solubility of uranyl phosphate minerals, like chernikovite, limits the mobility of uranium in contaminated soils. However, organic ligands can complex with aqueous metal cations to form more soluble species. For example, citrate is a commonly occurring organic ligand produced by plants and microbes that increases the solubility of uranium and therefore the dissolution of uranyl phosphate minerals in the uranyl phosphate-citrate system. This effect is an important control on the mobility of uranium in organic-rich, and near-surface vegetated environments. Nevertheless, key aspects of the citrate-uranyl phosphate system …

Biodegradation Of Methyl Tert-Butyl Ether And Tert-Butyl Alcohol Using Bioaugmentation With Biowish® Aqua, Elizabeth Villanueva

Master's Theses

Aqua, a commercial product manufactured by BiOWiSH® Technologies, was utilized in this research to study its effectiveness to biodegrade methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Microcosms containing varying concentrations of MTBE and TBA as well as a growth media and mineral salt solution were examined. Analytical instrumentation used in this study included the use of a gas chromatograph-mass spectrometer (GC/MS) to determine concentrations of MTBE and TBA and a spectrophotometer to extrapolate approximate active biomass concentrations in each experiment. Four different environmental conditions were tested for both MTBE and TBA. The environmental conditions tested for each contaminant included: …

Nexuscapes: A Landscape Approach For A Transdisciplinary Water-Energy-Food Nexus Decision-Making Process, Fortino Acosta

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study develops a reliable transdisciplinary framework for complex ecological and social systems by characterizing, mapping, typifying, assessing, and testing enhanced water-energy-food nexus scenarios under critical time constraints, specialized skills, or sensitive data accessibility. Detached management of limited essential resources like fresh water, reliable energy from renewable sources, and nutritious food can jeopardize regional economies and governance. Using a novel landscape approach, this study recommends a decision-making the framework focused on the circular economy that induces collaboration among diverse sectors and brings strategic coordination, specificity, and magnitude to the proposed solutions. The study elaborates on a decision-making tool that integrates …

Mysteerio: Multi-Regional Environmentally Extended Input-Output Model For United States, Yash Srivastava

All Theses

This research work titled My State Environmentally Extended Regional Input-Output (MYSTEERIO) is based on the concept of multi-regional environmentally extended input-output (MREEIO), which is a combination of lifecycle thinking and economics principles. Numerous studies have highlighted the advantages of using this methodology to determine the environmental impacts associated with economic activities for a region. However, no prior attempt has been made to conduct a state-level analysis for the US. This research work thus tries to estimate the impacts embodied due to the consumption of goods and services at the state level by using the MREEIO principles. Extensive coverage of the …

Microcosm Evaluation Of Natural And Biologically-Enhanced Abiotic Transformation Of Chlorinated Ethenes In Low Permeability Formations, Hao Wang

All Dissertations

Trichloroethene (TCE) is one of the most commonly found hazardous compounds at Superfund sites, especially in groundwater. Its volatility and toxicity pose a threat to drinking water safety and human health. In the past decades, research on the fate of TCE in the environment has shifted to contamination of low-permeability formations, for example fractured bedrock aquifers. TCE back-diffusion from low permeability zones and management of persistent TCE groundwater plumes caused by this long-term source zone pose major challenges for remediation.

Monitored natural attenuation (MNA) is a cost-effective remediation strategy that has gradually gained acceptance by regulators. Compared to extensive active …

Performance Evaluation Of Sediment Basin Designs For Highway Construction Sites In Tennessee, Jeffery Cole Emmett Jr

Masters Theses

Performance of three sediment basin designs were tested; they were: 1) the TDEC standard design with a forebay, 2) the TDOT design with an inlet check dam, and 3) the TDOT standard design that does not include an inlet check dam. An 1/17 of an acre scaled physical model sediment basin, was constructed next to an elevated outdoor open flume used to mix known water volumes and sediment mass routed by gravity-flow into the basin. The measurement for performance was simply the percent sediment mass retained in the basin from the total input per experimental run (percent sediment removal). Three …

Joint Failure Probability Of Dams Based On Probabilistic Flood Hazard Analysis, Matthew G. Montgomery

Masters Theses

Probabilistic risk methods are becoming increasingly accepted as a means of carrying out risk-informed decision making regarding the design and operation of structures such as dams. Probabilistic risk calculations require the quantification of epistemic and aleatory uncertainties not investigated through deterministic methodologies. In this hydrological study, a stochastic sampling methodology is employed to investigate the joint failure probability of three dams in adjacent, similarly sized watersheds within the same Hydrologic Unit Code (HUC) 6 basin. A Probabilistic Flood Hazard Analysis (PFHA) framework is used to simulate the hydrologic loading of a wide range of extreme precipitation events across the combined …

Biochar Amended Biological Systems For Enhanced Landfill Leachate And Lignocellulosic Banana Waste Treatment, Xia Yang

USF Tampa Graduate Theses and Dissertations

Biochar is an inexpensive and environmentally friendly carbonaceous pyrolysis byproduct with a high surface area, pore volume, and adsorption capacities for inorganic and organic compounds. The goal of this dissertation is to evaluate the feasibility of biochar application in biological treatment systems for enhanced waste management. Three major objectives guided this research to provide a compressive understanding of biochar enhancement effects on biological treatment systems for contaminant removal, energy recovery, and environmental impacts as well as essential factors influencing biochar production and properties.

In Objective 1 a low-cost hybrid Constructed Wetland (CW) system modified with biochar/zeolite was developed for enhanced …

Corrosion Performance Of Carbon And Galvanized Steel In Calcium Silicate Cement, Maria Cardoso

USF Tampa Graduate Theses and Dissertations

The concrete manufacturing industry has faced challenges with reducing carbon dioxide emissions as it currently produces about 8% of the world’s anthropogenic carbon dioxide emissions. With global atmospheric carbon dioxide concentrations being higher than ever, the solution is urgent. Due to this, a more sustainable type of concrete has been proposed.Calcium silicate cement (CSC) composed of essentially the same raw materials as ordinary portland cement (OPC) cures through the consumption of carbon dioxide rather than hydration like OPC. CSC is being explored as a potential alternative to OPC, however, there is little to no information on its corrosion related durability. …

Fabrication Of Thin-Film Composite, Reverse-Osmosis Membranes With Polyethylenimine Modifications For Enhancing Membrane Fouling Resistance, Stephanie N. Hamilton

Master's Theses

Increasing water reuse opportunities for communities has become increasingly important as access to clean water is becoming more scarce. Reverse Osmosis (RO) is an advanced treatment technology used in water recycling wastewater for potable reuse applications. RO is a promising technology; however, the membranes have limitations including their high energy demand and their susceptibility to membrane fouling. The main objective of this study was to develop a reproducible method for the fabrication of RO membranes with enhanced flux and reduced susceptibility to fouling. Literature contains numerous publications on fabrication of thin film composite (TFC) RO membranes with high performance. However, …

Barriers To Implementing Ports Energy Efficiency And Greenhouse Gas Emission Reduction Measures: Kenya’S Mombasa Port In Consideration, Alex Mwangome Mwakuni

World Maritime University Dissertations

No abstract provided.

Assessment And Prevention Of Bacterial Regrowth In Stored Household Water In Eastern Coastal Madagascar, Lauren Judah

USF Tampa Graduate Theses and Dissertations

As of 2020, diarrheal diseases were the leading cause of death in Madagascar. A major cause of diarrheal illness is contaminated water, and one crucial aspect of preventing contaminated water is safe household storage. Bacterial regrowth between point-of-collection and household storage has been well established in literature. A frequently implicated source of regrowth is the storage container’s biofilm, which is a community of varying bacteria enclosed in a “slimy” extracellular polymeric substance that forms on surfaces in wet environments and anchors bacteria to those surfaces. The overall goal of this thesis was to quantify and control bacterial regrowth in household …

Predicting Water Quality Vulnerability Under Climate Change With Machine Learning, Khanh Thi Nhu Nguyen

Doctoral Dissertations

Water quality deterioration is a global and pervasive issue due to pollution caused by industrialization, urbanization, agriculturalization, and human population growth in the modern era. This issue is even more challenging in the context of climate change due to warming temperatures and the intensification of precipitation. Therefore, assessing the potential impacts of climate change on water quality is a concern. Assessment is necessary so that planners can prepare for and reduce the negative impacts on water quality. At present, climate change impact assessment frameworks are relatively adolescent. Most studies rely on climate projections from General Circulation Models for simulations of …

Spatiotemporal Changes Of Lagged Compound Dry And Wet Spells In The Northwest North America Under Climate Change, Reza Rezvani

Electronic Thesis and Dissertation Repository

Recently, an upsurge in the occurrence of hydroclimatic extremes and their temporal swings is observed in several regions around the world. Such transitions to the contrasting extremes such as the drought to flood in California (2016 – 17) has raised concerns about the increasing variability and rapid transitions between hydrological extremes and their associated compounding economic and environmental impacts. The intensification of the global hydrological cycle associated with climate change can further alter the drivers of such extremes and their interactions. Therefore, it is important to understand the characteristics of consecutive flood and drought events, including their spatiotemporal frequency and …

The Novel Application Of Electrical Resistivity Tomography For Spatiotemporal Monitoring Of Urban Stormwater Bioretention Systems, Darren Alvarenga

Electronic Thesis and Dissertation Repository

Bioretention systems are an increasingly popular low-impact development (LID) stormwater management approach that are used to reduce the water quantity and quality impacts of urban stormwater. The study investigated the feasibility and benefits of using non-invasive time-lapse electrical resistivity tomography (ERT) to understand the infiltration and soil moisture dynamics within bioretention systems. This was achieved through monitoring two field-scale operational bioretention systems in London, Ontario, Canada. High-resolution two-dimensional time-lapse ERT surveys were first completed during synthetic and natural rain events to assess the viability of time-lapse ERT to monitor soil moisture changes during events. Following this, three-dimensional ERT surveys were …

Nutrient Removal From Recirculating Aquaculture System Water, Eliza M. Costigan

Electronic Theses and Dissertations

Recirculating aquaculture systems (RAS), where only approximately 10% of the total system water is exchanged per day, have grown in popularity in recent years due to their potential to provide a high-quality protein source in a contained environment. With increased production comes the need for RAS water treatment to mitigate recirculation and discharge of nutrients produced by fish; mainly phosphorus and nitrogen. When discharged, nutrients can contribute to eutrophication in surrounding water bodies, harming the fish and other aquatic life. Therefore, RAS effluent should be treated before discharge. One method of phosphorus removal is adsorption, a surface phenomenon that is …