Digital Commons Network^™

Treatment Of Combined Sewer Overflows Using Ferrate (Vi), Rohan Gandhi

Electronic Thesis and Dissertation Repository

Prevention of pollution from combined sewer overflows (CSOs) is currently a major concern due to their impact on aquatic and human environment. With the stringent regulations related to the CSOs treatment, it is necessary to develop an efficient, fast and low cost treatment technique that meets the applicable criteria. In this work, the comprehensive study was done to determine the efficiency of ferrate (VI) for the treatment of CSOs. At a Fe (VI) dose of 0.24 mg/l, TCOD, SCOD, TBOD₅, SBOD₅, TSS, VSS, TP, TN and soluble TN removal efficiencies of 71%, 75%, 69%, 68%, 72%, …

Seasonal Change In Bacteria Levels And Eluent Comparison For The Enumeration Of E. Coli And Enterococci From Recreational Beach Sand, Kyle Hines

Theses and Dissertations

Research into the causes of bacterial contamination of recreational beaches has been increasing. Many researchers are now looking to enumerate bacteria from beach sands in order to find the connections between the water and sand quality. As the number of these studies increase, there is a need to determine a standard procedure for enumerating bacteria from sand. The eluent that a researcher chooses could impact the results that they obtain due to ionic strength. The first part of this paper compares the E. coli and Enterococci counts of identical sand samples using phosphate buffered saline and distilled water as eluents. …

Recovering Bioresources From Integrated Photo-Bioelectrochemical System, Li Xiao

Theses and Dissertations

Compared to traditional wastewater treatment technologies, the electricity generation is one of the most important advantages of bioelectrochemical systems (BES). However, due to its high cost and low energy production, BES technologies are still far away from feasible application. The main purpose of this work was to investigate ways to improve the electricity generation and reduce the cost of BES technologies. We focused on microbial fuel cells (MFCs) and microbial electrolysis cells (MECs) as two representative BES technologies. In order to improve the energy performance of MFCs, an accurate evaluation of the energy is necessary. However, the common evaluation methods …

Development Of Novel Bioelectrochemical Systems For In Situ Nitrate Removal From Groundwater, Yiran Tong

Theses and Dissertations

This study aims to develop new approaches for in situ nitrate removal from groundwater by using bioelectrochemical systems (BES). BESs employ bioelectricity generated from organic compounds to drive nitrate moving from groundwater into the electrode chamber and reduce nitrate to nitrogen gas by heterotrophic denitrification. In first phase experiments, nitrate ions were driven into the anode chamber of a de-coupled reactor, whose electrode chambers were separated, where heterotrophic denitrification took place with organic reduction. It was proved that by applying additional electrical potential at 0.8V, the reactor could achieve highest removal rate of 208.2±13.3 g NO3--N/m3/d, when initial nitrate concentration …

Assessing Potential Environmental Impacts According To Probable Patterns Of Switchgrass Adoption In The Southeastern Us, Benjamin Sharp

All Dissertations

To assess the overall net impact of an emerging technology, life cycle assessment (LCA) must be accompanied by projections of adoption. Diffusion of innovation research provides tools that incorporate economic and social variables to explain and forecast integration of technologies. A switchgrass-to-ethanol case study for the southeastern U.S. is used to demonstrate methods for gauging aggregate environmental effects of an emerging energy technology. Before applying diffusion concepts, breakeven capacities are calculated for land in row crops, hay, pasture and marginal land. Breakeven curves are generated to provide upper bounds to switchgrass adoption over a range of farm-gate prices. The amount …

Chemical, Physical, And Moisture Release Characteristics Of Compost Based Potting Media, Tianzhen Wang

All Theses

A commercially available composted cow manure was used as a potting media amendment. A common base mix for woody ornamentals of 8 parts pine bark and 1 part sand was compared with 3 other mixes that contained 20%, 30%, and 40% compost (v/v). The remaining fraction of these three mixes was the base mix (bark and sand). Samples of the pine bark and compost were analyzed to determine the following plant nutrients and mineral concentrations: nitrogen (organic and soluble), carbon, P2O5, K2O, Ca, S, Mg, Mn, Cu, Zn, Na, Fe, and Al.

Sodhana Environmental - Final Design Report, Eric Taylor, Corissa Bellis, Cody Perez, Cameron Zeller

Mechanical Engineering

A fully designed cost-effective, sustainable, toilet for the developing world.

Using Bioelectrochemical Systems For Sustainable Desalination, Bo Zhang

Theses and Dissertations

Desalination of seawater or brackish water holds the potential to solve the freshwater shortage that is threatening nearly half of the world population. Current desalination technologies are energy intensive, which makes the desalinated water prohibitively expensive. In this study, investigations have been made to use renewable energy sources from organic waste to power the desalination process. Since desalination is driven by renewable energy, such desalination systems are more sustainable than currently wide employed commercial technologies. Efforts have been made to study how to operate BES driven desalination process such that the energy consumption will be minimized. Forward osmosis technology is …

Investigation Of Application Niche For Sustainable Wastewater Treatment Using Microbial Fuel Cells, Patrick Thomas Kelly

Theses and Dissertations

Microbial fuel cells represent a sustainable wastewater treatment technology due to its simultaneous treatment of contaminants and electricity production. Selection of suitable substrates is important to identifying proper application of microbial fuel cell (MFC) technology. In this work, four identical MFCs were used to treat the wastes sampled from different stages of a cheese wastewater treatment process, and both treatment performance and energy balance were examined. The two MFCs treating liquid wastes achieved more than 80% removal of total chemical oxygen demand (TCOD), while the other two MFCs fed with sludge or cheese whey removed about 60% of TCOD. The …

Reassessment Of Biowish Activation Procedure For Denitrification, William Wah Yee

Master's Theses

BiOWiSH^TM – Aqua is a blend of preserved multi-bacteria culture with the capability of denitrification. If an anaerobic nitrate rich activation procedure is used instead of the standard aerobic activation procedure, the denitrification rate is increased by 28 percent under the conditions of 30°C, 1C:1N, 200mg/L of carbon, and 200mg/L nitrogen.

Lipid Production By Microalgae Treating Municipal Wastewater, James Edward Kelley

Master's Theses

Microalgae hold much promise as a feedstock in liquid biofuel production. Lipid content of microalgae cells range from 30-80% dry weight of biomass. It is projected that microalgae can produce between 1,000-6,500 gallons/acre/year of oil. Currently, production of industrial algae operates in open raceway ponds that use minimal capital and energy inputs to culture algae. Raceway ponds can also be used to grow microalgae from municipal waste streams. Although high biomass productivity can be achieved in these systems, there remains a large production gap between large volumes of biomass cultivation and high lipid content from microalgae cells. Low lipid content …

Effects Of Waste Placement Practices On The Engineering Response Of Municipal Solid Waste, Jason Taylor Cox

Master's Theses

An extensive laboratory and field investigation was conducted at Santa Maria Regional Landfill (SMRL) in Santa Maria, CA to determine the effects of waste placement practices on the engineering response of municipal solid waste (MSW). Laboratory and field testing was used to determine the engineering properties and monitor field response of MSW.

The specific gravity (G_s) of manufactured MSW (MMSW), fresh MSW (FMSW), and old MSW (OMSW) was determined experimentally using a modified version of standard soil testing procedures. Effects of particle size, compactive effort, and degradation on the specific gravity of waste were evaluated. Specific gravity …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …

Dissolved Carbon Dioxide For Scale Removal In Reverse Osmosis, Erin Partlan

All Theses

Membrane fouling is a major operational issue in reverse osmosis (RO) desalination plants. In particular, plants treating brackish groundwater can encounter troublesome inorganic scales, including carbonates, sulfates, and silicates. A novel cleaning method is proposed to remove inorganic scales from fouled RO membranes usinag dissolved CO ₂ . As CO₂ molecules encounter membrane foulants, the surfaces serve as nucleation sites for small bubbles to form and shear off foulants. Dissolved CO₂ solutions were prepared by bubbling CO₂ gas into water held in a pressure vessel. Gas dissolution was confirmed by enhanced exit velocities for water containing CO …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Hydrogeological And Thermal Sustainability Of Geothermal Borehole Heat Exchangers, S. Emad Dehkordi

Electronic Thesis and Dissertation Repository

Assessment of the current approach taken by guidelines and design methods of vertical closed loop heat exchangers shows that often groundwater flow is either disregarded or is not methodically incorporated. The state of scientific research in this arena reveals that overlooking the groundwater flow in the design procedure may not always be a correct assumption. The significance of advective heat transport compared to conduction is defined by the groundwater flux or Darcy velocity which heavily depends on the hydraulic conductivity of the ground, followed by the hydraulic gradient which has a relatively limited range. A sensitivity analysis on ground and …

Optimisation Of The Transesterification Stage Of Biodiesel Production Using Statistical Methods, Arnold Paintsil

Electronic Thesis and Dissertation Repository

The present research examines solely the transesterification stage of the biodiesel production process. Six process variables that affect the yield of biodiesel at this stage are examined using the 12 run Plackett-Burman Design. To study the effect of FFA[1] and to replicate real life situations where oil (feedstock) contain varying amounts of FFA, linoleic acid is used as FFA and intentionally added to high oleic acid canola oil containing less than 0.07% FFA. The process is catalyzed with potassium carbonate and evaluated at varying temperatures, stirring rates, reaction times and methanol oil ratios. The yields at the end of …

Anaerobic Co-Digestion Planning And Research For Green Bay, Wi, Jonathan Kusowski

Master's Theses (2009 -)

The aspiration to find an alternative sustainable fuel source is an ever growing concern. Anaerobic digestion might hold the answer to finding an alternative sustainable energy source. Anaerobic digestion does not only provide a renewable resource in the form of biogas, but also stabilizes wastes, preventing large amounts from being landfilled or incinerated. Anaerobic digestion of municipal wastewater sludges can often be improved by the addition of high strength industrial wastes, in a process called co-digestion. High strength industrial wastes provide an additional carbon source for the microbes to utilize and convert into usable biogas. Co-digestion also offers the opportunity …

Adaptive Targeting: Engaging Farmers To Assess Perceptions And Improve Watershed Modeling, Optimization, And Adoption Of Agricultural Conservation Practices, Margaret Mccahon Kalcic

Open Access Dissertations

Targeting agricultural conservation practices to farmland that has the greatest impact on surface water quality has received wide support from scientists and watershed managers. The targeting approach has, however, been politically contentious as many believe farmers will oppose the approach on grounds such as privacy invasion and unfair distribution of government incentives. Targeting conservation practices using complex optimization models has become common in the scientific community, and yet targeted results are underutilized in practice because of difficulties such as knowledge transfer and absence of a political framework for their use. For targeting to be successful, it must be politically supported …

Evidence Supporting Treatment Practice Based Delineation Of Stormwater Runoff Zones, Jacob J. Gorski

Dissertations and Theses

Particles mobilized by stormwater negatively affect receiving surface waters. Stormwater best management practices (BMPs) can reduce solids along with associated pollutants in runoff but engineers and environmental managers have been long vexed by the problem of choosing the optimal BMP for a given situation. A common BMP process for solids removal is sedimentation. This thesis addresses the question of whether the effectiveness (and thus choice) of a sedimentation device can be estimated (and thus optimized) from the particle size properties of runoff, which, in turn, could be associated with specific runoff zones or land uses. Presented here is a series …

Ion Exchange Nutrient Recovery From Municipal Wastewater, Allen Williams

Master's Theses (2009 -)

Nitrogen and phosphorus discharge is regulated due to eutrophication. Typically ammonium-nitrogen is removed through nitrification which requires energy and phosphorus (P) is removed by metal salt addition to precipitate P. A more sustainable approach may be to implement nutrient recovery to form fertilizers. Most nitrogen fertilizer is formed through the energy intensive Haber-Bosch process. Phosphate rock, a limited resource, is mined for P fertilizer. Discharge regulations and the fertilizer production costs provide an economic driver for recovery. The current project used anionic and cationic ion exchange (IX) to concentrate the nutrients with recovery by struvite precipitation. Previous work lacks direct …

Dimensionless Criteria For Selecting Tidally-Influenced Advective-Dispersive Desalination Brine Mixing Plume Characterization Models, Alireza Shahvari

Civil & Environmental Engineering Theses & Dissertations

The very nature of requirements for implementing a desalination process is highly spatial due to the need to secure both a source for the operation and sink for brine dilution. Thus, the applicable coastal location is bound to natural tidal mixing characteristics and subjected to a near- or a far-field availability for source and sink. Mixing characteristics of coastal waters are very different from one point to another due to the spatiotemporal tidal characteristic in loco in a manner that it can vary from being highly advective to completely dispersive dominant. Once a location is identified, estimation of corresponding water …

Carbon-Nzvi Nanocomposites For Dechlorination Of Halogenated Hydrocarbons, Jing Cheng

Electronic Thesis and Dissertation Repository

A family of hybrid nanocarbon/nanoiron composites has been developed with the aim to carry out simultaneous adsorption and dechlorination of chlorinated hydrocarbons from aqueous solutions. Several methodologies for the synthesis of these materials are evaluated in terms of their adsorption capacities and dechlorination activities. Detailed spectroscopic and microscopy studies indicate that the adsorption ability of the carbonaceous support is greatly improved after acid oxidization, attributed to the formation of oxygenated functional groups on their surfaces. When iron nanoparticles are incorporated on the composites, the materials show a much higher trichloroethylene (TCE) removal efficiency compared to bare metallic nanoiron particles or …

Ignition Method Development And First Field Demonstration Of In Situ Smouldering Remediation, Grant C. Scholes

Electronic Thesis and Dissertation Repository

Self-sustaining Treatment for Active Remediation (STAR), a smouldering combustion-based technology for remediating sites contaminated by industrial liquids, has been extensively studied in the laboratory. The technology had not been demonstrated at a real site. Moreover, the ignition method (based on heat conduction) for the process used in the laboratory was not appropriate for field deployment and an alternative was required. This work first presents the development of a new ignition method for smouldering combustion. This ignition technique (based on heat convection) was proven effective via laboratory tests, and then applied and improved through two field tests. These field tests, conducted …

Characterization Of Secondary Organic Aerosol Precursors Using Two-Dimensional Gas Chromatography With Time Of Flight Mass Spectrometry (Gc×Gc/Tofms), Melissa Jordan Roskamp

Dissertations and Theses

The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality through the formation of secondary organic aerosols (SOA). More than 1000TgC/yr of non-methane VOCs are emitted from biogenic sources (significantly greater than from anthropogenic sources). Despite this magnitude and potential importance for air quality, the body of knowledge around the identities, quantities and oxidation processes of these compounds is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). Two-dimensional gas chromatography paired with time-of-flight mass spectrometry (GC×GC/TOFMS) is a powerful analytical technique which is explored here for its role in better …

Rooftop Pv Impacts On Fossil Fuel Electricity Generation And Co2 Emissions In The Pacific Northwest, Daniel Albert Weiland

Dissertations and Theses

This thesis estimates the impacts of rooftop photovoltaic (PV) capacity on electricity generation and CO2 emissions in America's Pacific Northwest. The region's demand for electricity is increasing at the same time that it is attempting to reduce its greenhouse gas emissions. The electricity generated by rooftop PV capacity is expected to displace electricity from fossil fueled electricity generators and reduce CO2 emissions, but when and how much? And how can this region maximize and focus the impacts of additional rooftop PV capacity on CO2 emissions? To answer these questions, an hourly urban rooftop PV generation profile for 2009 was created …

Study Of Vertical Dense Jet Dilution In A Marine Environment, Nadeem Ahmad

Electronic Thesis and Dissertation Repository

Brine is a byproduct of many industrial and mining processes, including desalination. Brine is commonly conveyed in long pipe lines and disposed in the bottom of the sea through multiport diffusers, forming dense jets, also known as fountains. An acceptable level of brine concentration is required to be achieved at the boundary of a regulatory mixing zone surrounding a point of discharge. Such mixing zones are allocated with the objective of limiting environmental deterioration within their boundaries. Mixing zones are, nevertheless, not allowed when discharging brine in sensitive areas and when brine is toxic.

The main contribution of this study …

Numerical Evaluation Of Community-Scale Aquifer Storage, Transfer And Recovery Technology, Jessica Barker

Electronic Thesis and Dissertation Repository

Communities in the coastal regions of south-western Bangladesh currently experience severe seasonal water scarcity and groundwater sources of unsuitable salinity. Aquifer storage, transfer and recovery (ASTR), using a seasonal surplus of potable water, is being tested as a potential low-cost (less than $8000 USD) water supply alternative for these communities. A variable-density numerical groundwater model was developed to investigate the engineering technical feasibility of small-scale ASTR systems for the coastal communities in Bangladesh and specifically to support future field site selection and system design. The numerical model was calibrated based on an existing ASTR site and applied to explore the …

Upgrading Pyrolysis Oil To Produce Liquid Transportation Fuels, Ehsan Reyhanitash

Electronic Thesis and Dissertation Repository

The effects of stabilizing fast pyrolysis oil via catalytic alcohol pretreatment on upgrading via hydrodeoxygenation or thermal treatment was studied by comparing the properties of upgraded-stabilized oils with those of upgraded-non-stabilized oils (benchmarks). The major expected effect was reduction in molar mass of upgraded oils, as stabilization was expected to reduce the reactivity of fast pyrolysis oil, thereby reducing polymerization. It was observed that molar mass reduction was induced by dilution effect of the alcohol rather than reactivity reduction due to stabilization. Also, the effects of different alcohols on stabilization and subsequent upgrading were examined at minimized dilution effect conditions. …