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Removing Methane Via Atmospheric Oxidation Enhancement: The Legal Framework, Romany M. Webb, Martin Lockman, Korey Silverman-Roati
Removing Methane Via Atmospheric Oxidation Enhancement: The Legal Framework, Romany M. Webb, Martin Lockman, Korey Silverman-Roati
Sabin Center for Climate Change Law
To achieve the Paris Agreement’s goal of limiting the increase in global average temperatures to “well below 2 degrees Celsius,” and ideally 1.5 degrees Celsius, above pre-industrial levels, global greenhouse gas (“GHG”) emissions must reach net zero in the second half of the century. The global community is not currently on track to achieve net zero emissions. In fact, with the exception of a slight dip during the Covid-19 pandemic, emissions have risen steadily in recent years. This, together with the increasingly visible impacts of climate change, has prompted growing interest in the possibility of removing GHGs directly from the …
Potential Interactions Between Diatoms And Bacteria Are Shaped By Trace Element Gradients In The Southern Ocean, Alexa R. Sterling, Laura Z. Holland, Randelle M. Bundy, Shannon M. Burns, Kristen N. Buck, P. Dreux Chappell, Bethany D. Jenkins
Potential Interactions Between Diatoms And Bacteria Are Shaped By Trace Element Gradients In The Southern Ocean, Alexa R. Sterling, Laura Z. Holland, Randelle M. Bundy, Shannon M. Burns, Kristen N. Buck, P. Dreux Chappell, Bethany D. Jenkins
OES Faculty Publications
The growth of diatoms in the Southern Ocean, especially the region surrounding the West Antarctic Peninsula, is frequently constrained by low dissolved iron and other trace metal concentrations. This challenge may be overcome by mutualisms between diatoms and co-occurring associated bacteria, in which diatoms produce organic carbon as a substrate for bacterial growth, and bacteria produce siderophores, metal-binding ligands that can supply diatoms with metals upon uptake as well as other useful secondary compounds for diatom growth like vitamins. To examine the relationships between diatoms and bacteria in the plankton (diatom) size class (> 3 mu m), we sampled both …
The Variability Of Seawater Carbonate Chemistry In Two Florida Urban Mangrove Ecosystems, Alexandrina R. Rangel
The Variability Of Seawater Carbonate Chemistry In Two Florida Urban Mangrove Ecosystems, Alexandrina R. Rangel
All HCAS Student Capstones, Theses, and Dissertations
Anthropogenic carbon dioxide (CO2) emissions into the atmosphere are yielding serious impacts across the world’s ocean, including ocean acidification, sea level rise, and increasing seawater temperature. However, these changes are not occurring uniformly across all marine ecosystems. Coastal ecosystems, such as mangroves, already experience extreme and variable environmental conditions due to natural biogeochemical and physical processes. The goal of this study was to document small-scale variability in two urban mangrove ecosystems to gain insight into how ocean acidification will manifest within these systems. Using a stand-up paddleboard, a suite of sensors, and traditional bottle sampling techniques, we measured …
Functionalized Ionic Liquids For Improved Co2 Hydrogenation Catalysts, Amol Nanduji Jaybhaye
Functionalized Ionic Liquids For Improved Co2 Hydrogenation Catalysts, Amol Nanduji Jaybhaye
Masters Theses & Specialist Projects
Climate change is one of the biggest problems we are facing today, and anthropogenic greenhouse gases contribute significantly to it. Among greenhouse gasses, carbon dioxide emission is increased drastically and affecting majorly for increasing global temperature, and anything we can do to mitigate carbon dioxide emission will be helpful. A carbon dioxide hydrogenation reaction is a promising technique that can convert carbon dioxide into value-added chemicals, but the reaction rate is slow, and for that, we can use catalysts that will accelerate the reaction rate. Platinum-based nanoparticles have sparked research related to energy and environmental catalysts. Catalytic properties are depending …
The Role Of Oxygen In Stimulating Methane Production In Wetlands, Jared L. Wilmoth, Jeffra K. Schaefer, Danielle R. Schlesinger, Spencer W. Roth, Patrick G. Hatcher, Julie K. Shoemaker, Xinning Zhang
The Role Of Oxygen In Stimulating Methane Production In Wetlands, Jared L. Wilmoth, Jeffra K. Schaefer, Danielle R. Schlesinger, Spencer W. Roth, Patrick G. Hatcher, Julie K. Shoemaker, Xinning Zhang
Chemistry & Biochemistry Faculty Publications
Methane (CH4), a potent greenhouse gas, is the second most important greenhouse gas contributor to climate change after carbon dioxide (CO2). The biological emissions of CH4 from wetlands are a major uncertainty in CH4 budgets. Microbial methanogenesis by Archaea is an anaerobic process accounting for most biological CH4 production in nature, yet recent observations indicate that large emissions can originate from oxygenated or frequently oxygenated wetland soil layers. To determine how oxygen (O2) can stimulate CH4 emissions, we used incubations of Sphagnum peat to demonstrate that the temporary exposure of …
Climate Change, Spring/Summer 2007, Issue 16
Heat Islands, Fall/Winter 2014, Issue 29
The Spectroscopic And Computational Exploration Of Sulfur Hydrogen Bonding, Andrew Yoonkeun Lee
The Spectroscopic And Computational Exploration Of Sulfur Hydrogen Bonding, Andrew Yoonkeun Lee
Honors Projects
Hydrogen bonds are a subset of non-covalent interactions that occur between X-H — Y, in which X and Y are the very electronegative atoms. In our research, we examine the more unconventional hydrogen bond-like interactions of thiol (SH) containing molecules using vapor-phase infrared (IR) spectroscopy and ab initio computational chemistry. When the SH hydrogen bond donor complexes to a hydrogen bond acceptor, a red shift of the SH stretching mode emerges. An anharmonic oscillator local mode model is applied to the ethanethiol-trimethylamine dimer, and we determine that any IR evidence of dimerization in our experiment is likely obscured by the …
Biogeochemical Response To Vegetation And Hydrologic Change In An Alaskan Boreal Fen Ecosystem, Danielle L. Rupp
Biogeochemical Response To Vegetation And Hydrologic Change In An Alaskan Boreal Fen Ecosystem, Danielle L. Rupp
Dissertations, Master's Theses and Master's Reports
Boreal peatlands store approximately one third of the earth’s terrestrial carbon, locked away in currently waterlogged and frozen conditions. Peatlands of boreal and arctic ecosystems are affected increasingly by shifting hydrology caused by climate change. The consequences of these relatively rapid ecosystem changes on carbon cycling between the landscape and the atmosphere could provide an amplifying feedback to climate warming. Alternatively, the advancement of terrestrial vegetation into once waterlogged soils could uptake carbon as a sink. Previous work suggests that fens will become an increasingly dominant landscape feature in the boreal. However, studies investigating fens, their response to hydrologic and …
Developing A Risk Assessment Protocol To Quantify Distribution And Uptake Of Persistent Organic Pollutants In Glacial Outflows, Kimberley Rain Miner
Developing A Risk Assessment Protocol To Quantify Distribution And Uptake Of Persistent Organic Pollutants In Glacial Outflows, Kimberley Rain Miner
Electronic Theses and Dissertations
Pollutants released by industrialized nations between 1960 and 2004 have been transported northward through atmospheric processes and deposited into glaciated alpine ecosystems. Many of these chemicals retain their original structure and are absorbed into the biota thousands of miles away from where they were originally utilized. With a warming climate increasing the melt of alpine glaciers, these glaciers may be introducing growing amounts of toxins into the watershed. While studies have demonstrated the existence of resident pollutants within glaciated ecosystems, no one has developed a risk assessment to identify sources and quantity of risk posed by these compounds when released …
Methane Emissions As Energy Reservoir: Context, Scope, Causes And Mitigation Strategies, Xiaoli Chai, David J. Tonjes, Devinder Mahajan
Methane Emissions As Energy Reservoir: Context, Scope, Causes And Mitigation Strategies, Xiaoli Chai, David J. Tonjes, Devinder Mahajan
Technology & Society Faculty Publications
Methane (CH4) is now considered a bridge fuel between present fossil (carbon) economy and desired renewables and this energy molecule is projected to play an important role in the global energy mix well beyond 2035. The atmospheric warming potential of CH4 is 28-36 times, when averaged over a 100-year period, that of carbon dioxide (CO2) and this necessitates a close scrutiny of global CH4 emissions inventory. As the second most abundant greenhouse gas (GHG), the annual global CH4 emissions were 645 million metric tons (MMT), accounting for 14.3% of the global anthropogenic GHG emissions. Of this, five key anthropogenic sources: …
Carbon Sequestration In Tidal Salt Marshes And Mangrove Ecosystems, Carlos Eduardo Quintana-Alcantara
Carbon Sequestration In Tidal Salt Marshes And Mangrove Ecosystems, Carlos Eduardo Quintana-Alcantara
Master's Projects and Capstones
Wetlands are dynamic systems that provide support to vital environmental functions and services. Wetlands take part in the global carbon cycle by holding organic carbon in biomass, soils and sediments. In recent years, the wetland carbon sequestration capacity has been researched worldwide due to the increase of the concentrations of greenhouse gasses implicated in global warming and climate change. Although coastal wetlands release the greenhouse gasses carbon dioxide, methane and nitrous oxide, these ecosystems maintain high performance in offsetting significant amounts of atmospheric carbon. This paper investigated the carbon sequestration capacity of coastal wetland ecosystems summarizing the environmental conditions and …
Wetlands And Greenhouse Gas Fluxes: Causes And Effects Of Climate Change – A Meta-Analysis, Robert E. Ventura
Wetlands And Greenhouse Gas Fluxes: Causes And Effects Of Climate Change – A Meta-Analysis, Robert E. Ventura
Pomona Senior Theses
Climate change is one of the largest problems facing this generation. Anthropogenically caused increases of greenhouse gas emissions is a significant culprit to this problem. Although the obvious problems such as cars, industry, and urbanism garnish a significant amount of the criticism, natural sources such as wetlands are also beginning to contribute to this issue. This is becoming increasingly significant as wetlands shift from being sinks of greenhouse gases to becoming sources as various anthropogenic impacts, including global warming itself, begin to affect the health of the wetlands. The aim of this project is to look at four common types …
Process-Evaluation Of Tropospheric Humidity Simulated By General Circulation Models Using Water Vapor Isotopic Observations: 2. Using Isotopic Diagnostics To Understand The Mid And Upper Tropospheric Moist Bias In The Tropics And Subtropics, Camille Risi, David Noone, John Worden, Christian Frankenberg, Gabriele Stiller, Michael Kiefer, Bernd Funke, Kaley Walker, Peter Bernath, Matthias Schneider, Sandrine Bony, Jeonghoon Lee, Derek Brown, Christophe Sturm
Process-Evaluation Of Tropospheric Humidity Simulated By General Circulation Models Using Water Vapor Isotopic Observations: 2. Using Isotopic Diagnostics To Understand The Mid And Upper Tropospheric Moist Bias In The Tropics And Subtropics, Camille Risi, David Noone, John Worden, Christian Frankenberg, Gabriele Stiller, Michael Kiefer, Bernd Funke, Kaley Walker, Peter Bernath, Matthias Schneider, Sandrine Bony, Jeonghoon Lee, Derek Brown, Christophe Sturm
Chemistry & Biochemistry Faculty Publications
Evaluating the representation of processes controlling tropical and subtropical tropospheric relative humidity (RH) in atmospheric general circulation models (GCMs) is crucial to assess the credibility of predicted climate changes. GCMs have long exhibited a moist bias in the tropical and subtropical mid and upper troposphere, which could be due to the mis-representation of cloud processes or of the large-scale circulation, or to excessive diffusion during water vapor transport. The goal of this study is to use observations of the water vapor isotopic ratio to understand the cause of this bias. We compare the three-dimensional distribution of the water vapor isotopic …