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Engineering

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2018

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Cfd Modelling To Evaluate The Effect Of Digester Temperature On Biogas Production, Shuichi Torii Dec 2018

Cfd Modelling To Evaluate The Effect Of Digester Temperature On Biogas Production, Shuichi Torii

Manipal Journal of Science and Technology

Biogas production from chicken manure and food solid waste has grabbed the attention of engineers and managers globally because of the substantial advantages in achieving environmental protection, generation of energy and Green House Gas emission reductions. However, there are a number of problems involved in scaling up experimental Anaerobic Digestion (AD) plants to field level plants. One of the major problems associated with AD is mixing, which is a key component in segregating synthesized gas and biomass from digester liquid, enhancing homogeneity and in ensuring adequate contact between bacteria and substrate in the Anaerobic Digestion. Besides this, temperature plays a …

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Rancang Bangun Alarm Deteksi Asap Rokok Dan Kebisingan Pada Ruang Kelas Secara Otomatis Berbasis Mikrokontroler, Imas Dian Ratnasari Dec 2018

Rancang Bangun Alarm Deteksi Asap Rokok Dan Kebisingan Pada Ruang Kelas Secara Otomatis Berbasis Mikrokontroler, Imas Dian Ratnasari

Elinvo (Electronics, Informatics, and Vocational Education)

Abstrak- Asap rokok dan kebisingan merupakan masalah yang sering terjadi di sekolah, sedangkan dalam penanganan masalah asap rokok dan kebisingan di sekolah belum maksimal karena belum terdapat alat yang mampu mendeteksi asap rokok sekaligus kebisingan yang diterapkan di sekolah. Pemantauan kondisi ruang kelas agar tetap kondusif perlu diadakan, maka dari itu dilakukan pengembangan alarm deteksi asap rokok dan kebisingan pada ruang kelas secara otomatis. Penelitian ini bertujuan untuk membantu guru dalam memonitoring kondisi di ruang kelas ketika ruang kelas sedang tidak ada guru. Metode penelitian yang digunakan adalah Research and Development (R&D), yang terdiri dari beberapa tahapan mulai yaitu dari …

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Otomasi Sistem Hidroponik Dft (Deep Flow Technique) Berbasis Arduino Android Dengan Memanfaatkan Panel Surya Sebagai Energi Alternatif, Eko Agus Suprayitno Mt, Rohman Dijaya M. Kom, M. Atho㢂¬„¢Illah St Dec 2018

Otomasi Sistem Hidroponik Dft (Deep Flow Technique) Berbasis Arduino Android Dengan Memanfaatkan Panel Surya Sebagai Energi Alternatif, Eko Agus Suprayitno Mt, Rohman Dijaya M. Kom, M. Atho㢂¬„¢Illah St

Elinvo (Electronics, Informatics, and Vocational Education)

The application of hydroponic farming methods has been widely applied by the community, the system used is still manual so that it lacks quality, both in terms of humidity and growth. For that we need a system that is able to regulate the time of watering and the provision of nutritional solutions automatically without disturbing the activity. In the design of an automatic DFT hydroponic system using an Android Arduino based solar panel. Where the solar panel system functions as a renewable energy substitute for PLN which will fill the accumulator. The accumulator filling process is equipped with a solar …

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Pengatur Suhu Dan Kelembaban Kumbung Jamur Otomatis, Aji Nugroho Dec 2018

Pengatur Suhu Dan Kelembaban Kumbung Jamur Otomatis, Aji Nugroho

Elinvo (Electronics, Informatics, and Vocational Education)

Temperature and humidity have an important role in the cultivation of oyster mushrooms to obtain optimal growth of oyster mushrooms. The optimum temperature required ranges from 24 ° C - 27 ° C and 80% - 90% humidity. The watering of mushroom kumbung should be done regularly, in order to maintain the temperature and humidity of the surrounding air, then conducted research that aims to create a tool that can regulate the temperature and humidity kumbung mushrooms automatically to facilitate farmers keep the temperature and humidity stability continuously. This automatic adjustment system uses DHT-11 sensors as air and humidity and …

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Aplikasi Alat Ukur Debu Berbasis Sms Dan Analisis Model Dispersi Gauss, S. Syahrorini, A. Ahfas Dec 2018

Aplikasi Alat Ukur Debu Berbasis Sms Dan Analisis Model Dispersi Gauss, S. Syahrorini, A. Ahfas

Elinvo (Electronics, Informatics, and Vocational Education)

Udara merupakan komponen penting dalam kehidupan ini, untuk itu perlu dijaga kualitas udara dari polusi udara. Penurunan kualitas udara akibat polusi debu bisa menyebabkan penyakit saluran pernafasan. Untuk mempermudah penyampaian hasil pengukuran debu udara ambien sesuai perkembangan teknologi bisa menggunakan sms. Perancangan alat ukur debu berbasis sms menggunakan sensor debu gp2y1010au0f mendeteksi konsentrasi debu, rangkaian amplifier, mikrokontroler Arduino Uno, modul SMS Gateway sim 900 dan LCD (Liquid Crystal Display). Aplikasi pengukuran di PG. Krembung Sidoarjo Jatim pada Desa Lemujut berjarak 1800 m dan desa Mojoruntut berjarak 1500 m. Hasil pengukuran menunjukkan konsentrasi dibawa baku mutu udara ambien, jadi …

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Pengembangan Media Pembelajaran Kendali Fuzzy Logic Berbasis Arduino Nano Pada Mata Kuliah Praktik Sistem Kendali Cerdas, Hernawan Prabowo, Fatchul Arifin Dec 2018

Pengembangan Media Pembelajaran Kendali Fuzzy Logic Berbasis Arduino Nano Pada Mata Kuliah Praktik Sistem Kendali Cerdas, Hernawan Prabowo, Fatchul Arifin

Elinvo (Electronics, Informatics, and Vocational Education)

Dewasa ini berbagai aplikasi dalam bidang industri yang canggih banyak menggunakan kecerdasan buatan. Mata kuliah praktik Sistem Kendali Cerdas di Jurusan Pendidikan Teknik Elektronika & Informatika FT UNY memerlukan sebuah media pembelajaran yang terintegrasi antara hardware dan software agar kualitas pembelajaran sesuai dengan tuntutan dunia Industri. Hasil penelitian ini untuk menghasilkan media pembelajaran kendali fuzzy logic yang teruji kinerja dan kelayakannya pada mata kuliah praktik Sistem Kendali Cerdas. Pendekatan penelitian menggunakan Research and Development dengan 9 tahapan prosedur pengembangan meliputi: (1) potensi dan masalah, (2) pengumpulan data, (3) desain produk, (4) validasi desain, (5) revisi desain, (6) ujicoba produk, (7) …

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Implementation Of Scalar Control Method For 3 Phase Induction Motor Speed Control, Abdul Muis Prasetia, Hadi Santoso Dec 2018

Implementation Of Scalar Control Method For 3 Phase Induction Motor Speed Control, Abdul Muis Prasetia, Hadi Santoso

Elinvo (Electronics, Informatics, and Vocational Education)

This paper presents design and implementation of scalar control for 3 phase induction motor. This method leads to be able to adjust the speed of the motor by control the frequency and amplitude of the stator voltage of 3 phase induction motor, the ratio of stator voltage to frequency should be kept constant, which is called as V/F or scalar control of 3 phase induction motor drive. The proposed control system is used to generate control signals to overcome the nonlinear dynamics of 3 phase induction motor. Simulation results show that the 3 phase induction motor is able to track …

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Analisis Forensik Digital Pada Frozen Solid State Drive Dengan Metode National Institute Of Justice (Nij), Imam Riadi, Rusydi Umar, Imam Mahfudl Nasrulloh Dec 2018

Analisis Forensik Digital Pada Frozen Solid State Drive Dengan Metode National Institute Of Justice (Nij), Imam Riadi, Rusydi Umar, Imam Mahfudl Nasrulloh

Elinvo (Electronics, Informatics, and Vocational Education)

Kejahatan komputer memiliki bukti digital dari tindak kejahatan dan perlu dilakukan analisa. Perkembangan teknologi komputer yang demikian pesat telah membawa perubahan pada bidang perangkat keras. Pada perangkat keras saat ini terdapat Solid State Drive (SSD) sebagai media penyimpanan utama komputer, karena teknologi SSD memiliki kecepatan akses data yang cepat. Penggunaan software pembeku drive pada komputer sering dilakukan oleh teknisi komputer, karena dapat menghemat biaya perawatan. Software tersebut digunakan untuk melindungi komputer dari perubahan yang tidak dikehendaki, sistem komputer yang tanam software tersebut menjadikan perubahan yang terjadi pada sistem komputer tidak disimpan pada media penyimpanan setelah komputer dimatikan. …

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Sistem Buka Tutup Pintu Otomatis Berbasis Suara, Sinta Ariyanti, Slamet Seno Adi, Sugeng Purbawanto Dec 2018

Sistem Buka Tutup Pintu Otomatis Berbasis Suara, Sinta Ariyanti, Slamet Seno Adi, Sugeng Purbawanto

Elinvo (Electronics, Informatics, and Vocational Education)

Biometric identification is one of the media on the operation of the system of home automation are much sought after.This is because conventional identification such as the use of your PIN, password, and a key card is already not enough reliable, in terms of security and how to operate.Biometrics is essentially an introduction to someone based on the unique personality of each person owned such as facial recognition, fingerprints, voice recognition, the introduction of the retina, and signature.Voice recognition is a process to identify a person by recognizing speech from that person.The purpose of this research is to know the …

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Modifikasi Alat Medis Stetoskop Untuk Monitoring Suara Jantung Menggunakan Tampilan Gui Matlab, Dessy Irmawati, Ridho Prasakti Dec 2018

Modifikasi Alat Medis Stetoskop Untuk Monitoring Suara Jantung Menggunakan Tampilan Gui Matlab, Dessy Irmawati, Ridho Prasakti

Elinvo (Electronics, Informatics, and Vocational Education)

Heart sounds are very important for the initial diagnosis of a disease. This article aims to modify the stethoscope's medical device by adding a Low Pass Filter (LPF) and a condenser sensor so that data can be recorded in a digital device. The stages of tool development begin with analysis, design, development and testing. At the analysis stage, it was stated that a conventional medical stethoscope can only be done by a medical expert directly, where data cannot be stored for detailed analysis purposes, the device is not equipped with LPF which can limit the frequency in a certain range, …

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Reosquido Desalinasi Metode Evaporasi Dengan Ultraviolet Berbasis Mikrokontroller, Muhammad Abdul Azis, Nuryake Fajaryati Dec 2018

Reosquido Desalinasi Metode Evaporasi Dengan Ultraviolet Berbasis Mikrokontroller, Muhammad Abdul Azis, Nuryake Fajaryati

Elinvo (Electronics, Informatics, and Vocational Education)

This research aims to create a Reosquido desalination tool for evaporation methods using a microcontroller. This tool can control the temperature to speed up the evaporation process in producing fresh water. The method applied to Reosquido desalination uses Evaporation. The first process before evaporation is the detection of temperature in sea water that will be heated using an element heater. The second process of temperature measurement is to turn off and turn on the Arduino Uno controlled heater, when the temperature is less than 80 ° then the heater is on. The third process is evaporation during temperatures between 80 …

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Sistem Pendeteksi Dini Kebakaran Gedung Berbasis Zigbee Mesh Network, Ponco Wali Pranoto, Rovadita Anggorowati Dec 2018

Sistem Pendeteksi Dini Kebakaran Gedung Berbasis Zigbee Mesh Network, Ponco Wali Pranoto, Rovadita Anggorowati

Elinvo (Electronics, Informatics, and Vocational Education)

Perkembangan teknologi khususnya dalam hal informasi dan komunikasi menjadi peran penting dalam dunia masa kini, sebagai contoh penerapan teknologi informasi dan komunikasi telah merambah dalam segala aspek kehidupan diantaranya ialah rumah tangga, otomotif, militer, kesehatan, industri, hingga lingkungan. Salah satu contoh perkembangan teknologi informasi dan komunikasi saat ini ialah wireless sensor network (WSN) yang mana pengembangan dan penelitiannya masih sangat terbuka lebar. Pada penelitian ini peneliti membangun sebuah sistem deteksi bahaya kebakaran dengan mengimplementasikan Zigbee Mesh Network berbasis wireless sensor network (WSN). Untuk sensor pendeteksi bahaya kebakaran yang digunakan adalah LM35, dan MQ-2 selain itu untuk komunikasi wireless nya menggunakan …

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Desain Dan Implementasi Real-Time Visible Light Communication System Berbasis Bpsk, Trio Adiono, Syifaul Fuada Dec 2018

Desain Dan Implementasi Real-Time Visible Light Communication System Berbasis Bpsk, Trio Adiono, Syifaul Fuada

Elinvo (Electronics, Informatics, and Vocational Education)

Salah satu teknik multiplexing yang saat ini populer digunakan untuk aplikasi akses komunikasi cepat berbasis cahaya tampak adalah Orthogonal Frequency Division Multiplexing (OFDM). Meskipun lebih kompleks dibandingkan modulasi berbasis Pulse Time Modulation (PTM), teknik OFDM disinyalir dapat lebih menghemat bandwidth komunikasi karena membagi bandwidth lebar menjadi spektrum yang sempit (sub-carrier) dan saling overlap. Sebagai akibat, transfer data akan lebih cepat dibandingkan PTM. Pada penelitian sebelumnya, penulis telah berhasil mendesain sistem low-cost VLC dengan modulasi digital 1-PWM (3,3 kbps) dan 2-PWM (6,2 kbps). Motivasi dari penelitian ini adalah menigkatkan laju data dengan menggunakan OFDM. Modulasi binary shift-keying modulation …

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Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao Dec 2018

Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao

Journal of Electrochemistry

The self/non-humidification membrane electrode assembly（SH-MEA）is an important pathway towards the self- humidification fuel cell and plays a crucial role for the large scale commercialization of low temperature proton exchange membrane fuel cell (LT-PEMFC), because it not only can reduce the volume and complexity of fuel cell system, resulting in the decrease of the cost, but also can improve the output power density of the fuel cell system. Currently, the researches on the self-humidifying MEA of LT-PEMFC mainly focus on three aspects: the preparation of self-humidification proton exchange membrane, the construction of self-humidification catalyst layer, and the construction of composite self-humidifying …

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A Review Of Proton Exchange Membrane Fuel Cell Catalyst Layer By Electrospinning, Yong Liu, Han Ding, De-Chun Si, Jie Peng, Jian-Bo Zhang Dec 2018

A Review Of Proton Exchange Membrane Fuel Cell Catalyst Layer By Electrospinning, Yong Liu, Han Ding, De-Chun Si, Jie Peng, Jian-Bo Zhang

Journal of Electrochemistry

The limitation of catalyst layer for proton exchange membrane fuel cell (PEMFC) in cost, durability and performance constitutes the bottleneck for the commercialization of fuel cell vehicles. Electrospun catalyst layer, with high catalyst utilization, increased triple phase boundary (TPB) and triple phase channel (TPC), has been developed by many researchers. This paper reviews the research progress in the electrospun catalyst layer for PEMFC, combined with the author’s work. Firstly, the development progress of catalyst layer is summarized, and the catalyst layer is classified and analyzed based on its fabrication method and structure character. Next, the fabrication process, physical property characterization, …

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Effects Of So2 In Air On Performance Of Direct Methanol Fuel Cell, Bin Qin, Fen-Ning Jing, Xue-Jing Sun, Gong-Quan Sun, Hai Sun Dec 2018

Effects Of So2 In Air On Performance Of Direct Methanol Fuel Cell, Bin Qin, Fen-Ning Jing, Xue-Jing Sun, Gong-Quan Sun, Hai Sun

Journal of Electrochemistry

Direct methanol fuel cells (DMFC) generally use oxygen as an oxidant. Contaminants such as sulfides and nitrides in the air can affect the performance of the DMFC. In this work, the effects of SO2 on the performance of DMFC were investigated and the mechanism of poisoning was analyzed, by means of constant current discharge curve, polarization performance curve, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). In the CV scan, the permeated methanol was oxidized at a low potential to eliminate its effect on the SO2 poisoning behavior test. The results showed that the SO2 poisoning resulted …

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Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang Dec 2018

Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang

Journal of Electrochemistry

The development of non-precious metal catalysts for oxygen reduction reaction (ORR) is essential for large-scale application of proton exchange membrane fuel cells. Herein, we present the in situ formed Fe-N doped hollow carbon nanospheres linked by carbon nanotubes composite, synthesized by using ZIF-8 as sacrificed template to form polydopamine (PDA) hollow nanospheres, followed by complexing with FeCl3, high temperature heat-treatment and NH3-etching. ZIF-8 was gradually decomposed simultaneously with PDA coating due to the loss of Zn2+ grabbed by PDA. NH3 etching resulted in the improved surface area, while the reducibility of NH3 resulted in …

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Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells, He-Mu Chen, Chen-Xi Qiu, Yuan-Yuan Cong, Hui-Yuan Liu, Zi-Hui Zhai, Yu-Jiang Song Dec 2018

Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells, He-Mu Chen, Chen-Xi Qiu, Yuan-Yuan Cong, Hui-Yuan Liu, Zi-Hui Zhai, Yu-Jiang Song

Journal of Electrochemistry

In order to improve the hydrophilicity and electrocatalytic activity, commercial carbon black (BP 2000) was subjected to acid treatment to obtain acid-treated carbon (ATC). The generation of rich oxygen-containing groups on the surface of the ATC was proved by X-ray photoelectron spectra (XPS), Fourier transform-infra red spectra (FTIR), thermogravimetric analysis (TG) and contact angle measurement. UV-vis spectra were firstly recorded to calculate activation energy (Ea) of ascorbic acid (AA) chemical oxidation in alkaline conditions by oxygen in air and the Ea value was determined to be 37.1 kJ·mol-1. Additionally, electrochemical impedance spectra (EIS) were used to evaluate unprecedented …

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Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao Dec 2018

Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao

Journal of Electrochemistry

Palladium (Pd) is a good catalyst for ethanol electro-oxidation in alkaline solutions. The activity of Pd is further improved in this study by modifying the gold (Au) nanoparticles with Pd adatoms using a simple spontaneous deposition process. The Pd overlayer on the Au core (Au@Pd) is un-uniform with some Au atoms exposed to the electrolyte. The activity of Au@Pd/C toward ethanol oxidation reaction (EOR) is much higher than that of Pd/C in an alkaline solution. The peak current density of Au@Pd/C is 4.6 times higher than that of Pd/C with a 100 mV lower onset potential. The enhanced activity may …

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Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma Dec 2018

Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma

Journal of Electrochemistry

As an energy conversion device, fuel cells can efficiently convert chemical energy into electrical energy. With the developing of technology, it is used as a reactor to conduct the synthesis of high value-added chemicals while generating electrical energy. Having benefits such as mild reaction conditions, controllability of the reaction process, high selectivity of the product, as well as high efficiency of energy utilization, it is widely used in many fields such as preparation of high value-added industrial products, gas separation, water treatment, etc. This paper introduces the current trends and statuses of fuel cell reactors in the cogeneration of chemicals …

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Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing Dec 2018

Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

Hydrogen energy technology with hydrogen as an energy carrier is gaining more and more attention due to its cleanliness and high energy density. Hydrogen fuel cell vehicles have been listed as one of the ultimate energy technologies in the 21st century. Among them, sustainable hydrogen production technology is a necessary prerequisite for the future development of hydrogen energy economy. Electrolyzed water technology driven by renewable resources represents an important way to support the sustainable development of hydrogen energy economy. The development and utilization of high activity, low cost hydrogen evolution catalysts is a key factor in improving the efficiency and …

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Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei Dec 2018

Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei

Journal of Electrochemistry

One major challenge for a large-scale commercialization of the proton-exchange membrane fuel cells (PEMFCs) technologies that enable a shift to ‘zero-emission’ personal transportation, is the expensive and unstable Pt catalysts, which are mainly used to catalyze the sluggish kinetics of the oxygen reduction reaction (ORR) occurred on the air electrode of PEMFCs. Many research works have targets to improve the stability of Pt-based catalysts and to construct Pt/transitional metal alloys with low Pt loading amount. Herein, we provide a minireview for the Pt-based ORR catalysts based on our recent work, which covers a brief background introduction, the stability improvement of …

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Constructions Of Noble Metal Nanocrystals With Specific Crystal Facets And High Surface Area, Qiao-Li Chen, Hui-Qi Li, Ya-Qi Jiang, Zhao-Xiong Xie Dec 2018

Constructions Of Noble Metal Nanocrystals With Specific Crystal Facets And High Surface Area, Qiao-Li Chen, Hui-Qi Li, Ya-Qi Jiang, Zhao-Xiong Xie

Journal of Electrochemistry

Noble metal nanocrystals (NCs) have widespread applications in catalysis. Their catalytic performances are strongly related to the surface structures while the atomic utilization efficiency of noble metal is considerably correlated with the surface area. Thus, advantages of both specific surface structure and large surface area are highly required to show off simultaneously so as to optimize the catalytic performance and decrease the usage of noble metal. However, it seems that the two advantages are incompatible with each other in one NC since it is difficult for small NCs to keep their specific facets, while NCs with specific surface structure usually …

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Stabilization Strategies Of Pt Catalysts Forproton Exchange Membrane Fuel Cells, Da-Ping He, Shi-Chun Mu Dec 2018

Stabilization Strategies Of Pt Catalysts Forproton Exchange Membrane Fuel Cells, Da-Ping He, Shi-Chun Mu

Journal of Electrochemistry

The low service lifetime of proton exchange membrane fuel cells (PEMFCs) is the main bottleneck for their commercial applications. One of the main factors is that the expensive metal Pt catalyst is easy to degradation under the harsh working environment of PEMFC (such as variable voltage, strong acidity, gas-liquid two-phase flow), which leads to the inevitable decay of the catalytic performance, thus, seriously restricting the lifetime of PEMFC. Therefore, the electrochemical stability of Pt-based electrocatalysts has become an important and hot topic to improve the PEMFC lifetime. In this paper, we review the recent development in enhancing the stability of …

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Fuel Cell Performance Curve After Mea Optimization Structural Optimization Of Low Pt Membrane Electrode Assembly, Yan Rao, Shang Li, Fen Zhou, Tian Tian, Qing Zhong, Zhao-Hui Wan, Jin-Ting Tan, Mu Pan Dec 2018

Fuel Cell Performance Curve After Mea Optimization Structural Optimization Of Low Pt Membrane Electrode Assembly, Yan Rao, Shang Li, Fen Zhou, Tian Tian, Qing Zhong, Zhao-Hui Wan, Jin-Ting Tan, Mu Pan

Journal of Electrochemistry

Membrane electrode assemblies (MEAs) are the key component of proton exchange membrane fuel cell. For a long time, much attention has been paid to develop MEA technology. At present, the research, development and industrialization of fuel cell has entered a new era. More strict requirements for MEA, especially for the reduction of Pt loading with a challenging target of 0.125 mg·W-1 have to be met. In this paper, the performance losses under low Pt loading are analyzed in terms of activation polarization, ohm polarization and mass-transfer polarization. It is proposed that research should be focused on the activity of …

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The Pilot Application Of Electrochemical Impedance Spectroscopy On Dynamic Proton Exchange Membrane Fuel Cell, Jian-Wei Guo, Jian-Long Wang Dec 2018

The Pilot Application Of Electrochemical Impedance Spectroscopy On Dynamic Proton Exchange Membrane Fuel Cell, Jian-Wei Guo, Jian-Long Wang

Journal of Electrochemistry

By analyzing Electrochemical Impedance Spectroscopy (EIS) in applications of dynamic proton exchange membrane fuel cell (PEMFC), bottlenecks which restrict EIS tool development have been pointed out in this paper. Though the high-frequency resistance in EIS is largely accepted as cell inner-resistance, this can only be applied for cell with low current. The low-frequency resistance is difficult to be realized due to its relation with mass transfer. Furthermore, the improved Randles equivalent circuits are built up preliminarily, thus, penetrating into studies for mass transfer reaction, cell operation/degeneration, and high temperature fuel cell. Inspiringly, EIS is becoming an analyzing tool for stack …

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Morphological Control Of Ptcu2 Octahedron And Oxygen Reduction Electrocatalytic Performance Of Ptcu For Fuel Cell, Long-Sheng Cao, Lei Wan, Zhi-Gang Shao, Hong-Mei Yu, Ming Hou, Bao-Lian Yi Dec 2018

Morphological Control Of Ptcu2 Octahedron And Oxygen Reduction Electrocatalytic Performance Of Ptcu For Fuel Cell, Long-Sheng Cao, Lei Wan, Zhi-Gang Shao, Hong-Mei Yu, Ming Hou, Bao-Lian Yi

Journal of Electrochemistry

Platinum acetylacetonate (Pt(acac)2) and copper acetylacetonate (Cu(acac)2) were co-reduced to prepare PtCu2 octahedron alloy catalyst in N,N-dimethylformamiade by solvothermal method. The PtCu2 showed lattice compression, and high ratio of non-oxidized Pt with high electronic binding energy. All those structural features contributed to weak adsorption strength of oxygen species on Pt and lower d-band centre position. The influence of structure-directing agent on morphology of PtCu alloy was systematically studied. In the half cell test, as a result of the uniform morphology and regular octahedron of PtCu2 formed, the mass activity and area specific activity …

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Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction, Liu-Xuan Luo, Guang-Hua Wei, Shui-Yun Shen, Feng-Juan Zhu, Chang-Chun Ke, Xiao-Hui Yan, Jun-Liang Zhang Dec 2018

Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction, Liu-Xuan Luo, Guang-Hua Wei, Shui-Yun Shen, Feng-Juan Zhu, Chang-Chun Ke, Xiao-Hui Yan, Jun-Liang Zhang

Journal of Electrochemistry

Structures and compositions have significant effects on the catalytic properties of nanomaterials. Herein, a facile etching-based method was employed to synthesize Pt-Cu nanodendrites (NDs) with uniform and homogeneous alloy structures for enhancing oxygen reduction reaction (ORR). The formation of dendritic morphology was ascribed to the etching effect caused by the oxidative etchants of the Br-/O2 pair. The atomic ratio of Pt/Cu in Pt-Cu NDs could be easily tuned by altering the ratio of the Pt/Cu precursors, without deteriorating the dendritic morphology. The most active carbon-supported Pt1Cu1 NDs (Pt1Cu1 NDs/C) exhibited the …

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Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect, Dun-Feng Gao, Cheng-Cheng Yan, Guo-Xiong Wang, Xin-He Bao Dec 2018

Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect, Dun-Feng Gao, Cheng-Cheng Yan, Guo-Xiong Wang, Xin-He Bao

Journal of Electrochemistry

Nanostructured heterogeneous catalysts have been widely used in the electrochemical carbon dioxide (CO2) reduction reaction (CO2RR), which can simultaneously achieve the electrocatalytic conversion of CO2 to fuels and the storage of renewable energy sources. Carbon supported palladium nanoparticles (Pd/C) catalysts have been previously reported to show excellent CO2RR performance. However, the crucial role of the metal loading in supported electrocatalysts has been rarely reported. In this work, we study the Pd loading effect on the structure of Pd/C catalysts as well as their activity and selectivity of CO2RR to CO. The …

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Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang Dec 2018

Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang

Journal of Electrochemistry

In this work, the self-adaptive characteristics of self-humidifying air-cooled PEMFC stack was investigated. The performance and the unit-cell voltage distribution of the stack were measured and analyzed through the unit-cell I-V curve fitting. The operating conditions for this experimental study were set as follows: hydrogen pressure at the anode was 2 bar, the fan power used for the reactant oxygen feed and stack cooling was at 0.3 W, and the duration and time gap of water purged from hydrogen chamber were 1 s and 10 s, respectively. The experimental results showed that the self-humidifying air-cooled PEMFC stack used for this …

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