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Screening Of Tar Cracking Catalysts For Syngas Produced By Biomass Gasification, Bijeet Mukherjee
Screening Of Tar Cracking Catalysts For Syngas Produced By Biomass Gasification, Bijeet Mukherjee
LSU Master's Theses
The gasification of biomass produces tars and particulates. These tars and particulates create problems in the gasification systems. Tars condense on surfaces at lower temperatures, such as exit pipes and on particulate filters, leading to blockages and clogged filters. Tars also have varied impacts on other downstream processes. Due to these reasons, syngas containing significant concentrations of tars cannot be used in internal combustion engines. Thus the processes through which tars can be removed have been subject to considerable research. The objective of this research was to identify the best catalyst for for down-draft gasifiers, including the LSU AgCenter down-draft …
Dry Reforming Of Methane On Rhodium And Nickel Substituted Pyrochlore Catalysts, Sarthak Gaur
Dry Reforming Of Methane On Rhodium And Nickel Substituted Pyrochlore Catalysts, Sarthak Gaur
LSU Master's Theses
Dry reforming of methane (DRM) has been widely investigated, with most studies showing rapid deactivation due to carbon deposition. This suggests a need to develop catalysts that limit carbon formation while avoiding structural changes at the elevated temperatures typical of this reaction. Here, we report CO2 reforming of methane on four pyrochlore catalysts. First, Rh was partially substituted for Zr in lanthanum zirconate (La2Zr2O7) to give La2Zr2-xRhxO7.5 (LRZ, x=0.112, 2 wt% Rh) pyrochlore. A second pyrochlore catalyst was synthesized in which Ca was further substituted into the La-site to give La1.95Ca0.05Zr2-xRhxO7 (LCRZ, x=0.055, 1 wt% Rh). A third catalyst was …