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S/N-Doped Carbon Nanofibers Affording Fe7s8 Particles With Superior Sodium Storage, Xiu Li, Tao Liu, Yunxiao Wang, Shulei Chou, Xun Xu, Anmin Cao, Libao Chen Jan 2020

S/N-Doped Carbon Nanofibers Affording Fe7s8 Particles With Superior Sodium Storage, Xiu Li, Tao Liu, Yunxiao Wang, Shulei Chou, Xun Xu, Anmin Cao, Libao Chen

Australian Institute for Innovative Materials - Papers

2020 Iron sulfides draw much attention as electrode candidates for sodium-ion batteries (SIBs) due to the rich chemical stoichiometries and high capacity. However, they usually exhibit poor cycling performance due to the large volume change during sodiation/desodiation process. In this work, we embed Fe7S8 nanoparticles into sulfur, nitrogen-doped carbon (S/N-C) nanofibers through electrospinning/sulfurization processes. The heteroatom doped carbon matrixes could effectively protect the Fe7S8 from structural collapse, obtaining a stable cycling performance. Moreover, the conductive matrixes with 1D structure can facilitate the diffusion of electrons, leading to good rate capability. As results, the as-designed Fe7S8@S/N-C nanofibers present a discharge capacity …


A Method Of Uncertainty Analysis For Whole-Life Embodied Carbon Emissions (Co2-E) Of Building Materials Of A Net-Zero Energy Building In Australia, Mehdi Robati, Daniel J. Daly, Georgios Kokogiannakis Jan 2019

A Method Of Uncertainty Analysis For Whole-Life Embodied Carbon Emissions (Co2-E) Of Building Materials Of A Net-Zero Energy Building In Australia, Mehdi Robati, Daniel J. Daly, Georgios Kokogiannakis

Faculty of Engineering and Information Sciences - Papers: Part B

The construction of new buildings requires the use of a substantial amount of materials, which have an associated embodied energy for manufacturing, transport, construction and end-of-life disposal. A number of inventories have been developed to collate the typical embodied energy or carbon emissions associated with different building materials and activities, and these can be used to quantify the environmental impacts of different construction methods. However, uncertainty exists in the estimation of embodied CO2-e emissions and other environmental impact results, due to i) inconsistencies in typical embodied carbon emissions values in inventories; ii) errors in estimations of material quantities; iii) assumptions …


Electrostatically Assembled Construction Of Ternary Tio2-Cu@C Hybrid With Enhanced Solar-To-Hydrogen Evolution Employing Amorphous Carbon Dots As Electronic Mediator, Jiaxin Zhu, Mengmeng Zhang, Jinyan Xiong, Yinan Yan, Weijie Li, Gang Cheng Jan 2019

Electrostatically Assembled Construction Of Ternary Tio2-Cu@C Hybrid With Enhanced Solar-To-Hydrogen Evolution Employing Amorphous Carbon Dots As Electronic Mediator, Jiaxin Zhu, Mengmeng Zhang, Jinyan Xiong, Yinan Yan, Weijie Li, Gang Cheng

Australian Institute for Innovative Materials - Papers

The huge demand for renewable hydrogen produced by water splitting has prompted people to conduct in-depth research on the hydrogen evolution reaction for the development of earth-abundant, non-precious, and multi-functional metal catalysts. Herein, a noble-metal-free ternary composite of TiO2-Cu@C was prepared by electrostatic self-assembly loaded copper nanoparticles and amorphous carbon dots (CDs) on porous TiO2 microrods. The good conductivity of the CDs was beneficial to promoting the charge transfer and separation, generating an enhanced solar-to-hydrogen performance on TiO2-Cu@C. The optimized TiO2-Cu@C reveals a stable and notable hydrogen evolution rate of 3911 μmol g−1h−1, which is 1.6 times that of TiO2-Cu …


Bio‑Derived Hierarchical Multicore-Shell Fe2n‑Nanoparticle‑Impregnated N‑Doped Carbon Nanofiber Bundles: A Host Material For Lithium‑/Potassium‑Ion Storage, Hongjun Jiang, Ling Huang, Yunhong Wei, Boya Wang, Hao Wu, Yun Zhang, Hua-Kun Liu, Shi Xue Dou Jan 2019

Bio‑Derived Hierarchical Multicore-Shell Fe2n‑Nanoparticle‑Impregnated N‑Doped Carbon Nanofiber Bundles: A Host Material For Lithium‑/Potassium‑Ion Storage, Hongjun Jiang, Ling Huang, Yunhong Wei, Boya Wang, Hao Wu, Yun Zhang, Hua-Kun Liu, Shi Xue Dou

Australian Institute for Innovative Materials - Papers

Despite the significant progress in the fabrication of advanced electrode materials, complex control strategies and tedious processing are often involved for most targeted materials to tailor their compositions, morphologies, and chemistries. Inspired by the unique geometric structures of natural biomacromolecules together with their high affinities for metal species, we propose the use of skin collagen fibers for the template crafting of a novel multicore-shell Fe2N-carbon framework anode configuration, composed of hierarchical N-doped carbon nanofiber bundles firmly embedded with Fe2N nanoparticles (Fe2N@N-CFBs). In the resultant heterostructure, the Fe2N nanoparticles firmly confined inside the carbon shells are spatially isolated but electronically well …


Synthesis Of Cose2-Snse2 Nanocube-Coated Nitrogen-Doped Carbon (Nc) As Anode For Lithium And Sodium Ion Batteries, Jin Bai, Huimin Wu, Shiquan Wang, Guangxue Zhang, Chuanqi Feng, Hua-Kun Liu Jan 2019

Synthesis Of Cose2-Snse2 Nanocube-Coated Nitrogen-Doped Carbon (Nc) As Anode For Lithium And Sodium Ion Batteries, Jin Bai, Huimin Wu, Shiquan Wang, Guangxue Zhang, Chuanqi Feng, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

CoSe2-SnSe2/NC nanocubes (CSNC@NC) coated by nitrogen-doped carbon (NC) were synthesized successfully by an ordinary pyrazole polymerization and carbonization process. In comparison with bare CSNC, the CSNC@NC composite exhibited good structural stability and improved electrical conductivity when used as anode. The CSNC@NC electrode showed a stable Li storage capacity (730.41 mAh g−1 over 100 cycles at 0.2 A g−1) and excellent rate performance (402.10 mAh g−1 at 2 A g−1). For Na storage, the discharge capacity could be maintained 279.3 mAh g−1 over 100 cycles at 0.2 A g−1; the lower capacity than that for Li storage maybe caused by the …


Constructing Coo/Co3s4 Heterostructures Embedded In N-Doped Carbon Frameworks For High-Performance Sodium-Ion Batteries, Can Guo, Wenchao Zhang, Yi Liu, Jiapeng He, Shun Yang, Mingkai Liu, Qinghong Wang, Zaiping Guo Jan 2019

Constructing Coo/Co3s4 Heterostructures Embedded In N-Doped Carbon Frameworks For High-Performance Sodium-Ion Batteries, Can Guo, Wenchao Zhang, Yi Liu, Jiapeng He, Shun Yang, Mingkai Liu, Qinghong Wang, Zaiping Guo

Australian Institute for Innovative Materials - Papers

Heterostructures are attractive for advanced energy storage devices due to their rapid charge transfer kinetics, which is of benefit to the rate performance. The rational and facile construction of heterostructures with satisfactory electrochemical performance, however, is still a great challenge. Herein, ultrafine hetero-CoO/Co3S4 nanoparticles embedded in N-doped carbon frameworks (CoO/Co3S4@N-C) are successfully obtained by employing metal-organic frameworks as precursors. As anodes for sodium ion batteries, the CoO/Co3S4@N-C electrodes exhibit high specific capacity (1029.5 mA h g−1 at 100 mA g−1) and excellent rate capability (428.0 mA h g−1 at 5 A g−1), which may be attributed to their enhanced electric …


Porous Nati2(Po4)(3) Nanocubes Anchored On Porous Carbon Nanosheets For High Performance Sodium-Ion Batteries, Ziqi Wang, Jiaojiao Liang, Kai Fan, Xiaodi Liu, Caiyun Wang, Jianmin Ma Jan 2018

Porous Nati2(Po4)(3) Nanocubes Anchored On Porous Carbon Nanosheets For High Performance Sodium-Ion Batteries, Ziqi Wang, Jiaojiao Liang, Kai Fan, Xiaodi Liu, Caiyun Wang, Jianmin Ma

Australian Institute for Innovative Materials - Papers

NaTi2(PO4)3 has attracted great interest as anode material for sodium ion batteries owing to its open three-dimensional framework structure and limited volume changes during the charge and discharge process. However, the poor intrinsic electronic conductivity of NaTi2(PO4)3 needs to be improved for high rate capability. In this work, porous NaTi2(PO4)3 nanocubes anchored on porous carbon nanosheets (NaTi2(PO4)3/C) are designed and developed. This material exhibits a large discharge capacity and good rate capacity including a first discharge capacity of 485 mAh g−1 at a current density of 0.1 A g−1, and 98 mAh g−1 retained at a high rate of 4 …


Probe Sensor Using Nanostructured Multi-Walled Carbon Nanotube Yarn For Selective And Sensitive Detection Of Dopamine, Wed Al-Graiti, Zhilian Yue, Javad Foroughi, Xu-Feng Huang, Gordon G. Wallace, Ray H. Baughman, Jun Chen Jan 2017

Probe Sensor Using Nanostructured Multi-Walled Carbon Nanotube Yarn For Selective And Sensitive Detection Of Dopamine, Wed Al-Graiti, Zhilian Yue, Javad Foroughi, Xu-Feng Huang, Gordon G. Wallace, Ray H. Baughman, Jun Chen

Australian Institute for Innovative Materials - Papers

The demands for electrochemical sensor materials with high strength and durability in physiological conditions continue to grow and novel approaches are being enabled by the advent of new electromaterials and novel fabrication technologies. Herein, we demonstrate a probe-style electrochemical sensor using highly flexible and conductive multi-walled carbon nanotubes (MWNT) yarns. The MWNT yarn-based sensors can be fabricated onto micro Pt-wire with a controlled diameter varying from 100 to 300 µm, and then further modified with Nafion via a dip-coating approach. The fabricated micro-sized sensors were characterized by electron microscopy, Raman, FTIR, electrical, and electrochemical measurements. For the first time, the …


Hollow Carbon Nanobubbles: Monocrystalline Mof Nanobubbles And Their Pyrolysis, Wei Zhang, Xiangfen Jiang, Yanyi Zhao, Arnau Carne-Sanchez, Victor Malgras, Jeonghun Kim, Jung Ho Kim, Shaobin Wang, Jian Liu, Ji-Sen Jiang, Yusuke Yamauchi, Ming Hu Jan 2017

Hollow Carbon Nanobubbles: Monocrystalline Mof Nanobubbles And Their Pyrolysis, Wei Zhang, Xiangfen Jiang, Yanyi Zhao, Arnau Carne-Sanchez, Victor Malgras, Jeonghun Kim, Jung Ho Kim, Shaobin Wang, Jian Liu, Ji-Sen Jiang, Yusuke Yamauchi, Ming Hu

Australian Institute for Innovative Materials - Papers

While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nanobubbles with monocrystalline frameworks. By a spatially controlled etching approach, here, we can achieve the synthesis of zeolitic imidazolate framework (ZIF-8) nanobubbles with a uniform size of less than 100 nm. Interestingly, the ZIF-8 nanobubbles possess a monocrystalline nanoshell with a thickness of around 10 nm. Under optimal pyrolytic conditions, the ZIF-8 nanobubbles can be converted into hollow carbon nanobubbles while keeping their original shapes. The …


Hybrid Structure Of White Layer In High Carbon Steel - Formation Mechanism And Its Properties, Rumana Hossain, Farshid Pahlevani, Evelien Witteveen, Amborish Banerjee, Bill Joe, B Prusty, Rian J. Dippenaar, Veena Sahajwalla Jan 2017

Hybrid Structure Of White Layer In High Carbon Steel - Formation Mechanism And Its Properties, Rumana Hossain, Farshid Pahlevani, Evelien Witteveen, Amborish Banerjee, Bill Joe, B Prusty, Rian J. Dippenaar, Veena Sahajwalla

Faculty of Engineering and Information Sciences - Papers: Part B

This study identifies for the first time, the hybrid structure of the white layer in high carbon steel and describes its formation mechanism and properties. The so-called 'white layer' in steel forms during high strain rate deformation and appears featureless under optical microscopy. While many researchers have investigated the formation of the white layer, there has been no definitive study, nor is there sufficient evidence to fully explain the formation, structure and properties of the layer. In this study, the formation, morphology and mechanical properties of the white layer was determined following impact testing, using a combination of optical and …


Flexible Polycaprolactone (Pcl) Supercapacitor Based On Reduced Graphene Oxide (Rgo)/Single-Wall Carbon Nanotubes (Swnts) Composite Electrodes, Hyeon Taek Jeong, Yong-Ryeol Kim, Byung Chul Kim Jan 2017

Flexible Polycaprolactone (Pcl) Supercapacitor Based On Reduced Graphene Oxide (Rgo)/Single-Wall Carbon Nanotubes (Swnts) Composite Electrodes, Hyeon Taek Jeong, Yong-Ryeol Kim, Byung Chul Kim

Australian Institute for Innovative Materials - Papers

The reduced graphene oxide (rGO)/single-wall carbon nanotubes (SWNTs) composites are coated onto the polycaprolactone (PCL) substrate via spray coating technique to prepare a flexible supercapacitor. The electrochemical properties of the flexible PCL supercapacitor as a function of bending cycles and angles are evaluated using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge tests. The EIS and charge/discharge curves of the flexible PCL supercapacitor exhibit capacitive behavior even after prolonged bending cycles up to 500. The highest capacitance value of the unbent PCL supercapacitor is 52.5 F g-1 which retained 65% after 500 bending with 6000th galvanostatic charge/discharge cycles.


Capillary-Induced Ge Uniformly Distributed In N-Doped Carbon Nanotubes With Enhanced Li-Storage Performance, Haipeng Guo, Boyang Ruan, Lili Liu, Lei Zhang, Zhanliang Tao, Shulei Chou, Jiazhao Wang, Hua-Kun Liu Jan 2017

Capillary-Induced Ge Uniformly Distributed In N-Doped Carbon Nanotubes With Enhanced Li-Storage Performance, Haipeng Guo, Boyang Ruan, Lili Liu, Lei Zhang, Zhanliang Tao, Shulei Chou, Jiazhao Wang, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Germanium (Ge) is a prospective anode material for lithium-ion batteries, as it possesses large theoretical capacity, outstanding lithium-ion diffusivity, and excellent electrical conductivity. Ge suffers from drastic capacity decay and poor rate performance, however, owing to its low electrical conductivity and huge volume expansion during cycling processes. Herein, a novel strategy has been developed to synthesize a Ge at N-doped carbon nanotubes (Ge at N-CNTs) composite with Ge nanoparticles uniformly distributed in the N-CNTs by using capillary action. This unique structure could effectively buffer large volume expansion. When evaluated as an anode material, the Ge at N-CNTs demonstrate enhanced cycling …


Continuous Adsorption And Biotransformation Of Micropollutants By Granular Activated Carbon-Bound Laccase In A Packed-Bed Enzyme Reactor, Ngoc Luong Nguyen, Faisal I. Hai, Anthony Dosseto, Christopher Richardson, William E. Price, Long D. Nghiem Jan 2016

Continuous Adsorption And Biotransformation Of Micropollutants By Granular Activated Carbon-Bound Laccase In A Packed-Bed Enzyme Reactor, Ngoc Luong Nguyen, Faisal I. Hai, Anthony Dosseto, Christopher Richardson, William E. Price, Long D. Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

Laccase was immobilized on granular activated carbon (GAC) and the resulting GAC-bound laccase was used to degrade four micropollutants in a packed-bed column. Compared to the free enzyme, the immobilized laccase showed high residual activities over a broad range of pH and temperature. The GAC-bound laccase efficiently removed four micropollutants, namely, sulfamethoxazole, carbamazepine, diclofenac and bisphenol A, commonly detected in raw wastewater and wastewater-impacted water sources. Mass balance analysis showed that these micropollutants were enzymatically degraded following adsorption onto GAC. Higher degradation efficiency of micropollutants by the immobilized compared to free laccase was possibly due to better electron transfer between …


Superior Sodium-Ion Storage Performance Of Co3o4@Nitrogen-Doped Carbon: Derived From A Metal–Organic Framework, Ying Wang, Caiyun Wang, Yijing Wang, Hua-Kun Liu, Zhenguo Huang Jan 2016

Superior Sodium-Ion Storage Performance Of Co3o4@Nitrogen-Doped Carbon: Derived From A Metal–Organic Framework, Ying Wang, Caiyun Wang, Yijing Wang, Hua-Kun Liu, Zhenguo Huang

Australian Institute for Innovative Materials - Papers

Nitrogen-doped carbon coated Co 3 O 4 nanoparticles (Co 3 O 4 @NC) with high Na-ion storage capacity and unprecedented long-life cycling stability are reported in this paper. The Co 3 O 4 @NC was derived from a metal – organic framework ZIF-67, where the Co ions and organic linkers were, respectively, converted to Co 3 O 4 nanoparticle cores and nitrogen-doped carbon shells through a controlled two-step annealing process. The Co 3 O 4 @NC shows a porous nature with a surface area of 101 m 2 g 1 . When applied as an anode for sodium ion batteries …


Binder-Free And Carbon-Free 3d Porous Air Electrode For Li-O2 Batteries With High Efficiency, High Capacity, And Long Life, Wenbin Luo, Xuanwen Gao, Dongqi Shi, Shulei Chou, Jiazhao Wang, Hua-Kun Liu Jan 2016

Binder-Free And Carbon-Free 3d Porous Air Electrode For Li-O2 Batteries With High Efficiency, High Capacity, And Long Life, Wenbin Luo, Xuanwen Gao, Dongqi Shi, Shulei Chou, Jiazhao Wang, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Pt-Gd alloy polycrystalline thin film is deposited on 3D nickel foam by pulsed laser deposition method serving as a whole binder/carbon-free air electrode, showing great catalytic activity enhancement as an efficient bifunctional catalyst for the oxygen reduction and evolution reactions in lithium oxygen batteries. The porous structure can facilitate rapid O2 and electrolyte diffusion, as well as forming a continuous conductive network throughout the whole energy conversion process. It shows a favorable cycle performance in the full discharge/charge model, owing to the high catalytic activity of the Pt-Gd alloy composite and 3D porous nickel foam structure. Specially, excellent cycling performance …


Achieving High-Performance Room-Temperature Sodium−Sulfur Batteries With S@Interconnected Mesoporous Carbon Hollow Nanospheres, Yunxiao Wang, Jianping Yang, Weihong Lai, Shulei Chou, Qinfen Gu, Hua-Kun Liu, Dongyuan Zhao, Shi Xue Dou Jan 2016

Achieving High-Performance Room-Temperature Sodium−Sulfur Batteries With S@Interconnected Mesoporous Carbon Hollow Nanospheres, Yunxiao Wang, Jianping Yang, Weihong Lai, Shulei Chou, Qinfen Gu, Hua-Kun Liu, Dongyuan Zhao, Shi Xue Dou

Australian Institute for Innovative Materials - Papers

Despite the high theoretical capacity of the sodium-sulfur battery, its application is seriously restrained by the challenges due to its low sulfur electroactivity and accelerated shuttle effect, which lead to low accessible capacity and fast decay. Herein, an elaborate carbon framework, interconnected mesoporous hollow carbon nanospheres, is reported as an effective sulfur host to achieve excellent electrochemical performance. Based on in-situ synchrotron X-ray diffraction, the mechanism of the room temperature Na/S battery is proposed to be reversible reactions between S8 and Na2S4, corresponding to a theoretical capacity of 418 mAh g-1. The cell is capable of achieving high capacity retention …


Bio-Inspired, Moisture-Powered Hybrid Carbon Nanotube Yarn Muscles, Shi Hyeong Kim, Cheong Hoon Kwon, Karam Park, Tae Jin Mun, Xavier Lepro, Ray H. Baughman, Geoffrey M. Spinks, Seon Jeong Kim Jan 2016

Bio-Inspired, Moisture-Powered Hybrid Carbon Nanotube Yarn Muscles, Shi Hyeong Kim, Cheong Hoon Kwon, Karam Park, Tae Jin Mun, Xavier Lepro, Ray H. Baughman, Geoffrey M. Spinks, Seon Jeong Kim

Australian Institute for Innovative Materials - Papers

Hygromorph artificial muscles are attractive as self-powered actuators driven by moisture from the ambient environment. Previously reported hygromorph muscles have been largely limited to bending or torsional motions or as tensile actuators with low work and energy densities. Herein, we developed a hybrid yarn artificial muscle with a unique coiled and wrinkled structure, which can be actuated by either changing relative humidity or contact with water. The muscle provides a large tensile stroke (up to 78%) and a high maximum gravimetric work capacity during contraction (2.17 kJ kg−1), which is over 50 times that of the same weight human muscle …


3d Binder-Free Mose2 Nanosheets/Carbon Cloth Electrodes For Efficient And Stable Hydrogen Evolution Prepared By Simple Electrophoresis Deposition Strategy, Yundan Liu, Long Ren, Zhen Zhang, Xiang Qi, Hongxing Li, Jianxin Zhong Jan 2016

3d Binder-Free Mose2 Nanosheets/Carbon Cloth Electrodes For Efficient And Stable Hydrogen Evolution Prepared By Simple Electrophoresis Deposition Strategy, Yundan Liu, Long Ren, Zhen Zhang, Xiang Qi, Hongxing Li, Jianxin Zhong

Australian Institute for Innovative Materials - Papers

We successfully developed a simple electrophoretic deposition (EPD) method to decorate the MoSe2 nanosheets on the carbon fiber surface of carbon cloth (MoSe2/CC). With this process, MoSe2 nanosheets can be uniformly and tightly deposited on this flexible conductor to form a 3D binder-free electrode for hydrogen evolution reaction (HER). The film thickness can also be controlled by the EPD time. Directly used as binder-free electrodes for hydrogen evolution reaction, the as-prepared 3D MoSe2/CC samples exhibit excellent catalytic activity in an acidic electrolyte (21 mA/cm2 at an over-potential of 250 mV). Variation of MoSe2 nanosheets film thickness in the electrodes could …


Contribution Of Radicals And Ions In Catalyzed Growth Of Single-Walled Carbon Nanotubes From Low-Temperature Plasmas, Z Marvi, S Xu, G Foroutan, Kostya Ostrikov Jan 2015

Contribution Of Radicals And Ions In Catalyzed Growth Of Single-Walled Carbon Nanotubes From Low-Temperature Plasmas, Z Marvi, S Xu, G Foroutan, Kostya Ostrikov

Australian Institute for Innovative Materials - Papers

The growth kinetics of single-walled carbon nanotubes (SWCNTs) in a low-temperature, low-pressure reactive plasma is investigated using a multiscale numerical simulation, including the plasma sheath and surface diffusion modules. The plasma-related effects on the characteristics of SWCNT growth are studied. It is found that in the presence of reactive radicals in addition to energetic ions inside the plasma sheath area, the effective carbon flux, and the growth rate of SWCNT increase. It is shown that the concentration of atomic hydrogen and hydrocarbon radicals in the plasma plays an important role in the SWCNT growth. The effect of the effective carbon …


One Dimensional Graphitic Carbon Nitrides As Effective Metal-Free Oxygen Reduction Catalysts, Muhammad Nawaz Tahir, Nasir Mahmood, Jinghan Zhu, Asif Mahmood, Faheem K. Butt, Syed Rizwan, Imran Aslam, M Tanveer, Faryal Idrees, Imran Shakir, Chuanbao Cao, Yanglong Hou Jan 2015

One Dimensional Graphitic Carbon Nitrides As Effective Metal-Free Oxygen Reduction Catalysts, Muhammad Nawaz Tahir, Nasir Mahmood, Jinghan Zhu, Asif Mahmood, Faheem K. Butt, Syed Rizwan, Imran Aslam, M Tanveer, Faryal Idrees, Imran Shakir, Chuanbao Cao, Yanglong Hou

Australian Institute for Innovative Materials - Papers

To explore the effect of morphology on catalytic properties of graphitic carbon nitride (GCN), we have studied oxygen reduction reaction (ORR) performance of two different morphologies of GCN in alkaline media. Among both, tubular GCN react with dissolved oxygen in the ORR with an onset potential close to commercial Pt/C. Furthermore, the higher stability and excellent methanol tolerance of tubular GCN compared to Pt/C emphasizes its suitability for fuel cells.


Zero Carbon Homes: Perceptions From The Uk Construction Industry, Emma Elizabeth Heffernan, Wei Pan, Xi Liang, Pieter De Wilde Jan 2015

Zero Carbon Homes: Perceptions From The Uk Construction Industry, Emma Elizabeth Heffernan, Wei Pan, Xi Liang, Pieter De Wilde

Faculty of Engineering and Information Sciences - Papers: Part A

The take-up of the many voluntary energy efficiency standards which exist in the UK and internationally has been limited. As a result, governments have recognised the need to introduce mandatory schemes through legislation, e.g. from 2016 all new build homes in the UK will be required to achieve zero carbon in regulated energy consumption. However, as 2016 approaches, very few zero carbon homes are being delivered. This paper explores the drivers and barriers for zero carbon homebuilding. The perceptions of the wider construction industry were gathered through a series of semi-structured interviews with professionals involved in commissioning, designing, constructing and …


Interface Analysis And Hot Deformation Behaviour Of A Novel Laminated Composite With High-Cr Cast Iron And Low Carbon Steel Prepared By Hot Compression Bonding, Zhengyi Jiang, Xingjian Gao, Sheng-Li Li, Hong Mei Zhang, Dengfu Chen, Jian Zhong Xu Jan 2015

Interface Analysis And Hot Deformation Behaviour Of A Novel Laminated Composite With High-Cr Cast Iron And Low Carbon Steel Prepared By Hot Compression Bonding, Zhengyi Jiang, Xingjian Gao, Sheng-Li Li, Hong Mei Zhang, Dengfu Chen, Jian Zhong Xu

Faculty of Engineering and Information Sciences - Papers: Part A

A hot compression bonding process was developed to prepare a novel laminated composite consisting of high-Cr cast iron (HCCI) as the inner layer and low carbon steel (LCS) as the outer layers on a Gleeble 3500 thermomechanical simulator at a temperature of 950 °C and a strain rate of 0.001 S-1. Interfacial bond quality and hot deformation behaviour of the laminate were studied by microstructural characterisation and mechanical tests. Experimental results show that the metallurgical bond between the constituent metals was achieved under the proposed bonding conditions without discernible defects and the formation of interlayer or intermetallic layer …


V2o5/Mesoporous Carbon Composite As A Cathode Material For Lithium-Ion Batteries, Mohammad Ihsan, Qing Meng, Li Li, Dan Li, Hongqiang Wang, Kuok Hau Seng, Zhixin Chen, Shane J. Kennedy, Zaiping Guo, Hua-Kun Liu Jan 2015

V2o5/Mesoporous Carbon Composite As A Cathode Material For Lithium-Ion Batteries, Mohammad Ihsan, Qing Meng, Li Li, Dan Li, Hongqiang Wang, Kuok Hau Seng, Zhixin Chen, Shane J. Kennedy, Zaiping Guo, Hua-Kun Liu

Faculty of Engineering and Information Sciences - Papers: Part A

V2O5/mesoporous carbon composite has been prepared by an ultrasonically assisted method followed by a sintering process. The as-prepared V2O5/mesoporous carbon material containing 90 wt% V2O5 shows better electrochemical performance, with capacity of 163 mA h g-1 after 100 cycles at the current density of 500 mA g-1, as well as better charge/discharge rate capability for lithium storage than V2O5 nanoparticles. The improved electrochemical performance indicates that the V2O5/mesoporous carbon composite could be used as a promising cathode material for …


Effect Of Pre-Quenching Process On Microstructure And Mechanical Properties In A Nb-Microalloyed Low Carbon Q-P Steel, Jun Zhang, Hua Ding, Jingwei Zhao Jan 2015

Effect Of Pre-Quenching Process On Microstructure And Mechanical Properties In A Nb-Microalloyed Low Carbon Q-P Steel, Jun Zhang, Hua Ding, Jingwei Zhao

Faculty of Engineering and Information Sciences - Papers: Part A

A refined microstructure consisting of martensite and retained austenite at room temperature has been produced in a Nb-microalloyed low carbon Si-Mn steel by a novel heat-treatment, pre-quenching prior to quenching and partitioning processes (Q&Q-P). The results showed that compared with the conventional quenching and partitioning steel the mechanical properties of steel obtained by the novel treatment have been significantly improved, with a good combination of ultimate tensile strength (1000MPa) and total elongation (above 30%). Meanwhile, the volume fraction of retained austenite has been increased. It was found that the improvement of mechanical properties was mainly attributed to the enhanced TRIP …


Stability Of Carbon Nanotube Yarn Biofuel Cell In Human Body Fluid, Cheong Hoon Kwon, Jae Ah Lee, Young-Bong Choi, Hyug-Han Kim, Geoffrey M. Spinks, Marcio D. Lima, Ray H. Baughman, Seon Jeong Kim Jan 2015

Stability Of Carbon Nanotube Yarn Biofuel Cell In Human Body Fluid, Cheong Hoon Kwon, Jae Ah Lee, Young-Bong Choi, Hyug-Han Kim, Geoffrey M. Spinks, Marcio D. Lima, Ray H. Baughman, Seon Jeong Kim

Faculty of Engineering and Information Sciences - Papers: Part A

High performance with stability, easy-handling electrodes, and biofluid-flow controllable system with mechanical strength of the biofuel cell can be considered as the critical issues for future human body implant. These three challenges are sufficiently considered by using the effective platform regarding the high surface area from multi-walled carbon nanotube-conducting polymer with poly(3,4-ethylenedioxythiophene), and size/shape dependent flexible yarn electrodes for the implantation of biofuel cell. High power biofuel cell of mW cm-2 range in physiological condition (low glucose-containing phosphate buffered saline solution and human blood serum) controlling the stirring degree is also first demonstrated for future implantation in this study. Biofuel …


Significantly Enhanced Critical Current Density In Nano-Mgb2 Grains Rapidly Formed At Low Temperature With Homogeneous Carbon Doping, Yongchang Liu, Feng Lan, Zongqing Ma, Ning Chen, Huijun Li, Shaon Barua, Dipakkumar Patel, Md S. Hossain, S Acar, Jung Ho Kim, S X. Dou Jan 2015

Significantly Enhanced Critical Current Density In Nano-Mgb2 Grains Rapidly Formed At Low Temperature With Homogeneous Carbon Doping, Yongchang Liu, Feng Lan, Zongqing Ma, Ning Chen, Huijun Li, Shaon Barua, Dipakkumar Patel, Md S. Hossain, S Acar, Jung Ho Kim, S X. Dou

Australian Institute for Innovative Materials - Papers

High performance MgB2 bulks using carbon-coated amorphous boron as a boron precursor were fabricated by Cu-activated sintering at low temperature (600 °C, below the Mg melting point). Dense nano-MgB2 grains with a high level of homogeneous carbon doping were formed in these MgB2 samples. This type of microstructure can provide a stronger flux pinning force, together with depressed volatility and oxidation of Mg owing to the low-temperature Cu-activated sintering, leading to a significant improvement of critical current density (Jc) in the as-prepared samples. In particular, the value of Jc for the carbon-coated (Mg …


A Fe/Fe3o4/N-Carbon Composite With Hierarchical Porous Structure And In Situ Formed N-Doped Graphene-Like Layers For High-Performance Lithium Ion Batteries, Yao Li, Qing Meng, Shenmin Zhu, Zeng-Hui Sun, Hao Yang, Zhixin Chen, Chengling Zhu, Zaiping Guo, Di Zhang Jan 2015

A Fe/Fe3o4/N-Carbon Composite With Hierarchical Porous Structure And In Situ Formed N-Doped Graphene-Like Layers For High-Performance Lithium Ion Batteries, Yao Li, Qing Meng, Shenmin Zhu, Zeng-Hui Sun, Hao Yang, Zhixin Chen, Chengling Zhu, Zaiping Guo, Di Zhang

Faculty of Engineering and Information Sciences - Papers: Part A

Fe/Fe3O4/N-carbon composite consisting of a porous carbon matrix containing a highly conductive N-doped graphene-like network and Fe/Fe3O4 nanoparticles was prepared. The porous carbon has a hierarchical structure which is inherited from rice husk and the N-doped graphene-like network formed in situ. When used as an anode material for lithium batteries, the composite delivered a reversible capacity of approximately 610 mA h g(-1) at a current density of 200 mA g(-1) even after 100 cycles, due to the synergism between the unique hierarchical porous structures, highly electrically conductive N-doped graphene- like networks and nanosized particles of Fe/Fe3O4. This work provides a …


Facile Synthesis Of Coaxial Cnts/Mnox-Carbon Hybrid Nanofibers And Their Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Jun Lv, Haidong Pang, Wenhuan Yan, Kun Qian, Tailiang Guo, Zaiping Guo Jan 2015

Facile Synthesis Of Coaxial Cnts/Mnox-Carbon Hybrid Nanofibers And Their Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Jun Lv, Haidong Pang, Wenhuan Yan, Kun Qian, Tailiang Guo, Zaiping Guo

Faculty of Engineering and Information Sciences - Papers: Part A

Carbon nanotubes (CNTs)/MnOx-Carbon hybrid nanofibers have been successfully synthesized by the combination of a liquid chemical redox reaction (LCRR) and a subsequent carbonization heat treatment. The nanostructures exhibit a unique one-dimensional core/shell architecture, with one-dimensional CNTs encapsulated inside and a MnOx-carbon composite nanoparticle layer on the outside. The particular porous characteristics with many meso/micro holes/pores, the highly conductive one-dimensional CNT core, as well as the encapsulating carbon matrix on the outside of the MnOx nanoparticles, lead to excellent electrochemical performance of the electrode. The CNTs/MnOx-Carbon hybrid nanofibers exhibit a high initial reversible capacity of …


Efficient, Absorption-Powered Artificial Muscles Based On Carbon Nanotube Hybrid Yarns, Marcio D. Lima, Mohammad W. Hussain, Geoffrey M. Spinks, Sina Naficy, Daniela Hagenasr, Julia S. Bykova, Derrick Tolly, Ray H. Baughman Jan 2015

Efficient, Absorption-Powered Artificial Muscles Based On Carbon Nanotube Hybrid Yarns, Marcio D. Lima, Mohammad W. Hussain, Geoffrey M. Spinks, Sina Naficy, Daniela Hagenasr, Julia S. Bykova, Derrick Tolly, Ray H. Baughman

Australian Institute for Innovative Materials - Papers

A new type of absorption-powered artificial muscle provides high performance without needing a temperature change. These muscles, comprising coiled carbon nanotube fibers infiltrated with silicone rubber, can contract up to 50% to generate up to 1.2 kJ kg−1. The drive mechanism for actuation is the rubber swelling during exposure to a nonpolar solvent. Theoretical energy efficiency conversion can be as high as 16%.


Dual Yolk-Shell Structure Of Carbon And Silica-Coated Silicon For High-Performance Lithium-Ion Batteries, L Y. Yang, H Z. Li, Jun Liu, Ziqi Sun, S S. Tang, M Lei Jan 2015

Dual Yolk-Shell Structure Of Carbon And Silica-Coated Silicon For High-Performance Lithium-Ion Batteries, L Y. Yang, H Z. Li, Jun Liu, Ziqi Sun, S S. Tang, M Lei

Australian Institute for Innovative Materials - Papers

Silicon batteries have attracted much attention in recent years due to their high theoretical capacity, although a rapid capacity fade is normally observed, attributed mainly to volume expansion during lithiation. Here, we report for the first time successful synthesis of Si/void/SiO2/void/C nanostructures. The synthesis strategy only involves selective etching of SiO2 in Si/SiO2/C structures with hydrofluoric acid solution. Compared with reported results, such novel structures include a hard SiO2-coated layer, a conductive carbon-coated layer, and two internal void spaces. In the structures, the carbon can enhance conductivity, the SiO2 layer has mechanically …