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Engineering

University of South Carolina

Series

2013

High temperatures

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Enhanced Reducibility And Conductivity Of Na/K-Doped Srti0.8Nb0.2O3, Guoliang Xiao, Sirikanda Nuansaeng, Lei Zhang, Suwit Suthirakun, Andreas Heyden, Hans-Conrad Zur Loye, Fanglin Chen Sep 2013

Enhanced Reducibility And Conductivity Of Na/K-Doped Srti0.8Nb0.2O3, Guoliang Xiao, Sirikanda Nuansaeng, Lei Zhang, Suwit Suthirakun, Andreas Heyden, Hans-Conrad Zur Loye, Fanglin Chen

Faculty Publications

Donor and acceptor co-doped SrTiO3 materials have shown interesting features in their conductivity and reducibility. In this work, 10 mol% Na+ or K+ as acceptor dopants have been introduced into the A-site of donor-doped strontium titanate, SrTi0.8Nb0.2O3, and the doping impact on their properties has been studied. By doping with Na or K, the sinterability of SrTi0.8Nb0.2O3 in reducing atmospheres has been improved. Na0.1Sr0.9Ti0.8Nb0.2O3 and K0.1Sr0.9Ti0.8Nb0.2O3 show metallic …


Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang Aug 2013

Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

The recently developed rechargeable solid oxide metal-air redox battery has shown a great potential for applications in mid- to large-scale stationary energy storage. Cyclic durability is one of the most important requirements for stationary energy storage. In this study, we report the cyclic durability of a solid oxide Fe-air redox battery operated at 650°C. The battery was continuously cycled 100 times under a current density of 50 mA/cm2 with rather flat performance, producing an average specific energy of 760 Wh/kg-Fe at a round-trip efficiency of 55.5%. The post-test examination indicated that the performance losses could arise from the fuel-electrode …