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Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

Chromium oxides and lithiated chromium oxides were synthesized by thermal decomposition of chromium trioxide (CrO₃) at high temperatures and oxygen pressures. Synthesis temperature and pressure markedly affect the performance of these cathode materials. Higher pressures lead to a higher O/Cr ratio and fewer impurities in the final product. These materials are stable intercalation hosts for lithium, and exhibit a higher capacity than any of the prominent positive electrodes used in secondary lithium batteries. m-CrO_x has a capacity of 255 mAh/g, while m-LiCrO_x has a capacity of 210 mAh/g, during the first discharge. The average …