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Engineering

University of Louisville

Theses/Dissertations

2021

Wastewater

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An Introductory Study Of Coal Fly Ash Enhancement For Heavy Metal Removal In Wastewater Treatment., Samuel T. Romes Dec 2021

An Introductory Study Of Coal Fly Ash Enhancement For Heavy Metal Removal In Wastewater Treatment., Samuel T. Romes

Electronic Theses and Dissertations

Coal Combustion Products are the materials that remain after pulverized coal is burned to generate electricity. The fine portion, fly ash, has many re-use capabilities across various industries. Most recent data shows that approximately 60% of fly ash produced in the United States was used with the largest re-use being concrete additives. This work aims to enhance fly ash via hydrothermal treatment in order to expand the re-use capabilities of the material. These materials were tested as adsorbents for heavy metal removal from wastewater samples. The metals tested for removal were Copper (II) Acetate, Cadmium Chloride, Boric Acid, Sodium Selenite, …


Coal Fly Ash Beneficiation For Reuse And Removal Of Boron, Cadmium, Chromium, Copper, And Selenium In Wastewater Treatment., Joseph E. Cahill Dec 2021

Coal Fly Ash Beneficiation For Reuse And Removal Of Boron, Cadmium, Chromium, Copper, And Selenium In Wastewater Treatment., Joseph E. Cahill

Electronic Theses and Dissertations

New regulations on coal-fired power plants make previously used wastewater treatment methods aimed to remove heavy metals obsolete. Therefore, there has been increased interest and investment into new technologies to treat coal-fired power plants effluent in the past few years. Traditionally, heavy metal removal technologies have been broken into three categories: physical, chemical or biological. However, with new regulations, each category by itself does not offer an ideal solution to removing acceptable concentrations of heavy metals found in the effluents at the coal-fired power plants. Here we report a novel proof-of-concept utilizing adsorption through ion-exchange/co-precipitation - chemical and physical - …


Annealing Of Encapsulated Heavy Metals From Brine Water Utilizing Microwave Enabled Sol-Gel Process, Adam Michael Flynn May 2021

Annealing Of Encapsulated Heavy Metals From Brine Water Utilizing Microwave Enabled Sol-Gel Process, Adam Michael Flynn

Electronic Theses and Dissertations

Various waste encapsulation strategies have been investigated to solidify and stabilize heavy metal wastewater for proper long-term storage. This work aims to enhance a method of novel sol-gel encapsulation of heavy metals from mock brine waters using tetramethyl orthosilicate with the addition of an annealing step at various temperatures in order to reduce leaching of metals from the silica monoliths when exposed to water. The metals tested for encapsulation and leaching were mercury (II) chloride, potassium dichromate, sodium selenite, boric acid, cadmium chloride, and copper (II) acetate. The annealing of the silica monoliths led to an increased degree of for …