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Prediction And Correlation Of The Salt-Effect In Vapor-Liquid Equilibrium, Enrique M. Bekerman

Theses

The feasibility of developing a method of correlation and prediction, for mixtures of two solvents containing a dissolved salt has been studied. The procedure consisted of arriving at the interaction parameters for the three binary systems (solvent 1-solvent 2, solvent 1-salt, solvent 2-salt) and using these to calculate the ternary results. Attempts to generate interaction parameters for the solvent-salt binaries by means of the Wilson equation were unsuccessful, whereas, use of the NRTL equation resulted in a very good fit of the binary data.

In correlating the ternary results, it became necessary to redefine the liquid phase mole fractions and …

Diffusion Of Single And Multicomponent Solutes From Capillaries, Oleh S. Sklepkowycz

Theses

The purpose of this investigation was to determine the diffusion coefficients of several single and multi-component solutes, and to establish the relations between the diffusivity, the solute composition) and the diffusion rate. Such information pertinent to the extraction and leaching operations, can not be found in literature.

The procedure developed by Piret, Wbel, and Armstrong (25), involving observation of the extraction rate of two-phase mixtures from straight capillaries, was adopted and verified on a known sodium chloride-water system.

In the course of the experimental work diffusion coefficients more determined for ursolic acid, palmitic acid, and tripalmitin in methyl isobutyl ketone. …