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Engineering

Clemson University

2012

Gold Nanoparticles

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Application Of Carbon Dioxide Towards The Development Of Smart Materials, Green Reaction Schemes And Metallic Nanoparticle Synthesis, Fiaz Mohammed Dec 2012

Application Of Carbon Dioxide Towards The Development Of Smart Materials, Green Reaction Schemes And Metallic Nanoparticle Synthesis, Fiaz Mohammed

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Global carbon dioxide (CO2) emissions have steadily risen over the last 50 years, with 34 billion tons of CO2 released in 2009 alone. Its potential as a greenhouse gas has negatively affected of our lives and environment by the resulting ocean acidification and climate change. To mitigate atmospheric CO2, various strategies have been implemented for CO2 separation, capture, storage and use as a chemical feedstock. The use of CO2 in various chemical industries is attractive as its non-flammable, non-toxic, and relatively inert properties have made it an inherently safer alternative to traditional organic …


Measuring Ligand Exchange On The Surface Of Gold Nanoparticles: A Study Of Competitive Binding Of Ligands Utilizing Fluorescent Resonance Energy Transfer, Daniel D'Unger Aug 2012

Measuring Ligand Exchange On The Surface Of Gold Nanoparticles: A Study Of Competitive Binding Of Ligands Utilizing Fluorescent Resonance Energy Transfer, Daniel D'Unger

All Theses

This study was conducted to track ligand exchange on the surface of metallic nanoparticles in order obtain a better understanding of binding strength of various functional groups. This study develops groundwork for further understanding ligand exchange as nanoparticles transition from engineered to natural systems. A problem exists in knowing the fate of these particles if they are released into natural systems, by accident or with intent. To gain a better understanding of what may occur we look at the binding strength of different ligands. This is done to gain knowledge of the possibility of displacement of ligands occurring in the …