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Engineering

Clemson University

2012

Copper

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Detecting Copper Residues In Sediments From Aquatic Copper-Based Pesticide Applications, Ben Willis Dec 2012

Detecting Copper Residues In Sediments From Aquatic Copper-Based Pesticide Applications, Ben Willis

All Theses

Copper-based algaecides and herbicides are commonly used to mitigate risks of problematic algae and weeds, however there are concerns regarding copper accumulation from treatments. Modeling and laboratory experiments can be used to predict copper accumulation and measurement in sediments, as well as benthic invertebrate responses following treatments. Modeling was used to estimate copper residual concentrations in sediments from algaecide and herbicide treatments. Reported and measured method detection limits (MDLs; minimum concentration of an analyte of interest that can be measured with 99 percent confidence in a specific matrix using an analytical method) were compared to model estimated copper residual concentrations …


Grain Boundaries Structures And Wetting In Doped Silicon, Nickel And Copper, Kaveh Meshinchi Asl May 2012

Grain Boundaries Structures And Wetting In Doped Silicon, Nickel And Copper, Kaveh Meshinchi Asl

All Dissertations

This thesis reports a series of fundamental investigations of grain boundary wetting, adsorption and structural (phases) transitions in doped Ni, Cu and Si with technological relevance to liquid metal embrittlement, liquid metal corrosion and device applications. First, intrinsically ductile metals are prone to catastrophic failure when exposed to certain liquid metals, but the atomic level mechanism for this effect is not fully understood. A nickel sample infused with bismuth atoms was characterized and a bilayer interfacial phase that is the underlying cause of embrittlement was observed. In a second related study, we showed that addition of minor impurities can significantly …