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Wayne State University Dissertations

Theses/Dissertations

2012

Biofuels, Carbide, Hydrotreating Catalyst, Nitride

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Biofuels Production From Hydrotreating Of Vegetable Oil Using Supported Noble Metals, And Transition Metal Carbide And Nitride, Huali Wang Jan 2012

Biofuels Production From Hydrotreating Of Vegetable Oil Using Supported Noble Metals, And Transition Metal Carbide And Nitride, Huali Wang

Wayne State University Dissertations

The focus of this research is to prepare non-sulfided hydrotreating catalysts, supported noble metal and transition metal carbide/ nitride, and evaluate their hydrocracking activities and selectivities by using soybean oil as the feedstock. For comparison study, catalytic cracking of soybean oil over a commercialized ZSM-5 was investigated. However, steady state could not be reached because significant amounts of tar and coke were generated during the reaction though a high yield (21%) of jet fuel was obtained from the process. Compared to the catalytic cracking process, less tar and coke were formed during the hydrocracking process and stable continuous flow reaction …