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Microscopic Role Of Carbon On Mgb2 Wire For Critical Current Density Comparable To Nbti, Jung Ho Kim, Sangjun Oh, Yoon-Uk Heo, Satoshi Hata, Hiroaki Kumakura, Akiyoshi Matsumoto, Masatoshi Mitsuhara, Seyong Choi, Yusuke Shimada, Minoru Maeda, Judith Macmanus-Driscoll, S X. Dou
Microscopic Role Of Carbon On Mgb2 Wire For Critical Current Density Comparable To Nbti, Jung Ho Kim, Sangjun Oh, Yoon-Uk Heo, Satoshi Hata, Hiroaki Kumakura, Akiyoshi Matsumoto, Masatoshi Mitsuhara, Seyong Choi, Yusuke Shimada, Minoru Maeda, Judith Macmanus-Driscoll, S X. Dou
Australian Institute for Innovative Materials - Papers
Increasing dissipation-free supercurrent has been the primary issue for practical application of superconducting wires. For magnesium diboride, MgB2, carbon is known to be the most effective dopant to enhance high-field properties. However, the critical role of carbon remains elusive, and also low-field critical current density has not been improved. Here, we have undertaken malic acid doping of MgB2 and find that the microscopic origin for the enhancement of high-field properties is due to boron vacancies and associated stacking faults, as observed by high-resolution transmission electron microscopy and electron energy loss spectroscopy. The carbon from the malic acid almost uniformly encapsulates …
A "Skeleton/Skin"Strategy For Preparing Ultrathin Free-Standing Single-Walled Carbon Nanotube/Polyaniline Films For High Performance Supercapacitor Electrodes, Zhiqiang Niu, Pingshan Luan, Qi Shao, Haibo Dong, Jinzhu Li, Jun Chen, Duan Zhao, Le Cai, Weiya Zhou, Xiaodong Chen, Sishen Xie
A "Skeleton/Skin"Strategy For Preparing Ultrathin Free-Standing Single-Walled Carbon Nanotube/Polyaniline Films For High Performance Supercapacitor Electrodes, Zhiqiang Niu, Pingshan Luan, Qi Shao, Haibo Dong, Jinzhu Li, Jun Chen, Duan Zhao, Le Cai, Weiya Zhou, Xiaodong Chen, Sishen Xie
Faculty of Engineering - Papers (Archive)
One of the most critical aspects in the preparation of single-walled carbon nanotubes (SWCNTs)/ conducting polymer hybrid electrodes is to improve the energy density without seriously deteriorating their high power capability. Here, we report a ‘‘skeleton/skin’’ strategy for the preparation of freestanding, thin and flexible SWCNT/polyaniline (PANI) hybrid films by a simple in situ electrochemical polymerization method using directly grown SWCNT films with a continuous reticulate structure as template. In situ electrochemical polymerization can achieve effective deposition of PANI onto the surface of SWCNT bundles in the films and control the morphology and microstructure of the SWCNT/PANI hybrid films. In …
Synthesis Of Uniform Tio2@Carbon Composite Nanofibers As Anode For Lithium Ion Batteries With Enhanced Electrochemical Performance, Zunxian Yang, Guodong Du, Qing Meng, Zaiping Guo, Xuebin Yu, Zhixin Chen, Tailiang Guo, Rong Zeng
Synthesis Of Uniform Tio2@Carbon Composite Nanofibers As Anode For Lithium Ion Batteries With Enhanced Electrochemical Performance, Zunxian Yang, Guodong Du, Qing Meng, Zaiping Guo, Xuebin Yu, Zhixin Chen, Tailiang Guo, Rong Zeng
Faculty of Engineering - Papers (Archive)
Very large area, uniform TiO2@carbon composite nanofibers were easily prepared by thermal pyrolysis and oxidization of electrospun titanium(IV) isopropoxide/polyacrylonitrile (PAN) nanofibers in argon. The composite nanostructures exhibit the unique feature of having TiO2 nanocrystals encapsulated inside a porous carbon matrix. The unique orderly-bonded nanostructure, porous characteristics, and highly conductive carbon matrix favour excellent electrochemical performance of the TiO2@carbon nanofiber electrode. The TiO2@carbon hybrid nanofibers exhibited highly reversible capacity of 206 mAh g−1 up to 100 cycles at current density of 30 mA g−1 and excellent cycling stability, indicating that the composite is a promising anode candidate for Li-ion batteries.
Precipitation Behavior Of Magnetite In Oxide Scale During Cooling Of Microalloyed Low Carbon Steel, Xianglong Yu, Zhengyi Jiang, Daijun Yang, Dongbin Wei, Quan Yang
Precipitation Behavior Of Magnetite In Oxide Scale During Cooling Of Microalloyed Low Carbon Steel, Xianglong Yu, Zhengyi Jiang, Daijun Yang, Dongbin Wei, Quan Yang
Faculty of Engineering - Papers (Archive)
Precipitation behavior of magnetite particles in the thermal grown oxide scale during isothermal cooling of microalloyed low carbon steel was studied using scanning electron microscopy (SEM) and thin film X-ray. The oxide scale was generated from Gleeble 3500 Thermal-Mechanical Simulator connected with a humid air generator, to simulate 550 and 450°C isothermal treatments. Several types of magnetite precipitates were observed during different cooling processes with respect to the possible mechanisms of precipitation have been discussed. It is found that magnetite particles is as a result of pro-eutectoid precipitation from oxygen-rich wustite, and also as a product of the partial decomposition …
Enhanced Hydrogen Storage Properties Of Naalh4 Co-Catalysed With Niobium Fluoride And Single-Walled Carbon Nanotubes, Jianfeng Mao, Zaiping Guo, Hua-Kun Liu
Enhanced Hydrogen Storage Properties Of Naalh4 Co-Catalysed With Niobium Fluoride And Single-Walled Carbon Nanotubes, Jianfeng Mao, Zaiping Guo, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
The effects of single-walled carbon nanotubes (SWCNTs) as a co-catalyst with NbF5 on the dehydrogenation and hydrogenation kinetics of NaAlH4 were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, differential thermal analysis, temperature-programmed desorption, and isothermal hydrogen ab/desorption techniques. It has been revealed that there is a synergistic effect of SWCNTs and NbF5 on the de/rehydrogenation of NaAlH4, which improves the hydrogen de/absorption performance when compared to adding either SWCNTs or NbF5 alone. For example, the apparent activation energy for the first-step and the second-step dehydrogenation of the co-doped NaAlH4 sample is estimated to be 85.9 …
Power To You: Carbon Nanotube Muscles Are Going Strong, Geoffrey M. Spinks
Power To You: Carbon Nanotube Muscles Are Going Strong, Geoffrey M. Spinks
Australian Institute for Innovative Materials - Papers
Just on a year ago my colleagues and I announced our discovery that carbon nanotube yarns could be made to twist and rotate at great speeds when electrically stimulated. In this way we had created "artificial muscles" that could change their shape in response to stimulus.
Carbon Nanotube Nanoweb-Bioelectrode For Highly Selective Dopamine Sensing, Jie Zhao, Weimin Zhang, Peter Sherrell, Joselito M. Razal, Xu-Feng Huang, Andrew I. Minett, Jun Chen
Carbon Nanotube Nanoweb-Bioelectrode For Highly Selective Dopamine Sensing, Jie Zhao, Weimin Zhang, Peter Sherrell, Joselito M. Razal, Xu-Feng Huang, Andrew I. Minett, Jun Chen
Faculty of Engineering - Papers (Archive)
A highly sensitive and selective dopamine sensor was fabricated with the unique 3D carbon nanotube nanoweb (CNT-N) electrode. The as-synthesised CNT-N was modified by oxygen plasma to graft functional groups in order to increase selective electroactive sites at the CNT sidewalls. This electrode was characterized physically and electrochemically using HRSEM, Raman, FT-IR, and cyclic voltammetry (CV). Our investigations indicated that the O2-plasma treated CNT-N electrode could serve as a highly sensitive biosensor for the selective sensing of dopamine (DA, 1 μM to 20 μM) in the presence of ascorbic acid (AA, 1000 μM).
Carbon Nanotube/Graphene Nanocomposite As Efficient Counter Electrodes In Dye-Sensitized Solar Cells, Josef Velten, Attila J. Mozer, Dan Li, David Officer, G G. Wallace, Ray Baughman, A Zakhidov
Carbon Nanotube/Graphene Nanocomposite As Efficient Counter Electrodes In Dye-Sensitized Solar Cells, Josef Velten, Attila J. Mozer, Dan Li, David Officer, G G. Wallace, Ray Baughman, A Zakhidov
Faculty of Engineering - Papers (Archive)
We demonstrated the replacement of the Pt catalyst normally used in the counter electrode of a dye-sensitized solar cell (DSSC) by a nanocomposite of dry spun carbon multi-walled nanotube (MWNT) sheets with graphene flakes (Gr-F). The effectiveness of this counter electrode on the reduction of the triiodide in the iodide/triiodide redox (I−/I− 3 ) redox reaction was studied in parallel with the use of the dry spun carbon MWNT sheets alone and graphene flakes used independent of each other. This nanocomposite deposited onto fluorinated tin-oxide-coated glass showed improved catalytic behavior and power conversion efficiency (7.55%) beyond the use of the …
Biomorphic Porous Graphitic Carbon For Electromagnetic Interference Shielding, Qinglei Liu, Jiajun Gu, Wang Zhang, Yoshinari Miyamoto, Zhixin Chen, Di Zhang
Biomorphic Porous Graphitic Carbon For Electromagnetic Interference Shielding, Qinglei Liu, Jiajun Gu, Wang Zhang, Yoshinari Miyamoto, Zhixin Chen, Di Zhang
Faculty of Engineering - Papers (Archive)
Using a kind of plant biomass (coconut shell) as template and carbon precursor, we prepare biomorphic porous carbon materials for electromagnetic interference shielding application. The carbon frameworks of the porous carbon materials are modified by in situ formation of graphitic nanostructures in a catalytic graphitization process, leading to well-tailored electrical conductivity of the resultant materials. The modified porous carbon materials exhibit shielding effectiveness of 40 dB over the X-band frequency, and the shielding by absorption is as high as 91%, indicating an absorptiondominant shielding mechanism. The high absorption contribution is attributed to the coupled effects of the biomorphic porous structures …
Enhanced Electrochemical Properties Of Lifepo4 By Mo-Substitution And Graphitic Carbon-Coating Via A Facile And Fast Microwave-Assisted Solid-State Reaction, Dan Li, Yudai Huang, Neeraj Sharma, Zhixin Chen, Dianzeng Jia, Zaiping Guo
Enhanced Electrochemical Properties Of Lifepo4 By Mo-Substitution And Graphitic Carbon-Coating Via A Facile And Fast Microwave-Assisted Solid-State Reaction, Dan Li, Yudai Huang, Neeraj Sharma, Zhixin Chen, Dianzeng Jia, Zaiping Guo
Faculty of Engineering - Papers (Archive)
A composite cathode material for lithium ion battery applications, Mo-doped LiFePO4/C, is obtained through a facile and fast microwave-assisted synthesis method. Rietveld analysis of LiFePO4-based structural models using synchrotron X-ray diffraction data shows that Mo-ions substitute onto the Fe sites and displace Fe-ions to the Li sites. Supervalent Mo6+ doping can act to introduce Li ion vacancies due to the charge compensation effect and therefore facilitate lithium ion diffusion during charging/discharging. Transmission electron microscope images demonstrate that the pure and doped LiFePO4 nanoparticles were uniformly covered by an approximately 5 nm thin layer of graphitic carbon. Amorphous carbon on the …
Electrical And Thermoelectric Properties Of Single-Wall Carbon Nanotube Doped Bi2te3, Y Zhang, Xiaolin Wang, W K. Yeoh, R K. Zeng, C Zhang
Electrical And Thermoelectric Properties Of Single-Wall Carbon Nanotube Doped Bi2te3, Y Zhang, Xiaolin Wang, W K. Yeoh, R K. Zeng, C Zhang
Faculty of Engineering - Papers (Archive)
The effects of single-wall carbon nanotube (SWCNT) doping in n-type Bi2Te3 bulk samples on the electrical and thermal transport properties have been studied. Bi2Te3 samples doped with 0–5 wt. % SWCNTs were fabricated using solid state reaction and investigated using x-ray diffraction, transmission electron microscopy, and magneto transport measurements. Results show that the 0.5% doping results in the significant enhancement of the Seebeck coefficience to as high as -231.8 lV/K, giant magneto resistance of up to 110%, reduction of thermal conductivity, and change of sign of the Seebeck coefficient from n to p type depending on the doping level and …
Removal Of Trace Organic Contaminants By A Membrane Bioreactor-Granular Activated Carbon (Mbr -Gac) System, Luong N. Nguyen, Faisal I. Hai, Jinguo Kang, William E. Price, Long Nghiem
Removal Of Trace Organic Contaminants By A Membrane Bioreactor-Granular Activated Carbon (Mbr -Gac) System, Luong N. Nguyen, Faisal I. Hai, Jinguo Kang, William E. Price, Long Nghiem
Faculty of Engineering - Papers (Archive)
The removal of trace organics by a membrane bioreactor–granular activated carbon (MBR–GAC) integrated system were investigated. The results confirmed that MBR treatment can be effective for the removal of hydrophobic (logD > 3.2) and readily biodegradable trace organics. The data also highlighted the limitation of MBR in removing hydrophilic and persistent compounds (e.g. carbamazepine, diclofenac, and fenoprop) and that GAC could complement MBR very well as a post-treatment process. The MBR– GAC system showed high removal of all selected trace organics including those that are hydrophilic and persistent to biological degradation at up to 406 bed volumes (BV). However, over an …
Delivering Zero Carbon Homes In The Uk, Emma Elizabeth Heffernan, Wei Pan, Xi Liang
Delivering Zero Carbon Homes In The Uk, Emma Elizabeth Heffernan, Wei Pan, Xi Liang
Faculty of Engineering and Information Sciences - Papers: Part A
In the UK and internationally, a plethora of voluntary and mandatory energy efficiency standards for new buildings exist, with the common aim of mitigating the impact of new buildings on climate change. However, the take-up of voluntary schemes has been limited and, as a result, many governments have seen the need to introduce mandatory schemes through legislation; from 2016 all new build homes in England and Wales will be required to achieve zero carbon in regulated energy consumption. The international context of voluntary and mandatory building energy efficiency standards is examined through a review of the literature. The review is …
Recrystallisation Behaviour Of Low Carbon Steel With And Without Addition Of Chromium, Azdiar A. Gazder, Vladimir Bata, Sujoy S. Hazra, Elena V. Pereloma
Recrystallisation Behaviour Of Low Carbon Steel With And Without Addition Of Chromium, Azdiar A. Gazder, Vladimir Bata, Sujoy S. Hazra, Elena V. Pereloma
Faculty of Engineering and Information Sciences - Papers: Part A
The effects of 0.74wt% Cr addition on the recrystallisation kinetics of low carbon (LC) steel was investigated using Vickers hardness testing, optical metallography and Electron Back- Scattering Diffraction (EBSD). Compared to the unalloyed steel, Cr addition significantly delays the time for recrystallisation and increases the JMAK pre-exponential factor (k) by an order of magnitude. During initial softening, EBSD returned similar orientations for nucleated and growing grain fractions in both steels. However with longer annealing times the micro-texture of recrystallised grains differs from their earlier counterparts. Overall, the effect of fine Cr carbides on grain boundary mobility in the LC-Cr steel …
Coupling Powdered Activated Carbon (Pac) Adsorption With Membrane Bioreactor (Mbr) Treatment For Enhanced Removal Of Trace Organics, Luong Nguyen, Faisal Ibney Hai, Long Nghiem, Jinguo Kang, William Price
Coupling Powdered Activated Carbon (Pac) Adsorption With Membrane Bioreactor (Mbr) Treatment For Enhanced Removal Of Trace Organics, Luong Nguyen, Faisal Ibney Hai, Long Nghiem, Jinguo Kang, William Price
Faculty of Engineering and Information Sciences - Papers: Part A
the occurrence of trace organics such as pesticides, pharmaceutically active compounds, natural and synthetic hormones as well as varous industrial compounds in the aquatic environment is of great concern due to their potential adverse effects on human health and those of other biota. Therefore, the removal of these compounds from wastewater is an important consideration to ensure safe drinking water and better protection of the environment. In the literature, several techniques have been explored for trace organics removal, namely, conventional activated sludge, membrane bioreactors (MBRs), and absorptioin. However it has been found that neither MBR nor activated carbon on its …
The Effect Of Chromium Addition On The Strain Ageing And Recrystallisation Behaviour Of Low Carbon Steel, Elena Pereloma, V Bata, Azdiar A. Gazder
The Effect Of Chromium Addition On The Strain Ageing And Recrystallisation Behaviour Of Low Carbon Steel, Elena Pereloma, V Bata, Azdiar A. Gazder
Faculty of Engineering and Information Sciences - Papers: Part A
The strain ageing and recrystallisation behaviour of conventional low carbon A06 steel was compared with those containing varying amounts of chromium (0.26, 0.52 and 0.74 wt.%). The results show that the A06 steel undergoes four stages of strain ageing: (i) the pinning by solute atoms of dislocations generated during pre-strain, (ii) the generation of fresh dislocations from grain boundaries, (iii) the onset of precipitation and, (iv) the inhibition of dislocation generation from grain boundaries due to pinning by carbon segregation. On the other hand, the chromium containing steels only exhibit the fIrst three stages of strain ageing. An approximately twofold …
Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler
Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler
Australian Institute for Innovative Materials - Papers
Free-standingsingle-walledcarbonnanotube/SnO2 (SWCNT/SnO2) anodepaper was prepared by vacuum filtration of SWCNT/SnO2 hybrid material which was synthesized by the polyol method. From field emission scanning electron microscopy and transmission electron microscopy, the CNTs form a three-dimensional nanoporous network, in which ultra-fine SnO2 nanoparticles, which had crystallite sizes of less than 5 nm, were distributed, predominately as groups of nanoparticles on the surfaces of singlewalled CNT bundles. Electrochemical measurements demonstrated that the anodepaper with 34 wt.% SnO2 had excellent cyclic retention, with the high specific capacity of 454 mAh g−1 beyond 100 cycles at a current …
Hollow Nitrogen Containing Core/Shell Fibrous Carbon Nanomaterials As Support To Platinum Nanocatalysts And Their Tem Tomography Study, Cuifeng Zhou, Zongwen Liu, Xusheng Du, David Rg Mitchell, Yiu-Wing Mai, Yushan Yan, Simon Peter Ringer
Hollow Nitrogen Containing Core/Shell Fibrous Carbon Nanomaterials As Support To Platinum Nanocatalysts And Their Tem Tomography Study, Cuifeng Zhou, Zongwen Liu, Xusheng Du, David Rg Mitchell, Yiu-Wing Mai, Yushan Yan, Simon Peter Ringer
Australian Institute for Innovative Materials - Papers
Core/shell nanostructured carbon materials with carbon nanofiber (CNF) as the core and a nitrogen (N)-doped graphitic layer as the shell were synthesized by pyrolysis of CNF/polyaniline (CNF/PANI) composites prepared by in situ polymerization of aniline on CNFs. High-resolution transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared and Raman analyses indicated that the PANI shell was carbonized at 900 degress C. Platinum (Pt) nanoparticles were reduced by formic acid with catalyst supports. Compared to the untreated CNF/ PANI composites, the carbonized composites were proven to be better supporting materials for the Pt nanocatalysts and showed superior performance as catalyst …
Irradiation Si On Carbon Nanotube Paper As A Flexible Anode Material For Lithium-Ion Batteries, Shulei Chou, Mihail Ionescu, Jia-Zhao Wang, Brad Winton, Hua-Kun Liu
Irradiation Si On Carbon Nanotube Paper As A Flexible Anode Material For Lithium-Ion Batteries, Shulei Chou, Mihail Ionescu, Jia-Zhao Wang, Brad Winton, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
Silicon single walled carbon nanotube composite paper was modified by low energy ion implantation using 5i to obtain a flexible composite paper. Raman and FE-SEM results show that structure of SWCNT could be destroyed by the implantation. Electrochemical measurements display that the implanted SI can improve the specific capacity and the reversible capacity of CNT paper. After 50 cycles, the specific capacity of 5Hmplanted CNT paper is 30 per cent higher than the pristine CNT.