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Mitigating The Shrink-Swell Capacities Of The Yazoo Clay Through Application Of Lime And Biochar, Austin Alan Brister

Theses and Dissertations

Shrinking and swelling in Yazoo Clay is a cause of concern for construction projects in Mississippi. This thesis investigated the effects of adding lime and Douglas Fir biochar on the shrinking and swelling capabilities of Yazoo Clay. Samples of Yazoo Clay were mixed with the additives in defined ratios and subjected to the free swell test and the COLE(rod) test. Biochar addition reduced the COLE(rod) of the samples a large amount, while increasing the swelling potential of the clay samples. The addition of lime slightly reduced both the shrinking and swelling potentials of the samples. The mineralogical variability of Yazoo …

Grapefruit Peel Biochar Applications For Immobilizing Copper And Lead In Soil, Michael Alfredo Navarro

Theses and Dissertations

This study investigated the efficacy of grapefruit peel (GP) derived biochar materials (two pyrolysis temperatures 450°C and 800°C) as a potential adsorbent to immobilize heavy metal (copper and lead) in a local sandy loam clay soil. A batch adsorption test with heavy metal concentrations at 50 mg L-1, and 100 mg L-1 revealed that soil itself had the highest immobilization percentage compared to the GP biochars. A soil column experiment was conducted to determine how much the GP biochar samples and the tested soil will exhibit adsorptive characteristics for heavy metals when 50 ml of 50 mg L-1 copper or …

Enrofloxacin And Sulfamethoxazole Sorption On Carbonized Leonardite: Kinetics, Isotherms, Influential Effects, And Antibacterial Activity Toward S. Aureus Atcc 25923, Chanat Chokejaroenrat, Chainarong Sakulthaew, Khomson Satchasataporn, Daniel D. Snow, Tarik E. Ali, Mohammed A. Assiri, Apichon Watcharenwong, Saksit Imman, Nopparat Suriyachai, Torpong Kreetachat

Nebraska Water Center: Faculty Publications

Excessive antibiotic use in veterinary applications has resulted in water contamination and potentially poses a serious threat to aquatic environments and human health. The objective of the current study was to quantify carbonized leonardite (cLND) adsorption capabilities to remove sulfamethoxazole (SMX)- and enrofloxacin (ENR)-contaminated water and to determine the microbial activity of ENR residuals on cLND following adsorption. The cLND samples prepared at 450^oC and 850^oC (cLND450 and cLND550, respectively) were evaluated for structural and physical characteristics and adsorption capabilities based on adsorption kinetics and isotherm studies. The low pyrolysis temperature of cLND resulted in a …

Iron And Magnesium Impregnation Of Avocado Seed Biochar For Aqueous Phosphate Removal, James Ji Hoon Kang, Jason Parsons, Sampath Gunukula, Dat T. Tran

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

There has been increasing interest in using biochar for nutrient removal from water, and its application for anionic nutrient removal such as in phosphate (PO₄³⁻) necessitates surface modifications of raw biochar. This study produced avocado seed biochar (AB), impregnated Fe- or Mg-(hydr)oxide onto biochar (post-pyrolysis), and tested their performance for aqueous phosphate removal. The Fe- or Mg-loaded biochar was prepared in either high (1:8 of biochar to metal salt in terms of mass ratio) or low (1:2) loading rates via the co-precipitation method. A total of 5 biochar materials (unmodified AB, AB + High Fe, AB …

Biomass Residues Improve Soil Chemical And Biological Properties Reestablishing Native Species In An Exposed Subsoil In Brazilian Cerrado, Thaís Soto Boni, Engil Isadora Pujol Pereira, Adriana Avelino Santos, Ana Maria Rodrigues Cassiolato, Kátia Luciene Maltoni

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Revegetation of exposed sub-soil, while a desirable strategy in the recovery processes, often fails due to extreme soil chemical properties, such as low organic matter and pH levels inhospitable to biological activities such as nutrients cycling and plant establishment. This is the case for approximately 800 ha of the Cerrado biome in Brazil, where erecting the embankment of a hydroelectric dam in the 1960’s stripped vegetation, soil, and subsoil layers thereby distorting the soil properties. This work evaluates the effectiveness of restoration management (RM) treatments, to restore the soil quality, including biological activity and chemical attributes. In a factorial scheme, …

Evaluating The Biogeochemical Effects Of Enhanced Rock Weathering At Lawrence University, Katie Mahorney

Lawrence University Honors Projects

On geologic timescales, the weathering of silicate rocks is among the most powerful negative feedbacks controlling atmospheric CO₂. However, this process is too slow to meaningfully impact our current climate crisis. Enhanced Rock Weathering (ERW) is one of the most promising carbon capture strategies to remove anthropogenic carbon from the atmosphere. Models suggest that by crushing silicate rocks such as basalt to increase surface area, the process of rock weathering can be accelerated to sequester enough carbon to be significant on human timescales. At Lawrence University, ERW is being investigated to (1) field test the efficacy of the …

Effects Of Biochar Production Methods And Biomass Types On Lead Removal From Aqueous Solution, Paola Granados, Sergio Mireles, Engil Isadora Pujol Pereira, Chu-Lin Cheng, James Jihoon Kang

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Biochar has proven its potential in removing heavy metal ions from water. The objective of this study was to evaluate locally obtained biomass feedstocks for biochar production and their efficiency as a sorbent for aqueous lead (Pb²⁺) removal. The biomass feedstocks consisted of avocado seed, avocado peel, grapefruit peel, and brown seaweed, which represent agricultural and marine biomasses. The biochar materials were produced in two different methods: (1) a laboratory tube furnace at 300 °C and (2) a Do-It-Yourself (DIY) biochar maker, “BioCharlie Log”. The biochars were characterized for selected physicochemical properties, and batch adsorption tests with 10 …

Competitive Sorption And Transport Of Heavy Metals In Soil And Mn Oxide-Coated Sand, Joshua Tyler Padilla

LSU Doctoral Dissertations

This study investigated the competitive sorption of Ni, Pb, and Zn as well as synergistic interactions between Ni and phosphate (P) in soils and Mn oxide-coated sand. During stirred-flow experiments, the sorption of heavy metal cations by Olivier soil was mutually reduced when applied simultaneously. When applied consecutively, the cation of higher affinity was able to displace the cation of lower affinity from the soil surface, however, no evidence for the reverse case was observed. A novel general exchange kinetics model was able to correctly describe such displacement. Competition between Ni and Zn mutually increased mobility in Olivier and Windsor …

Effect Of Nitrogen Fertilization On Central Tendency And Spatial Heterogeneity Of Soil Moisture, Ph And Dissolved Organic Carbon And Nitrogen In Two Bioenergy Croplands, Xuehan Wang, Siyang Jian, Lahiru Gamage, Jianwei Li

Agricultural and Environmental Sciences Faculty Research

Background

Soil moisture, pH, dissolved organic carbon and nitrogen (DOC, DON) are important soil biogeochemical properties in switchgrass (SG) and gamagrass (GG) croplands. Yet their spatiotemporal patterns under nitrogen (N) fertilization have not been studied.

Aims

The objective of this study is to investigate the main and interactive effects of N fertilization and bioenergy crop type on central tendencies and spatial heterogeneity of soil moisture, pH, DOC and DON.

Methods

Based on a 3-year long fertilization experiment in Middle Tennessee, USA, 288 samples of top horizon soils (0–15 cm) under three fertilization treatments in SG and GG croplands were collected. …

Evaluating Split Timing Fertilizer Applications For Improving Bread Baking Quality Of Soft Red Winter Wheat In Kentucky, Ammar Al Zubade, Krista Jacobsen, Tim Phillips, Mark Williams, David Van Sanford

Plant and Soil Sciences Graduate Research

There is growing interest among farmers to locally produce high protein and strong gluten wheat that is suitable for bread making and meet the demand of local artisanal bakers in Kentucky. The warm and humid weather in southeast region is ideal for soft red winter wheat (SRW) production which characterized by low protein content. The technique of splitting nitrogen (N) fertilization according to the growth stages has been suggested to improve protein content and its composition. This study evaluated the effect of split N application on yield and baking quality traits of two SRW wheat cultivars grown in the eastern …

How Much Margin Is Left For Degrading Agricultural Soils? The Coming Soil Crises, Maheteme Gebremedhin, Mark S. Coyne, Karamat R. Sistani

Plant and Soil Sciences Faculty Publications

Agricultural soils are in peril. Multiple lines of observational and empirical evidence suggest that we are losing the world’s fertile soils at an alarming rate, worsening the on-going global food crisis. It is increasingly clear that the risk of soil crises driven by erratic precipitation, warming air, and farming mismanagement is coming sooner rather than later. At this critical time, society cannot avoid looking for ways to curb soil crises. We argue that now is the right time for science-based mitigation strategies and new insights to protect soils. We offer four research priority areas that society needs to address. Arresting …

Biochar: Properties And Potential Benefits For Agricultural Soil In Rwanda, Andromede Uwase

Honors Theses

Physical and chemical soil degradation is becoming a major challenge for agricultural productivity in Rwanda, which is the most important part of the country’s economy. The wide spreading soil degradation in Rwanda is mainly a result of naturally poor soils coupled with unsustainable soil management leading to, for example, accelerated soil erosion, acidification, nutrient loss, compaction, and to decreasing yields. Biochar, as an end product of pyrolysis of biomass in the absence of oxygen, has been proposed as a soil amendment in remediation strategies because of its positive effects on soil productivity relevant parameters such as soil pH, structure, nutrient …

Northern Great Plains Saline Sodic Soil Development, Classification, Remediation, And Management., Shaina Westhoff

Electronic Theses and Dissertations

Soil salinity and sodicity are issues of growing concern in the United States (U.S.) and globally. Knowledge gaps for glaciated, dryland salt-affected soils exist because much original salinity and sodicity research focused on irrigated systems. Land managers are being asked to produce food, feed, fiber, and fuel for an expanding global population. The number of land managers and crop advisors who are affected by these soils is increasing. Addressing salinity and sodicity knowledge gaps will be critical for their success. Salinity and sodicity have been impeding crop productivity since the advent of cultivation. Saline and sodic soils form via multiple …

Soil Hydro-Physical Properties, Computed Tomography Measured Pore Parameters, And Soil Health Indicators As Influenced By Tillage And Crop Rotation Systems, Goutham Thotakuri

Electronic Theses and Dissertations

Long-term tillage and crop rotation systems are important agricultural management practices as these can have direct impact on the soil’s key properties. The objectives of this study were to (ⅰ) quantify the soil pore characteristics under long-term tillage and crop rotation using X-ray computed tomography (XCT) and to assess the relationships between XCT-measured pore parameters and soil hydro-physical properties; and (ⅱ) evaluate the impacts of long-term tillage and crop rotation on select soil health indicators. The objective (ⅰ) was carried out at Haskell Agricultural Laboratory (HAL), Concord, NE; and objective (ⅰi) was carried out at South Central Agricultural Laboratory (SCAL), …