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Stratigraphic Controls On Diagenetic Pathways In The St. Peter Sandstone, Michigan Basin, Stephen A. Zdan

Masters Theses

The Middle Ordovician St. Peter Sandstone in the Michigan Basin is a target for hydrocarbon exploration/production, and carbon sequestration and geologic storage. The St. Peter is predominantly a marine sandstone with four dominant lithofacies. The uppermost facies contains zones of porosity and good reservoir quality. Because of the mostly uniform detrital composition, diagenesis must play a leading role in reservoir quality development. This study tests stratigraphic controls on diagenesis and reservoir quality development. The distribution of diagenetic regimes is believed to result from depositional setting and related geologic processes, including variations in sediment accumulation rate. Early carbonate cements preserve pre-compaction …

Utilizing Persistent Scatterer Interferometry To Investigate The Nature And Factors Controlling Nile Delta Subsidence, El Hachemi Yousef Bouali

Masters Theses

The Nile Delta in Egypt is being threatened by two continuous and relatively slow hazards: encroachment from the Mediterranean Sea as sea levels rise and land subsidence of the delta itself. The magnitude of sea level rise has been actively monitored, while the subsidence of the Nile Delta has not been adequately quantified spatially and temporally. Instead, all previous studies have either focused on measuring average Holocene subsidence rates or modern subsidence rates on local scales (point- or city-scale).

The overall study objective is three-fold: (1) to measure and map the spatial variations in subsidence rates across the entire Nile …

Origin Of High Levels Of Ammonium In Groundwater, Ottawa County, Michigan, Derrick Lingle

Masters Theses

Groundwater from wells located in and around Hemlock Crossing Park in Ottawa County, Michigan has elevated levels of ammonium. High ammonium concentrations in potable water wells are a common indicator of anthropogenic impact, such as landfill leachate or agricultural activity. Ammonium can also occur in groundwater through the decay of natural organic material. Along with the retrieval of a complete glacial sediment core via rotasonic drilling, numerous chemical and isotopic parameters were used to determine the source of ammonium in the impacted aquifer.

Buried organic material, deposited during the Athens subepisode interglacial period, is in contact with groundwater containing elevated …

Using Soil Organic Matter As An Iron Chelate To Enhance The Efficiency Of Modified Fenton Oxidition Of Diesel Fuel In Arctic Soils, Mary K. Sherwood

Masters Theses

Laboratory experiments were conducted to investigate the use of modified fenton chemistry on the treatment of three soils from the Canadian arctic, all with abundant soil organic matter, iron and manganese oxides, and diesel fuel contamination. The purpose of these studies was to (I) to assess modified fenton chemistry as a treatment option for petroleum-contaminated arctic soils, and (2) to evaluate the impact of soil organic matter on the modified fenton treatment of soils. Modified fenton treatment was compared for reactions in which ethylenediaminetetraacetate was added as a chelate vs. reactions in which the native soil organic matter was the …

Activated Carbon Preconditioning To Reduce Contaminant Leaching In Cement-Based Stabilization Of Soils, Renee Elizabeth Crane

Masters Theses

Powdered activated carbon (PAC) is often added with cement to enhance the stabilization and solidification (S/S) of materials contaminated with organic compounds. Adsorption of organic contaminants onto PAC can reduce leaching of organic contaminants. Simultaneous addition of PAC and cement reduces soil handling costs, but cement hydration reactions coat PAC with Ca(OH)2 before contaminants can be adsorbed onto PAC. Laboratory studies were done on four aged, contaminated soils from manufactured gas plant sites to compare the performance of S/S treatment with simultaneous addition of PAC and cement vs. cement addition after preconditioning with PAC to enhance contaminant adsorption. Performance was …

Surface Complexation Modeling Of Cr(Vi) Absorption On Mineral Assemblages, Ann M. Gilchrist

Masters Theses

Hexavalent chromium (Cr(VI)) is a waste product of many anthropogenic processes. Because it is highly mobile, the improper disposal of Cr(VI) has caused widespread contamination. Because reduction and adsorption reactions may reduce the bioavailability and mobility of Cr(VI) in environmental systems, a better understanding of Cr(VI) adsorption behavior will improve remediation efforts.

Subsurfaces and soils are heterogeneous, however most studies focus on single sorbate/sorbent interactions to develop surface complexation models (SCM) for prediction of heavy metal adsorption. Theoretically, combining the SCMsdeveloped for single sorbate/sorbent systems should yield accurate predictions of adsorption in more complex systems (i.e., the component additivity approach …

The Geology Of The South Antelope Pass Area Of The Southern Peloncillo Mountains, Hidalgo County, New Mexico, John A. Yellich

Masters Theses

Volcanic activity during the middle and late Tertiary has been recorded in the mountain ranges of the southwestern United States and northern Mexico and the two provinces of prominent volcanic activity, the Sierra Madre Occidental and the Mogollon Plateau, dominantly rhyolitic in composition, are connected by the Peloncillo Range. The predominant rock chemistry of the south Antelope Pass area is “rhyolitic”; however, lava rock types dominate over welded tuff rock types of the two provinces. There is a limited pre-Tertiary rock record of limestones and sandstones in the northeastern part of the study area. The rest of the study area …

Development And Evaluation Of An Inquiry-Based Unit For Teaching About Paleoclimate And Climate Change, Steven Barone

Masters Theses

The purpose of this action research study is to develop and evaluate a sequence of four lessons for an introductory earth science course taken by future elementary teachers. Action research is a reflective process of data collection and analysis used by teachers to improve their classroom practice. This study’s goal is to produce a series of lessons that align with the course philosophy of student-driven learning through guided-inquiry and are effective at improving students’ understanding of climate change.

Three data sets were used to evaluate the lessons: 1) student knowledge gains on an objective pre- and post-test, 2) students’ self-reported …

Adsorption Of Hexavalent Chromium On Hydrous Manganese Oxide, Andrew K. Macleod

Masters Theses

Hexavalent chromium is a very common contaminant most often associated with industrial processes, it is quite mobile in the subsurface and a better understanding of its mobility and interactions with soil constituents will help ongoing remediation efforts.

Hydrous manganese oxides (HMO) are a very common soil constituent and thus would be likely to interact with Cr(VI) in contaminated shallow subsurface environments. The goal of this study is to develop a working model that can improve predictions of Cr(VI) mobility in natural systems. A diffuse double layer surface complexation model (DLM) was developed by deriving reaction stoichiometries and stability constants for …

Analysis Of Depositional Facies And Geological Controls On Reservoir Quality In Lower-Middle Devonian Sylvania Sandstone, Midland County, Michigan, Katherine A. Pollard

Masters Theses

The early-Middle Devonian Sylvania “Sandstone” is considered a target for potential CO₂ geosequestration. In order to develop geostatic models for CO₂ injection simulations, controls on reservoir properties must be addressed. The three objectives of this study involve: 1) develop an overview of depositional lithofacies and their vertical stacking relationships, 2) determine fluid sources and controls of diagenesis (dolomitization and silicification), and 3) examine geological controls on the distribution and character of reservoir facies.

The grossly transgressive Sylvania-Bois Blanc interval is a complex lithologic assemblage. Sylvania “Sandstone” strata transition from high energy, subtidal to lower-intertidal mixed carbonate-siliciclastic facies to …

Late Mississippian (Chesterian) Through Early Pennsylvanian (Atokan) Strata, Michigan Basin, U.S.A., Shannon M. Towne

Masters Theses

Over 2,000 linear feet of core material was analyzed to evaluate the stratigraphy and basin evolution of Carboniferous strata in the Michigan basin. Rock units were evaluated on the basis of lithofacies type, contact relationships, and existing regional geologic interpretations. The recovery of three distinct pollen and spore assemblages from core confirms the timing of deposition during the Late Mississippian Chesterian and Early-Middle Pennsylvanian Morrowan and Atokan regional stages within the Michigan basin.

The deposition of a marine carbonate succession with significant interstratified quartz sandstone occurred during the Chesterian regional stage. The Bayport interval (Bayport Limestone) is composed of seven …

Integrating Depositional Facies And Sequence Stratigraphy In Characterizing Unconventional Reservoirs: Eagle Ford Shale, South Texas, Seth Jordan Workman

Masters Theses

The Mid-to-Late Cretaceous Eagle Ford Shale of South Texas is a mixed siliciclastic/carbonate, unconventional resource play with considerable oil and natural gas. Characterization of Eagle Ford reservoir quality and potential is made difficult by complex, small-scale heterogeneities.

The limited availability of subsurface data constrains previous subsurface Eagle Ford investigations. As a result, the internal variability of depositional facies and reservoir attributes remain poorly understood for these Eagle Ford rocks.

This investigation incorporates a representative group of four Eagle Ford cores, and core data, from within the current play area in order to: 1) determine facies successions, 2) establish a hierarchal …