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Isotopic Tracers As Evidence Of Denitrification In The Karlsruhe Aquifer, Eben J. Spencer

Theses and Dissertations

The Karlsruhe Aquifer of north-central North Dakota has experienced considerable nitrate contamination sparking an investigation by the North Dakota State Water Commission. Certain portions of the aquifer have experienced nitrate-N concentrations of up to seven times the drinking water standard. Although contamination is evident it is possible the NO₃¯ is naturally being eliminated by denitrification, whereby bacteria reduce NO₃¯ to nitrogen gas. Evidence of denitrification may be illustrated by accelerated reduction of NO₃¯ relative to the conservative tracer Cl¯ coupled with an increase in the heavy isotopes of 15N and 18O within the NO₃¯ ion. Such an increase is not …