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A Model For Palladium Catalyzed Destruction Of Chlorinated Ethenes In Contaminated Groundwater, Christopher M. Stoppel Mar 2001

A Model For Palladium Catalyzed Destruction Of Chlorinated Ethenes In Contaminated Groundwater, Christopher M. Stoppel

Theses and Dissertations

Groundwater contamination by chlorinated ethenes is a widespread environmental problem. Conventional remediation technologies have shortcomings that have prompted further research into the development of novel treatment technologies. A palladium/ alumina catalyst in the presence of dissolved molecular hydrogen (referred to hereafter as a PD/H2 system) has been demonstrated to rapidly destroy chlorinated ethene contaminated groundwater. First-order kinetics have been used to model chlorinated ethene destruction in a PD/H2 reactor. However, catalyst deactivation and regeneration are important processes that also need to be modeled in order to better understand their effect on treatment efficiency. This study presents a model …


Modeling Biodegradation Of Chlorinated Groundwater Contaminants Under Iron-Reducing Conditions Of A Constructed Wetland: A System Dynamics Approach, Max E. Johnson Mar 2001

Modeling Biodegradation Of Chlorinated Groundwater Contaminants Under Iron-Reducing Conditions Of A Constructed Wetland: A System Dynamics Approach, Max E. Johnson

Theses and Dissertations

The purpose of this study is to determine and explore the fundamental processes associated with biodegradation of chlorinated ethenes in iron-reducing conditions of a constructed wetland and to evaluate the impacts of changing conditions (both natural and engineer-controlled) on the system. The modeler uses a system dynamics approach to construct a model that represents behavior in the iron-reducing environment. The model incorporates hematite, a form of oxidized iron (Fe3+), as the electron acceptor in microbial biodegradation in the system. Vinyl chloride, cis-dichloroethene, and trans-dichloroethene are known to anaerobically degrade to carbon dioxide in the presence of oxidized iron. …


A System Dynamics Approach To Modeling Temperature Effects In Solid Waste, David A. Jokinen Mar 2001

A System Dynamics Approach To Modeling Temperature Effects In Solid Waste, David A. Jokinen

Theses and Dissertations

The amount of municipal solid waste discarded to landfills is continually increasing even with extensive recycling efforts. The need to understand the behavior of waste in landfills is increased due to the decreasing number of active landfills, communities' concern to the potential hazards associated with landfills, and companies or installations with landfills on-site need to understand landfill behavior comply with new legislation concerning design and detecting hazardous material movement of-site. This research is focused on increasing the understanding of landfill behavior by examining the effects of temperature in a landfill system. A system dynamics approach was used in this research …


Chromate Content Bias As A Function Of Particle Size In Aircraft Primer Paint Overspray, David B. Novy Mar 2001

Chromate Content Bias As A Function Of Particle Size In Aircraft Primer Paint Overspray, David B. Novy

Theses and Dissertations

Spray painting operations using chromate-containing primer paints produce particles which may expose workers to strontium chromate. Chromate contains hexavalent chromium (Cr(VI)) which is a confirmed human carcinogen. It is suspected that the smaller particles contain disproportionately less Cr(VI) than larger particles. In order to determine if a bias in chromate content exists, paint particles were collected and separated based on particle size and the Cr(VI) concentration was determined. Aviation primer paint from the DeSoto and Deft companies was sprayed in a booth and seven-stage cascade impactors were used to separate particles.


Determining The Value Of Groundwater Contamination Source Removal: A Methodology, Benjamin C. Recker Mar 2001

Determining The Value Of Groundwater Contamination Source Removal: A Methodology, Benjamin C. Recker

Theses and Dissertations

Subsurface contamination by industrial chemicals is one of the most prevalent and costly environmental problems facing the United States government. This contamination problem must be managed to protect human health and the environment. Two basic strategies are used to deal with subsurface contamination: source removal and contaminant containment. While much cost and performance data are available for individual technologies associated with each of these strategies, there have been very few studies that have examined the benefits of implementing source removal technologies in order to reduce contaminant containment (and hopefully total) costs. This study examines the tradeoff between extent of source …


Decision Analysis Methodology To Evaluate Integrated Solid Waste Management Alternatives For A Remote Alaskan Air Station, Mark J. Shoviak Mar 2001

Decision Analysis Methodology To Evaluate Integrated Solid Waste Management Alternatives For A Remote Alaskan Air Station, Mark J. Shoviak

Theses and Dissertations

Eareckson Air Station (AS), a remote U.S. Air Force installation, faces the complex decision of selecting a new municipal solid waste (MSW) management strategy to replace its current non-compliant system. This research effort applies value-focused thinking and multiattribute preference theory to decision analysis techniques to produce a multiple-objective decision analysis model that captures all of the site's MSW goals, objectives, and concerns in order to facilitate the evaluation of MSW management strategies available. The model ranks 40 specific MSW management alternatives, which were developed in accordance with the decision-maker's assumptions and constraints, based on how well they meet Eareckson's overall …


Quantitative Validation Of A Model Of Chlorinated Ethene Natural Attenuation, Harold C. Young Mar 2001

Quantitative Validation Of A Model Of Chlorinated Ethene Natural Attenuation, Harold C. Young

Theses and Dissertations

Chlorinated ethenes are among the most prevalent groundwater contaminants at hazardous waste sites nationwide. In an attempt to manage the risks posed by these contaminants, while controlling costs, monitored natural attenuation (MNA) is being considered as a remediation strategy at many sites. MNA relies on naturally occurring physical, chemical, and biological processes in the subsurface to reduce the risk posed by the contamination. The implementation of MNA, however, requires a detailed understanding of these processes, and how they impact contamination at a particular site. One way to gain this understanding is through contaminant fate and transport modeling. In this study, …


Modeling Chlorinated Ethene Removal In The Methanogenic Zone Of Constructed Wetlands: A System Dynamics Approach, Randall L. Roberts Mar 2001

Modeling Chlorinated Ethene Removal In The Methanogenic Zone Of Constructed Wetlands: A System Dynamics Approach, Randall L. Roberts

Theses and Dissertations

The purpose of this study is to gain understanding of the dynamics of the processes that degrade Perchloroethene (PCE) to ethene, within the confines of the methanogenic zone of a constructed wetland. A system dynamics modeling approach is used. This model is focused on determining conditions that will enhance contaminant degradation. The chemical and biological processes within the methanogenic zone of a wetland system are extremely complex and dynamic processes. The model is broken up into three simultaneous processes: dechlorination, methanogenesis, and fermentation. The system behavior of the methanogenic zone can be adequately described by the classical formulations of representative …


An Analysis Of Civil Engineer Officer Contingency Training, Rusty J. Vaira Mar 2001

An Analysis Of Civil Engineer Officer Contingency Training, Rusty J. Vaira

Theses and Dissertations

The primary objective of this research was to investigate the current overall civil engineer officer contingency training program and determine if civil engineer officers think it is adequately preparing them to perform in a contingency environment. In accomplishing this objective, this research explored the perceptions that officers have about the contingency training that is available through three primary training programs (Home Station Training, Silver Flag training, and Civil Engineer and Services School training). The overall intent of the author was to gauge how the officers feel about their contingency training and offer some suggestions on how to improve the training. …


Differences In Civil Engineer Perceptions Of Change Based On Prior Training And Experience, Steven W. Lo Mar 2001

Differences In Civil Engineer Perceptions Of Change Based On Prior Training And Experience, Steven W. Lo

Theses and Dissertations

The Department of Defense (DoD) and the United States Air Force (USAF) have moved toward an aggressive stance to competitively source and privatize (CS&P) support functions as much as possible. This move is intended to shrink support costs and redirect the savings to force and equipment modernization. In addition, the USAF hopes to realize improved services, gain access to technology, share risks with contractors, and allow its forces to focus on the core competencies. In order to implement OS&P, the USAF communicates information through two major pathways, passive and active. Passive communication is similar to traditional classroom learning where information …


Life-Cycle Cost Analysis, Ahmed Mohamed Ahmed Ibrahim Jan 2001

Life-Cycle Cost Analysis, Ahmed Mohamed Ahmed Ibrahim

Theses and Dissertations

The construction industry can be considered as an indication of economical status of any country.