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Redutive Dehalogenation Of Chlorinated Alkanes By Novel Bacteria At The Petroprocessor Of Louisiana Inc. Superfund Site, Jun Yan Jan 2008

Redutive Dehalogenation Of Chlorinated Alkanes By Novel Bacteria At The Petroprocessor Of Louisiana Inc. Superfund Site, Jun Yan

LSU Doctoral Dissertations

A reductively dehalogenating enrichment culture was established using chloroalkane-contaminated groundwater from the PetroProcessors of Louisiana, Inc. (PPI) Superfund site. Two novel, strictly anaerobic bacterial strains, designated as BL-DC-8 and BL-DC-9, were isolated from the enrichment culture. These strains represent the first bacteria known to anaerobically dehalogenate 1,2,3-trichloropropane, the degradation pathway of which was determined. Both strains could be cultured in completely defined basal medium and were also able to dehalogenate a variety of other vicinally chlorinated alkanes including 1,1,2,2-tetrachloroethane, 1,1,2-trichloroethane, 1,2-dichloroethane, and 1,2-dichloropropane via dichloroelimination reactions. Chlorinated alkanes containing only a single chlorine substituent (1-chloropropane, 2-chloropropane), chlorinated alkenes (tetrachloroethene, trichloroethene, …


Lattice Boltzmann Modeling For Mass Transport Equations In Porous Media, Borja Servan Camas Jan 2008

Lattice Boltzmann Modeling For Mass Transport Equations In Porous Media, Borja Servan Camas

LSU Doctoral Dissertations

The aim of this dissertation is to extend the lattice Boltzmann method (LBM) to cope with parameter heterogeneity and anisotropy in mass transport equations in porous media, as well as investigating the stability and accuracy. Although the LBM is a well known and effective numerical method to solve fluid flows, LBM has not been extensively applied to mass transport equations in porous medium flow yet, and only a few works can be found on improving LBM to cope with mass transport equations other than the diffusion and advection-diffusion equations. One of the reasons why LBM has not been extensively used …


Bayesian Model Averaging On Hydraulic Conductivity Estimation And Groundwater Head Prediction, Xiaobao Li Jan 2008

Bayesian Model Averaging On Hydraulic Conductivity Estimation And Groundwater Head Prediction, Xiaobao Li

LSU Doctoral Dissertations

Characterization of aquifer heterogeneity is inherently difficult because of the insufficiency of data, the inflexibility of parameterization methods, and non-uniqueness of parameterization methods. Groundwater predictions are greatly affected by multiple interpretations of aquifer properties and the uncertainties of model parameters. This study introduces a Bayesian model averaging (BMA) method along with multiple generalized parameterization (GP) methods to identify hydraulic conductivity and along with multiple simulation models to predict groundwater head and quantify the prediction uncertainty. Two major issues about BMA are discussed. The first problem is with using Occam’s window in usual BMA applications. Occam’s window only accepts models in …


Elasto-Plastic And Damage Modeling Of Reinforced Concrete, Ziad N. Taqieddin Jan 2008

Elasto-Plastic And Damage Modeling Of Reinforced Concrete, Ziad N. Taqieddin

LSU Doctoral Dissertations

Modeling the mechanical behavior of Reinforced Concrete (RC) is still one of the most difficult challenges in the field of structural engineering. The Nonlinear Finite Element Analysis (NFEA) and modeling of the behavior of RC members are the primary goals of this study. The macroscopic components of RC, Concrete material and reinforcing steel, are represented herein by separate material models. These material models are combined together using a model that describes the global effect of interaction between reinforcing steel and concrete in order to simulate the behavior of the composite RC material. A thermodynamically consistent constitutive model for concrete that …


Development Of An Ultrasonic Nde&T Tool For Yield Detection In Steel Structures, Yilmaz Bingol Jan 2008

Development Of An Ultrasonic Nde&T Tool For Yield Detection In Steel Structures, Yilmaz Bingol

LSU Doctoral Dissertations

Nondestructive Evaluation and Testing (NDE&T) is a commonly used and rapidly growing field that offers successful solutions for health assessment of structures. NDE&T methods have gained increasing attention in the last few decades especially with the contribution of the advancements in computer and instrumentation technologies. The applications of numerous NDE&T methods in civil engineering mostly focus on material characterization and defect detection. Techniques for nondestructively identifying the stress state in materials, on the other hand, mostly rely on the Theory of Acoustoelasticity. However, the sensitivity and the accuracy of acoustoelasticity are affected by several factors such as the microstructure of …


Fate And Transport Of Microorganisms In Coastal Subsurface-Experiment And Modeling, Haibo Cao Jan 2008

Fate And Transport Of Microorganisms In Coastal Subsurface-Experiment And Modeling, Haibo Cao

LSU Doctoral Dissertations

The objective of this dissertation was to investigate the fate and transport of microorganisms in coastal subsurface. Two topics were studied: (1) evaluation of the performance of the Marshland Upwelling System (MUS) in removing fecal bacteria and the background recovery after it is shut down; (2) Investigation of the effects of salinity and soluble organic matter (SOM) on sorption of MS-2 and development of a model to describe the sorption and transport process. The MUS showed effective performance in removing fecal bacteria during its 32 month operation period at Bayou Segnette Site. The removal efficiency was increased with its operation …


Dynamic Shear Bands In Metals Under High Strain Rates, Amin Hisham Almasri Jan 2008

Dynamic Shear Bands In Metals Under High Strain Rates, Amin Hisham Almasri

LSU Doctoral Dissertations

Adiabatic shear bands have been observed for a long time to occur under different conditions in many applications. Analysis of these localizations highly depends on the selection of the constitutive model. Hence, two constitutive models that take temperature and strain rate effect into account are proposed. The first model is a physically based model that depends on basic physical quantities, such as dislocation densities, Burgers vector, and activation energy. The second model is a simple empirical power model with a softening term. The empirical constitutive law is seen to be more successful in capturing the mechanical behavior of steel alloy …


Optimization Of Treatment Of Chlorinated Volatile Organic Compound Mixtures In Constructed Wetlands: Vegetation And Substrate Effects, Stephen Emmanuel Mbuligwe Jan 2008

Optimization Of Treatment Of Chlorinated Volatile Organic Compound Mixtures In Constructed Wetlands: Vegetation And Substrate Effects, Stephen Emmanuel Mbuligwe

LSU Doctoral Dissertations

Microcosm and mesocosm scale experiments were carried out to investigate the effects of vegetation and substrates on the performance of engineered wetland systems (EWSs) meant to treat mixtures of volatile organic compounds (cVOCs). The experiments were conducted with a view to optimizing contributions of these wetland components. Phragmites communis and Typha latifolia, the commonest wetland plant species, were compared in mesocosm scale EWSs. Eight common wetland plant species were compared using microcosm experiments based on the potential of their rootmatter to enhance treatment of cVOC mixtures. Twelve common wetland plants were similarly compared but on the basis of their aboveground …