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Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia Oct 2023

Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia

Department of Civil and Environmental Engineering: Faculty Publications

This work innovatively explores the bio-methanol production process, conducts comprehensive analyses, develops statistical models, and optimizes operational conditions, contributing valuable insights to the field of sustainable energy production from biomass. Accordingly, bio-methanol production from biomass through gasification route was investigated and simulated using Aspen Plus software. The effects of operational parameters on energy duty of gasification reactor and the methanol production rate in syngas to methanol reactor were investigated. The parameters affecting the process performance including temperature, pressure, and steam/feed ratio were examined using the response surface methodology (RSM) by central composite design (CCD) technique. Analysis of variance (ANOVA) was …


Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia Oct 2023

Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia

Department of Civil and Environmental Engineering: Faculty Publications

This work innovatively explores the bio-methanol production process, conducts comprehensive analyses, develops statistical models, and optimizes operational conditions, contributing valuable insights to the field of sustainable energy production from biomass. Accordingly, bio-methanol production from biomass through gasification route was investigated and simulated using Aspen Plus software. The effects of operational parameters on energy duty of gasification reactor and the methanol production rate in syngas to methanol reactor were investigated. The parameters affecting the process performance including temperature, pressure, and steam/feed ratio were examined using the response surface methodology (RSM) by central composite design (CCD) technique. Analysis of variance (ANOVA) was …


Potential Bioavailability Of Representative Pyrogenic Organic Matter Compounds In Comparison To Natural Dissolved Organic Matter Pools, Emily B. Graham, Hyun-Seob Song, Samantha Grieger, Vanessa A. Garayburu-Caruso, James C. Stegen, Kevin D. Bladon, Allison N. Myers-Pigg Apr 2023

Potential Bioavailability Of Representative Pyrogenic Organic Matter Compounds In Comparison To Natural Dissolved Organic Matter Pools, Emily B. Graham, Hyun-Seob Song, Samantha Grieger, Vanessa A. Garayburu-Caruso, James C. Stegen, Kevin D. Bladon, Allison N. Myers-Pigg

Biological Systems Engineering: Papers and Publications

Pyrogenic organic matter (PyOM) from wildfires impacts river corridors globally and is widely regarded as resistant to biological degradation. Though recent work suggests PyOM may be more bioavailable than historically perceived, estimating bioavailability across its chemical spectrum remains elusive. To address this knowledge gap, we assessed potential bioavailability of representative PyOM compounds relative to ubiquitous dissolved organic matter (DOM) with a substrate-explicit model. The range of potential bioavailability of PyOM was greater than natural DOM; however, the predicted thermodynamics, metabolic rates, and carbon use efficiencies (CUEs) overlapped significantly between all OM pools. Compound type (e.g., natural versus PyOM) had approximately …


Enrofloxacin And Sulfamethoxazole Sorption On Carbonized Leonardite: Kinetics, Isotherms, Influential Effects, And Antibacterial Activity Toward S. Aureus Atcc 25923, Chanat Chokejaroenrat, Chainarong Sakulthaew, Khomson Satchasataporn, Daniel D. Snow, Tarik E. Ali, Mohammed A. Assiri, Apichon Watcharenwong, Saksit Imman, Nopparat Suriyachai, Torpong Kreetachat Sep 2022

Enrofloxacin And Sulfamethoxazole Sorption On Carbonized Leonardite: Kinetics, Isotherms, Influential Effects, And Antibacterial Activity Toward S. Aureus Atcc 25923, Chanat Chokejaroenrat, Chainarong Sakulthaew, Khomson Satchasataporn, Daniel D. Snow, Tarik E. Ali, Mohammed A. Assiri, Apichon Watcharenwong, Saksit Imman, Nopparat Suriyachai, Torpong Kreetachat

Nebraska Water Center: Faculty Publications

Excessive antibiotic use in veterinary applications has resulted in water contamination and potentially poses a serious threat to aquatic environments and human health. The objective of the current study was to quantify carbonized leonardite (cLND) adsorption capabilities to remove sulfamethoxazole (SMX)- and enrofloxacin (ENR)-contaminated water and to determine the microbial activity of ENR residuals on cLND following adsorption. The cLND samples prepared at 450oC and 850oC (cLND450 and cLND550, respectively) were evaluated for structural and physical characteristics and adsorption capabilities based on adsorption kinetics and isotherm studies. The low pyrolysis temperature of cLND resulted in a …


Application Of Biochar As Beneficial Additive In Concrete, Temirlan Barissov Dec 2021

Application Of Biochar As Beneficial Additive In Concrete, Temirlan Barissov

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Biochar is a high-carbon solid material produced via thermal decomposition of organic biomass in a low-oxygen environment. Characterized with high water retention properties and high alkalinity, biochar is generally used for soil amendment and fertilization purposes. This study is intended to explore the feasibility of using biochar as a beneficial additive of the most used manmade material, concrete. Literature review revealed several studies where biochar was successfully implemented as an additive in concrete. The beneficial influence of biochar on the mechanical characteristics of concrete is based on nucleation and densification effects. However, the internal microstructure, porosity and chemical composition of …


Biotransformation Of Doxycycline By Brevundimonas Naejangsanensis And Sphingobacterium Mizutaii Strains, Ting He, Jianguo Bao, Yifei Leng, Daniel D. Snow, Shuqiong Kong, Tong Wang, Xu Li Jun 2021

Biotransformation Of Doxycycline By Brevundimonas Naejangsanensis And Sphingobacterium Mizutaii Strains, Ting He, Jianguo Bao, Yifei Leng, Daniel D. Snow, Shuqiong Kong, Tong Wang, Xu Li

Nebraska Water Center: Faculty Publications

The fate of doxycycline (DC), a second generation tetracycline antibiotic, in the environment has drawn increasing attention in recent years due to its wide usage. Little is known about the biodegradability of DC in the environment. The objective of this study was to characterize the biotransformation of DC by pure bacterial strains with respect to reaction kinetics under different environmental conditions and biotransformation products. Two bacterial strains, Brevundimonas naejangsanensis DD1 and Sphingobacterium mizutaii DD2, were isolated from chicken litter and characterized for their biotransformation capability of DC. Results show both strains rely on cometabolism to biotransform DC with tryptone as …


Uavs For Vegetation Monitoring: Overview And Recent Scientific Contributions, Ana I. De Castro, Yeyin Shi, Joe Mari Maja, Jose M. Peña May 2021

Uavs For Vegetation Monitoring: Overview And Recent Scientific Contributions, Ana I. De Castro, Yeyin Shi, Joe Mari Maja, Jose M. Peña

Biological Systems Engineering: Papers and Publications

This paper reviewed a set of twenty-one original and innovative papers included in a special issue on UAVs for vegetation monitoring, which proposed new methods and techniques applied to diverse agricultural and forestry scenarios. Three general categories were considered: (1) sensors and vegetation indices used, (2) technological goals pursued, and (3) agroforestry applications. Some investigations focused on issues related to UAV flight operations, spatial resolution requirements, and computation and data analytics, while others studied the ability of UAVs for characterizing relevant vegetation features (mainly canopy cover and crop height) or for detecting different plant/crop stressors, such as nutrient content/deficiencies, water …


Removal Of Carbamazepine Onto Modified Zeolitic Tuff In Different Water Matrices: Batch And Continuous Flow Experiments, Othman A. Al-Mashaqbeh, Diya A. Alsafadi, Layal Z. Alsalhi, Shannon L. Bartelt-Hunt, Daniel D. Snow Apr 2021

Removal Of Carbamazepine Onto Modified Zeolitic Tuff In Different Water Matrices: Batch And Continuous Flow Experiments, Othman A. Al-Mashaqbeh, Diya A. Alsafadi, Layal Z. Alsalhi, Shannon L. Bartelt-Hunt, Daniel D. Snow

Nebraska Water Center: Faculty Publications

Carbamazepine (CBZ) is the most frequently detected pharmaceutical residues in aquatic environments effluent by wastewater treatment plants. Batch and column experiments were conducted to evaluate the removal of CBZ from ultra-pure water and wastewater treatment plant (WWTP) effluent using raw zeolitic tuff (RZT) and surfactant modified zeolite (SMZ). Point zero net charge (pHpzc), X-ray diffraction (XRD), X-ray fluorescence (XRF), and Fourier Transform Infrared (FTIR) were investigated for adsorbents to evaluate the physiochemical changes resulted from the modification process using Hexadecyltrimethylammonium bromide (HDTMA-Br). XRD and FTIR showed that the surfactant modification of RZT has created an amorphous surface with new alkyl …


Advanced Concrete Composites For Improved Performance: A Bibliometric Survey, Dhruv Patel, Aryan Tiwari, Nishnat Nikhare, Rohit Shinde, Ashutosh Dubey, Manan Shah, Shalaka Hire, Sayali Sandbhor Mar 2021

Advanced Concrete Composites For Improved Performance: A Bibliometric Survey, Dhruv Patel, Aryan Tiwari, Nishnat Nikhare, Rohit Shinde, Ashutosh Dubey, Manan Shah, Shalaka Hire, Sayali Sandbhor

Library Philosophy and Practice (e-journal)

Concrete is the core component of any civil engineering construction. Conventional concrete can be modified depending upon the needs and requirements of the construction. Such concrete is called advanced concrete and this report aims to study advanced concrete and its composites. The main objective of this report is to perform a bibliographic survey on the latest research literature available under the domain of advanced concrete composites for improved performance. Timespan considered for the survey is from the year 2015 to 2020. The bibliographic survey consists of literature from online platforms such as the Web of Science (WoS) and Scopus database. …


Single-Step Hydrothermal Synthesis Of Biochar From H3po4-Activated Lettucewaste For Efficient Adsorption Of Cd(Ii) In Aqueous Solution, Quyun Chen, Tian C. Zhang, Like Ouyang, Shaojun Yuan Jan 2021

Single-Step Hydrothermal Synthesis Of Biochar From H3po4-Activated Lettucewaste For Efficient Adsorption Of Cd(Ii) In Aqueous Solution, Quyun Chen, Tian C. Zhang, Like Ouyang, Shaojun Yuan

Department of Civil and Environmental Engineering: Faculty Publications

Developing an ideal and cheap adsorbent for adsorbing heavy metals from aqueous solution has been urgently need. In this study, a novel, effective and low-cost method was developed to prepare the biochar from lettuce waste with H3PO4 as an acidic activation agent at a low-temperature (circa 200°C) hydrothermal carbonization process. A batch adsorption experiment demonstrated that the biochar reaches the adsorption equilibrium within 30 min, and the optimal adsorption capacity of Cd(II) is 195.8 mg⋅g-1at solution pH 6.0, which is significantly improved from circa 20.5 mg⋅g-1 of the original biochar without activator. The fitting …


Combining Electrochemical Nitrate Reduction And Anammox For Treatment Of Nitrate-Rich Wastewater: A Short Review, Xinyi Zou, Chongjun Chen, Changhong Wang, Qun Zhang, Zhuowei Yu, Haiping Wu, Chao Zhuo, Tian C. Zhang Jan 2021

Combining Electrochemical Nitrate Reduction And Anammox For Treatment Of Nitrate-Rich Wastewater: A Short Review, Xinyi Zou, Chongjun Chen, Changhong Wang, Qun Zhang, Zhuowei Yu, Haiping Wu, Chao Zhuo, Tian C. Zhang

Department of Civil and Environmental Engineering: Faculty Publications

Treatment of nitrate-rich wastewater is important but challenging for the conventional biological denitrification process. Here, we propose combining the electrochemical reduction and anaerobic ammonium oxidation (anammox) processes together for treatment of nitrate-rich wastewater. This article reviews the mechanism and current research status of electrochemical reduction of nitrate to ammonium as well as the mechanism and applicability of the anammox process. This article discusses the principles, superiorities, and challenges of this combined process. The feasibility of the combined process depends on the efficiency of electrochemical nitrate reduction to ammonium and the conditions in the anammox process to use the reduced ammonium …


Occurrence Of Arsenite In Surface And Groundwater Associated With A Perennial Stream Located In Western Nebraska, Usa, Arindam Malakar, Rajesh Singh, Jeffrey Westrop, Karrie A. Weber, Christopher N. Elofson, Manish Kumar, Daniel D. Snow Jan 2021

Occurrence Of Arsenite In Surface And Groundwater Associated With A Perennial Stream Located In Western Nebraska, Usa, Arindam Malakar, Rajesh Singh, Jeffrey Westrop, Karrie A. Weber, Christopher N. Elofson, Manish Kumar, Daniel D. Snow

Nebraska Water Center: Faculty Publications

Dissolved arsenic typically results from chemical weathering of arsenic rich sediments and is most often found in oxidized forms in surface water. The mobility of arsenic is controlled by its valence state and also by its association with iron oxides minerals, the forms of which are both influenced by abiotic and biotic processes in aqueous environment. In this study, speciation methods were used to measure and confirm the presence of reduced arsenic species in the surface water of Frenchman creek, a gaining stream that crosses the Colorado- Nebraska border. Selective extraction analysis of aquifer and stream bed sediments shows that …


Fate And Transport Of Antibiotics And Antibiotic Resistance Genes In Runoff And Soil As Affected By The Timing Of Swine Manure Slurry Application, Renys Enrique Barrios, Himanshu Khuntia, Shannon L. Bartelt-Hunt, John E. Gilley, Amy M. Schmidt Schmidt, Daniel D. Snow, Xu Li Apr 2020

Fate And Transport Of Antibiotics And Antibiotic Resistance Genes In Runoff And Soil As Affected By The Timing Of Swine Manure Slurry Application, Renys Enrique Barrios, Himanshu Khuntia, Shannon L. Bartelt-Hunt, John E. Gilley, Amy M. Schmidt Schmidt, Daniel D. Snow, Xu Li

Department of Civil and Environmental Engineering: Faculty Publications

Land application of swine manure slurry is a common practice to supplement nutrients to soil for crop production. This practice can introduce antibiotic residues and antibiotic resistance genes (ARGs) into the environment. Field testing is critical in identifying manure management practices effective in minimizing the environmental impacts of manure-borne antibiotic and ARGs. The objective of this study was to determine how the timing of swine manure application relative to rainfall events impacts the fate and transport of antibiotics and ARGs in surface runoff and manure-amended soil. Swine manure slurry was either broadcast or injected on test plots in the field. …


Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray Jan 2019

Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

In the race to enhance agricultural productivity, irrigation will become more dependent on poorly characterized and virtually unmonitored sources of water. Increased use of irrigation water has led to impaired water and soil quality in many areas. Historically, soil salinization and reduced crop productivity have been the primary focus of irrigation water quality. Recently, there is increasing evidence for the occurrence of geogenic contaminants in water. The appearance of trace elements and an increase in the use of wastewater has highlighted the vulnerability and complexities of the composition of irrigation water and its role in ensuring proper crop growth, and …


Greenhouse Gas Emissions From Beef Feedlot Surface Materials As Affected By Diet, Moisture, Temperature, And Time, Bryan L. Woodbury, John E. Gilley, David B. Parker, Bobbi S. Stomer Jan 2018

Greenhouse Gas Emissions From Beef Feedlot Surface Materials As Affected By Diet, Moisture, Temperature, And Time, Bryan L. Woodbury, John E. Gilley, David B. Parker, Bobbi S. Stomer

Biological Systems Engineering: Papers and Publications

A laboratory study was conducted to measure the effects of diet, moisture, temperature, and time on greenhouse gas (GHG) emissions from feedlot surface materials (FSM). The FSM were collected from open-lot pens where beef cattle were fed either a dry-rolled corn (DRC) diet containing no wet distillers grains with solubles (WDGS) or a DRC diet containing 35% WDGS. The FSM were collected, air-dried or mixed with 3.0 L of water to represent dry or wet conditions, and then incubated at temperatures of 5°C, 15°C, 25°C, or 35°C. Static flux chambers were used to quantify GHG emissions over a 14-day period. …


Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Yun Zhang, Yuping Zhang, J. Brett Sallach Jan 2016

Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Yun Zhang, Yuping Zhang, J. Brett Sallach

Nebraska Water Center: Faculty Publications

A total of 59 papers published in 2015 were reviewed ranging from detailed descriptions of analytical methods, to fate and occurrence studies, to ecological effects and sampling techniques for a wide variety of emerging contaminants likely to occur in agricultural environments. New methods and studies on veterinary pharmaceuticals, steroids, antibiotic resistance genes in agricultural environments continue to expand our knowledge base on the occurrence and potential impacts of these compounds. This review is divided into the following sections: Introduction, Analytical Methods, Steroid Hormones, Pharmaceutical Contaminants, Transformation Products, and “Antibiotic Resistance, Drugs, Bugs and Genes”.


Critical Factors Affecting The Integration Of Biomass Gasification And Syngas Fermentation Technology, Karthikeyan D. Ramachandriya, Dimple K. Kundiyana, Ashokkumar M. Sharma, Ajay Kumar, Hasan K. Atiyeh, Raymond L. Huhnke, Mark R. Wilkins Jan 2016

Critical Factors Affecting The Integration Of Biomass Gasification And Syngas Fermentation Technology, Karthikeyan D. Ramachandriya, Dimple K. Kundiyana, Ashokkumar M. Sharma, Ajay Kumar, Hasan K. Atiyeh, Raymond L. Huhnke, Mark R. Wilkins

Biological Systems Engineering: Papers and Publications

Gasification-fermentation is a thermochemical-biological platform for the production of fuels and chemicals. Biomass is gasified at high temperatures to make syngas, a gas composed of CO, CO2, H2, N2 and other minor components. Syngas is then fed to anaerobic microorganisms that convert CO, CO2 and H2 to alcohols by fermentation. This platform offers numerous advantages such as flexibility of feedstock and syngas composition and lower operating temperature and pressure compared to other catalytic syngas conversion processes. In comparison to hydrolysis-fermentation, gasification-fermentation has a major advantage of utilizing all organic components of biomass, including lignin, to yield higher fuel production. Furthermore, …


Biofuels From Crop Residue Can Reduce Soil Carbon And Increase Co2 Emissions, Adam J. Liska, Haishun Yang, Maribeth Milner, Steve Goddard, Humberto Blanco-Canqui, Matthew P. Pelton, Xiao X. Fang, Haitao Zhu, Andrew E. Suyker Apr 2014

Biofuels From Crop Residue Can Reduce Soil Carbon And Increase Co2 Emissions, Adam J. Liska, Haishun Yang, Maribeth Milner, Steve Goddard, Humberto Blanco-Canqui, Matthew P. Pelton, Xiao X. Fang, Haitao Zhu, Andrew E. Suyker

Adam Liska Papers

Removal of corn residue for biofuels can decrease soil organic carbon(SOC) and increase CO2 emissions because residue C in biofuels is oxidized to CO2 at a faster rate than when added to soil. Net CO2 emissions from residue removal are not adequately characterized in biofuel life cycle assessment (LCA). Here we used a model to estimate CO2 emissions from corn residue removal across the US Corn Belt at 580 million geospatial cells. To test the SOC model, we compared estimated daily CO2 emissions from corn residue and soil with CO2 emissions measured using eddy covariance, …