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Civil and Environmental Engineering

Louisiana State University

Theses/Dissertations

2003

Sorption

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Treatment Of Chlorinated Volatile Organic Compounds Using Wetland Systems, Gabriel Roderick Kassenga Jan 2003

Treatment Of Chlorinated Volatile Organic Compounds Using Wetland Systems, Gabriel Roderick Kassenga

LSU Doctoral Dissertations

Bench-scale continuous vertical flow column and microcosm studies were conducted to investigate the attenuation potential of chlorinated volatile organic compounds (CVOCs) in constructed wetland soil mixtures prepared from peat, compost and sand and in a pristine natural freshwater wetland soil. The study also determined geotechnical properties of potential synthetic peat mixtures for construction of treatment wetlands for CVOCs. Trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2-DCE) and 1,2-dichloroethane (1,2-DCA) were the main test chemicals used during the studies. Based on geotechnical and sorption characteristics, two mixtures (one comprised of sand and peat and the other comprised of sand, peat and compost product) were selected …


Clay Landfill Liners Subject To Variable Interfacial Redox And Ph Conditions-Heavy Metal And Clay Interactions, Ping Zhou Jan 2003

Clay Landfill Liners Subject To Variable Interfacial Redox And Ph Conditions-Heavy Metal And Clay Interactions, Ping Zhou

LSU Doctoral Dissertations

Municipal landfill leachate contains high levels of metal species, including Cu, Zn, Cd and Pb generating competitive interactions between these metal species and the landfill clay liner materials. Characterization of the clay fraction, physical and chemical characteristics of landfill clay liner materials, the competitive interaction of metal species with clay liner materials, the kinetic modeling of metal species transport in clay liner, and the effect of cyclic interfacial redox potential on the structural changes to the clay liner and leachate metal transport were investigated in this study. The clay liner materials studied included Na-bentonite, kaolinite and Amite soil (sandy silty …